Stannane, trimethyl(1-methylethyl)-
- Formula: C6H16Sn
- Molecular weight: 206.901
- IUPAC Standard InChI: InChI=1S/C3H7.3CH3.Sn/c1-3-2;;;;/h3H,1-2H3;3*1H3;
- IUPAC Standard InChIKey: CKDNMBVGKKTLEO-UHFFFAOYSA-N
- CAS Registry Number: 3531-46-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Isopropyltrimethyltin; Stannane, isopropyltrimethyl-; Isopropyltrimethylstannane; Trimethylisopropyltin; i-C3H7Sn(CH3)3
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.28 ± 0.01 | EI | Yergey and Lampe, 1968 | RDSH |
| 8.9 | PE | Kochi, 1980 | Vertical value; LLK |
| 8.77 | PE | Hosomi and Traylor, 1975 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C3H9Sn+ | 9.17 ± 0.14 | ? | EI | Yergey and Lampe, 1968 | RDSH |
| C5H13Sn+ | 10.03 ± 0.04 | CH3 | EI | Yergey and Lampe, 1968 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W.,
An electron impact study of ionization and dissociation of trimethylstannanes,
J. Organometal. Chem., 1968, 15, 339. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G.,
Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy,
J. Am. Chem. Soc., 1975, 97, 3682. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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