trifluoronitrosomethane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to CF3NO+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)168.1kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity160.3kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
>2.00 ± 0.20EIAEHarland, 1977From(CF3)2NO; G3MP2B3 calculations indicate an EA of ca. 1.7 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.5 ± 0.1EISyrvatka and Gil'burd, 1973LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CF2+16.7 ± 0.2FNOEISyrvatka and Gil'burd, 1973LLK
CF3+12.6 ± 0.1NOEISyrvatka and Gil'burd, 1973LLK
NO+12.4 ± 0.1CF3EISyrvatka and Gil'burd, 1973LLK
CNOF3+11.06 ± 0.05?PEErnsting, Pfab, et al., 1980Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Harland, 1977
Harland, P.W., Electron attachment to the stable free radical bis-trifluoromethylnitroxide in the gas phase, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 61. [all data]

Syrvatka and Gil'burd, 1973
Syrvatka, B.G.; Gil'burd, M.M., Mass-spectrometric study of trifluoronitrosomethane, Russ. J. Phys. Chem., 1973, 47, 1215. [all data]

Ernsting, Pfab, et al., 1980
Ernsting, N.P.; Pfab, J.; Green, J.C.; Romelt, J., Photoelectron spectra of nitrosomethane, t-nitrosobutane and some perhalogenonitrosomethanes, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 844. [all data]


Notes

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