Stannane, trimethyl(1-methylethyl)-
- Formula: C6H16Sn
- Molecular weight: 206.901
- IUPAC Standard InChI: InChI=1S/C3H7.3CH3.Sn/c1-3-2;;;;/h3H,1-2H3;3*1H3;
- IUPAC Standard InChIKey: CKDNMBVGKKTLEO-UHFFFAOYSA-N
- CAS Registry Number: 3531-46-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Isopropyltrimethyltin; Stannane, isopropyltrimethyl-; Isopropyltrimethylstannane; Trimethylisopropyltin; i-C3H7Sn(CH3)3
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 40.6 ± 2.1 | kJ/mol | CC-SB | Coleman and Skinner, 1966 |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.28 ± 0.01 | EI | Yergey and Lampe, 1968 | RDSH |
| 8.9 | PE | Kochi, 1980 | Vertical value; LLK |
| 8.77 | PE | Hosomi and Traylor, 1975 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C3H9Sn+ | 9.17 ± 0.14 | ? | EI | Yergey and Lampe, 1968 | RDSH |
| C5H13Sn+ | 10.03 ± 0.04 | CH3 | EI | Yergey and Lampe, 1968 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Coleman and Skinner, 1966
Coleman, D.J.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 15.?Heats of combustion of trimethyl-isopropyl tin, trimethyl-t-butyl tin and tetra-isopropyl tin,
Trans. Faraday Soc., 1966, 62, 1721, https://doi.org/10.1039/tf9666201721
. [all data]
Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W.,
An electron impact study of ionization and dissociation of trimethylstannanes,
J. Organometal. Chem., 1968, 15, 339. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G.,
Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy,
J. Am. Chem. Soc., 1975, 97, 3682. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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