H2N2O
- Formula: H2N2O
- Molecular weight: 46.0287
- IUPAC Standard InChIKey: XKLJHFLUAHKGGU-UHFFFAOYSA-N
- CAS Registry Number: 35576-91-1
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
HN2O- + =
By formula: HN2O- + H+ = H2N2O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1513. ± 9.6 | kJ/mol | G+TS | Sheldon, Ohair, et al., 1995 | gas phase; Acidity between PhCOMe, HCONHMe, near CF3CH2OH. Acid: H2N-NO |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1482. ± 8.4 | kJ/mol | IMRB | Sheldon, Ohair, et al., 1995 | gas phase; Acidity between PhCOMe, HCONHMe, near CF3CH2OH. Acid: H2N-NO |
Vibrational and/or electronic energy levels
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 4 | NH2 scissors | 1522.2 | Ne | IR | Jacox and Thompson, 2005 | |
4 | NH2 scissors | 1521.2 | Ar | IR | Crowley and Sodeau, 1990 | ||
4 | NH2 scissors | 1514.5 | Ar | IR | Crowley and Sodeau, 1990 | ||
5 | NNH deform. | 1203.2 | Ne | IR | Jacox and Thompson, 2005 | ||
5 | NNH deform. | 1207.3 | Ar | IR | Crowley and Sodeau, 1990 | ||
5 | NNH deform. | 1223 | N2 | IR | Crowley and Sodeau, 1990 | ||
6 | 1059.0 | Ne | IR | Jacox and Thompson, 2005 | |||
Additional references: Jacox, 1994, page 260
References
Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sheldon, Ohair, et al., 1995
Sheldon, J.C.; Ohair, R.A.J.; Downard, K.M.; Gronert, S.; Krempp, M.; Depuy, C.H.; Bowie, J.H.,
A potential surface map of the H-/N2O system. The gas phase ion chemistry of HN2O-,
Aust. J. Chem., 1995, 48, 155. [all data]
Jacox and Thompson, 2005
Jacox, M.E.; Thompson, W.E.,
Infrared spectra of NH[sub 2]NO, NH[sub 2]NO[sup +], and NNOH[sup +] and of the N[sub 2]...H[sub 2]O complex trapped in solid neon,
J. Chem. Phys., 2005, 123, 6, 064501, https://doi.org/10.1063/1.1993591
. [all data]
Crowley and Sodeau, 1990
Crowley, J.N.; Sodeau, J.R.,
Production and detection of nitrosamide in low-temperature matrixes,
J. Phys. Chem., 1990, 94, 21, 8103, https://doi.org/10.1021/j100384a023
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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