Thioformyl radical
- Formula: CHS
- Molecular weight: 45.084
- CAS Registry Number: 36058-28-3
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
View reactions leading to CHS+ (ion structure unspecified)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°(+) ion | 1020. | kJ/mol | N/A | N/A |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.412 ± 0.005 | PI | Ruscic and Berkowitz, 1993 | LL |
| ≤7.499 ± 0.005 | PI | Ruscic and Berkowitz, 1993 | LL |
| >7.3 | DER | Lias, Bartmess, et al., 1988 | LL |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ruscic and Berkowitz, 1993
Ruscic, B.; Berkowitz, J.,
Photoionization mass spectrometry of CH2S and HCS,
J. Chem. Phys., 1993, 98, 2568. [all data]
Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G.,
Gas-phase ion and neutral thermochemistry,
J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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