Tetrakis(trimethylsilylmethyl)titanium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-684. ± 17.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1579.0 ± 3.9 kJ/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-760. ± 15.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1579.0 ± 3.9 kJ/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap75.3 ± 8.4kJ/molRSCLappert, Patil, et al., 1975 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.0PELappert, Pedley, et al., 1974LLK
8.6 ± 0.1PELappert, Pedley, et al., 1974Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Lappert, Patil, et al., 1975
Lappert, M.F.; Patil, D.S.; Pedley, J.B., J. Chem. Soc., Chem. Commun., 1975, 830.. [all data]

Lappert, Pedley, et al., 1974
Lappert, M.F.; Pedley, J.B.; Sharp, G., Bonding studies of transition metal complexes. I. He(I) photoelectron spectra of d0 silylmethyl and neopentyl derivatives of Group IVA metals, J. Organomet. Chem., 1974, 66, 271. [all data]


Notes

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