Borane, fluorodimethyl-
- Formula: C2H6BF
- Molecular weight: 59.878
- CAS Registry Number: 353-46-8
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: F- + C2H6BF = (F- • C2H6BF)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 258.6 | kJ/mol | IMRB | Murphy and Beauchamp, 1977 | gas phase; Fluoride Affinity: Et3B > Me2BF > MeSiF3 > Me3B > SF4 |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.25 | PE | Berger, Kroner, et al., 1976 | Vertical value |
11.22 | PE | Fuss and Bock, 1974 | Vertical value |
Ion clustering data
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: F- + C2H6BF = (F- • C2H6BF)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 258.6 | kJ/mol | IMRB | Murphy and Beauchamp, 1977 | gas phase; Fluoride Affinity: Et3B > Me2BF > MeSiF3 > Me3B > SF4 |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Murphy and Beauchamp, 1977
Murphy, M.K.; Beauchamp, J.L.,
Fluorine and Alkyl Substituent Effects on Gas-Phase Lewis Acidities of Boranes by ICR Spectroscopy,
Inorg. Chem., 1977, 16, 2437. [all data]
Berger, Kroner, et al., 1976
Berger, H.-O.; Kroner, J.; Noth, H.,
Die borhalogen-bindung in Methylhalogenboranen: Photoelektronenspektren und ab initio-Rechnungen,
Chem. Ber., 1976, 109, 2266. [all data]
Fuss and Bock, 1974
Fuss, W.; Bock, H.,
Photoelectron spectra and molecular properties. XXXVI. (H3C)3B, (H3C)2BF, (H3C)2BN(CH3)2, and (H3C)2CC(CH3)2: The use of ionization potentials in assigning UV spectra,
J. Chem. Phys., 1974, 61, 1613. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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