Bromochlorodifluoromethane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil270.6KN/APCR Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
23.0283.AStephenson and Malanowski, 1987Based on data from 268. to 324. K.; AC
23.1272.AStephenson and Malanowski, 1987Based on data from 194. to 287. K.; AC
22.4336.AStephenson and Malanowski, 1987Based on data from 321. to 403. K.; AC
23.1415.AStephenson and Malanowski, 1987Based on data from 403. to 427. K.; AC
26.0193.N/AKudchadker, Kudchadker, et al., 1979Based on data from 178. to 283. K.; AC
18.7268.N/AGlew, 1960Based on data from 178. to 283. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
177.82 to 283.043.9640936.27-32.659Glew, 1960Coefficents calculated by NIST from author's data.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
11.21 ± 0.02PIWang and Leroi, 1983LBLHLM
11.83PEDoucet, Gilbert, et al., 1975Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kudchadker, Kudchadker, et al., 1979
Kudchadker, A.P.; Kudchadker, S.A.; Shukla, R.P.; Patnaik, P.R., Vapor pressures and boiling points of selected halomethanes, J. Phys. Chem. Ref. Data, 1979, 8, 2, 499, https://doi.org/10.1063/1.555600 . [all data]

Glew, 1960
Glew, D.N., THE GAS HYDRATE OF BROMOCHLORODIFLUOROMETHANE, Can. J. Chem., 1960, 38, 2, 208-221, https://doi.org/10.1139/v60-029 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Wang and Leroi, 1983
Wang, F.C.-Y.; Leroi, G.E., Photoionization and fragmentation of halogenated methanes, Ann. Isr. Phys. Soc., 1983, 6, 210. [all data]

Doucet, Gilbert, et al., 1975
Doucet, J.; Gilbert, R.; Sauvageau, P.; Sandorfy, C., Photoelectron and far-ultraviolet spectra of CF3Br, CF2BrCl, and CF2Br2, J. Chem. Phys., 1975, 62, 366. [all data]


Notes

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