(Ch3)3(tert-c4H9)sn


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub54.0 ± 4.2kJ/molCC-SBColeman and Skinner, 1966 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.34 ± 0.11EILappert, Pedley, et al., 1971LLK
8.34 ± 0.11EILappert, Simpson, et al., 1969RDSH
8.50PEKochi, 1980Vertical value; LLK
8.65PEHosomi and Traylor, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H9Sn+9.32 ± 0.16(CH3)3CEILappert, Pedley, et al., 1971LLK
C3H9Sn+9.32 ± 0.16?EILappert, Simpson, et al., 1969RDSH
C3H9Sn+9.50 ± 0.10?EIYergey and Lampe, 1968RDSH
C4H9+10.03 ± 0.23(CH3)3SnEILappert, Pedley, et al., 1971LLK
C4H9+10.03 ± 0.23?EILappert, Simpson, et al., 1969RDSH
C6H15Sn+10.95 ± 0.19CH3EIYergey and Lampe, 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Coleman and Skinner, 1966
Coleman, D.J.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 15.?Heats of combustion of trimethyl-isopropyl tin, trimethyl-t-butyl tin and tetra-isopropyl tin, Trans. Faraday Soc., 1966, 62, 1721, https://doi.org/10.1039/tf9666201721 . [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals, J.Organometal. Chem., 1969, 17, PI. [all data]

Kochi, 1980
Kochi, J.K., The role of electron transfer and charge transfer in organometallic chemistry, Pure Appl. Chem., 1980, 52, 571. [all data]

Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G., Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy, J. Am. Chem. Soc., 1975, 97, 3682. [all data]

Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W., An electron impact study of ionization and dissociation of trimethylstannanes, J. Organometal. Chem., 1968, 15, 339. [all data]


Notes

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