Hexamethyl tungsten

• Formula: C₆H₁₈W
• Molecular weight: 274.05
• IUPAC Standard InChI: InChI=1S/6CH3.W/h6*1H3; Copy

  
• IUPAC Standard InChIKey: XWAZCLPCQDERBK-UHFFFAOYSA-N Copy
• CAS Registry Number: 36133-73-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
• Options:
  • Switch to calorie-based units

Gas phase thermochemistry data

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Phase change data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Adedeji, Connor J.A., et al., 1976
Adedeji, F.A.; Connor J.A.; Skinner, H.A.; Galyer, L.; Wilkinson, G., J. Chem. Soc., Chem. Commun., 1976, 159.. [all data]

Galyer, Wilkinson, et al., 1975
Galyer, L.; Wilkinson, G.; Lloyd, D.R., The photoelectron spectra of hexamethyltungsten and pentamethyltantalum, J. Chem. Soc., Chem. Commun., 1975, 497. [all data]

Green, Lloyd, et al., 1978
Green, J.C.; Lloyd, D.R.; Galyer, L.; Mertis, K.; Wilkinson, G., Photoelectron spectra of some transition metal alkyls and oxoalkyls, J. Chem. Soc. Dalton Trans., 1978, 10, 1403. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.