Pentafluoromethylamine


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

CF5N = Tetrafluoromethane + 0.5Nitrogen + 0.5fluorine

By formula: CF5N = CF4 + 0.5N2 + 0.5F2

Quantity Value Units Method Reference Comment
Δr-54.0 ± 0.4kcal/molCcbWalker, 1972gas phase; Decompostion reaction

Tetrafluoromethane + 0.5Nitrogen + 0.5fluorine = CF5N

By formula: CF4 + 0.5N2 + 0.5F2 = CF5N

Quantity Value Units Method Reference Comment
Δr54.0 ± 0.4kcal/molCcbWalker, 1972gas phase; Decompostion reaction

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
11.9PEBurger, Pawelke, et al., 1982LBLHLM
12.62PEBurger, Pawelke, et al., 1982Vertical value; LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Walker, 1972
Walker, L.C., The enthalpy of decomposition of CF3NF2(g) to CF4(g), N2(g), and F2(g), J. Chem. Thermodyn., 1972, 4, 219-223. [all data]

Burger, Pawelke, et al., 1982
Burger, H.; Pawelke, G.; Dammel, R.; Bock, H., Effects of fluorine substitution on methyl amines, J. Fluorine Chem., 1982, 19, 565. [all data]


Notes

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