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Perfluoro(methylcyclohexane)

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.020 ± 0.060N/AMiller, Friedman, et al., 2012B
1.06 ± 0.13TDEqGrimsrud, Chowdhury, et al., 1985«DELTA»Gea(423 K) = -26.1 kcal/mol; «DELTA»Sea = -2.7 eu.; B

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CF+15.9 ± 0.2?EIJames and Carter, 1962RDSH
CF2+13.9 ± 0.2?EIJames and Carter, 1962RDSH
CF3+14.4 ± 0.2?EIJames and Carter, 1962RDSH
C2F3+14.1 ± 0.2?EIJames and Carter, 1962RDSH
C2F4+12.4 ± 0.2?EIJames and Carter, 1962RDSH
C2F5+14.4 ± 0.2?EIJames and Carter, 1962RDSH
C3F3+16.6 ± 0.2?EIJames and Carter, 1962RDSH
C3F4+11.9 ± 0.2?EIJames and Carter, 1962RDSH
C3F5+13.9 ± 0.2?EIJames and Carter, 1962RDSH
C4F5+14.9 ± 0.2?EIJames and Carter, 1962RDSH
C4F6+13.4 ± 0.2?EIJames and Carter, 1962RDSH
C4F7+15.9 ± 0.2?EIJames and Carter, 1962RDSH
C4F8+11.9 ± 0.2?EIJames and Carter, 1962RDSH
C5F7+11.9 ± 0.2?EIJames and Carter, 1962RDSH
C5F9+13.9 ± 0.2?EIJames and Carter, 1962RDSH
C5F10+15.9 ± 0.2?EIJames and Carter, 1962RDSH
C6F9+12.9 ± 0.2?EIJames and Carter, 1962RDSH
C6F10+12.4 ± 0.2?EIJames and Carter, 1962RDSH
C6F11+13.9 ± 0.2?EIJames and Carter, 1962RDSH
C7F13+15.4 ± 0.2FEIJames and Carter, 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Friedman, et al., 2012
Miller, T.M.; Friedman, J.F.; Shuman, N.S.; Ard, S.G.; Melko, J.J.; Viggiano, A.A., Electron Attachment to C7F14, Thermal Detachment from C7F14-, the Electron Affinity of C7F14, and Neutralization of C7F14- by Ar+, J. Phys. Chem. A, 2012, 116, 42, 10293-10300, https://doi.org/10.1021/jp306843a . [all data]

Grimsrud, Chowdhury, et al., 1985
Grimsrud, E.P.; Chowdhury, S.; Kebarle, P., Electron affinity of SF6 and perfluoromethylcyclohexane. The unusual kinetics of electron transfer reactions A- + B- + A, where A = SF6 or perfluorinated cycloalkanes, J. Chem. Phys., 1985, 83, 1059. [all data]

James and Carter, 1962
James, L.H.; Carter, G., A mass spectrometric study of ionization and dissociation by electron impact ofperfluoro-methyl cyclohexane, J. Electron. Control, 1962, 13, 213. [all data]


Notes

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