Stannane, ethyltrimethyl-
- Formula: C5H14Sn
- Molecular weight: 192.875
- IUPAC Standard InChIKey: VDYIOWXZMNKCHN-UHFFFAOYSA-N
- CAS Registry Number: 3531-44-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethyltrimethyltin; Ethyltrimethylstannane; Trimethylethyltin; (CH3)3SnC2H5
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 9.01 ± 0.41 | kcal/mol | CC-SB | Bullard and Haussmann, 1930 | MS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
9.18 | 258. | N/A | Stull, 1947 | Based on data from 243. to 381. K.; AC |
8.84 | 304. | I | Bullard and Haussmann, 1929 | Based on data from 273. to 336. K.; AC |
8.34 | 360. | I | Bullard and Haussmann, 1929 | Based on data from 336. to 384. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
243. to 382.0 | 4.38658 | 1532.512 | -32.327 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.1 | PE | Kochi, 1980 | Vertical value; LLK |
9.1 | PE | Hosomi and Traylor, 1975 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C3H9Sn+ | 9.50 | ? | EI | Yergey and Lampe, 1968 | RDSH |
C3H9Sn+ | 9.49 ± 0.07 | ? | EI | Yergey and Lampe, 1968 | RDSH |
C4H11Sn+ | 9.88 ± 0.02 | CH3 | EI | Yergey and Lampe, 1968 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bullard and Haussmann, 1930
Bullard, R.H.; Haussmann, A.C.,
J. Phys. Chem., 1930, 34, 743. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Bullard and Haussmann, 1929
Bullard, R.H.; Haussmann, A.C.,
The Vapor Pressure of Some Stannanes,
J. Phys. Chem., 1929, 34, 4, 743-747, https://doi.org/10.1021/j150310a006
. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G.,
Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy,
J. Am. Chem. Soc., 1975, 97, 3682. [all data]
Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W.,
An electron impact study of ionization and dissociation of trimethylstannanes,
J. Organometal. Chem., 1968, 15, 339. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.