Silane, ethyltrimethyl-
- Formula: C5H14Si
- Molecular weight: 102.2502
- IUPAC Standard InChI: InChI=1S/C5H14Si/c1-5-6(2,3)4/h5H2,1-4H3
- IUPAC Standard InChIKey: UKAJDOBPPOAZSS-UHFFFAOYSA-N
- CAS Registry Number: 3439-38-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethyltrimethylsilane; Trimethylethylsilane; (CH3)3SiC2H5
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.6 | PE | Potzinger, Ritter, et al., 1975 | LLK |
| 9.70 ± 0.01 | EI | Hess, Lampe, et al., 1965 | RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C3H9Si+ | 10.0 ± 0.1 | C2H5 | EI | Potzinger, Ritter, et al., 1975 | LLK |
| C3H9Si+ | 10.34 ± 0.11 | ? | EI | Connor, Finney, et al., 1966 | RDSH |
| C3H9Si+ | 10.53 ± 0.09 | ? | EI | Hess, Lampe, et al., 1964 | RDSH |
| C4H11Si+ | 11.41 ± 0.06 | CH3 | EI | Hess, Lampe, et al., 1965 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J.,
Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen,
Z. Naturforsch. A:, 1975, 30, 347. [all data]
Hess, Lampe, et al., 1965
Hess, G.G.; Lampe, F.W.; Sommer, L.H.,
An electron impact study of ionization and dissociation of trimethylsilanes,
J. Am. Chem. Soc., 1965, 87, 5327. [all data]
Connor, Finney, et al., 1966
Connor, J.A.; Finney, G.; Leigh, G.J.; Haszeldine, R.N.; Robinson, P.J.; Sedgwick, R.D.; Simmons, R.F.,
Bond dissociation energies in organosilicon compounds,
Chem. Commun., 1966, 178. [all data]
Hess, Lampe, et al., 1964
Hess, G.G.; Lampe, F.W.; Sommer, L.H.,
Bond dissociation energies and ion energetics in organosilicon compounds by electron impact,
J. Am. Chem. Soc., 1964, 86, 3174. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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