Stannane, trimethyl(1-methylethyl)-
- Formula: C6H16Sn
- Molecular weight: 206.901
- IUPAC Standard InChI: InChI=1S/C3H7.3CH3.Sn/c1-3-2;;;;/h3H,1-2H3;3*1H3;
- IUPAC Standard InChIKey: CKDNMBVGKKTLEO-UHFFFAOYSA-N
- CAS Registry Number: 3531-46-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Isopropyltrimethyltin; Stannane, isopropyltrimethyl-; Isopropyltrimethylstannane; Trimethylisopropyltin; i-C3H7Sn(CH3)3
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Gas phase ion energetics data
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.28 ± 0.01 | EI | Yergey and Lampe, 1968 | RDSH |
| 8.9 | PE | Kochi, 1980 | Vertical value; LLK |
| 8.77 | PE | Hosomi and Traylor, 1975 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C3H9Sn+ | 9.17 ± 0.14 | ? | EI | Yergey and Lampe, 1968 | RDSH |
| C5H13Sn+ | 10.03 ± 0.04 | CH3 | EI | Yergey and Lampe, 1968 | RDSH |
Mass spectrum (electron ionization)
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | M.GEILEN UNIVERSITE LIBRE DE BRUXELLES, BELGIUM |
| NIST MS number | 9602 |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | Apiezon L | 190. | 794. | Putnam and Pu, 1965 | Celite; Column length: 1. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | Apiezon L | 775. | Putnam and Pu, 1965, 2 | Celite, 10. K/min; Column length: 3. m; Tstart: 60. C |
| Packed | Apiezon L | 771. | Putnam and Pu, 1965, 2 | Celite, 15. K/min; Column length: 3. m; Tstart: 60. C |
| Packed | Apiezon L | 779. | Putnam and Pu, 1965, 2 | Celite, 6. K/min; Column length: 3. m; Tstart: 60. C |
References
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W.,
An electron impact study of ionization and dissociation of trimethylstannanes,
J. Organometal. Chem., 1968, 15, 339. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G.,
Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy,
J. Am. Chem. Soc., 1975, 97, 3682. [all data]
Putnam and Pu, 1965
Putnam, R.C.; Pu, H.,
Retention indices of organotins,
J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160
. [all data]
Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H.,
Retention indices of organotins (II),
J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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