Phosphorodiamidous chloride, tetramethyl-

• Formula: C₄H₁₂ClN₂P
• Molecular weight: 154.578
• IUPAC Standard InChI: InChI=1S/C4H12ClN2P/c1-6(2)8(5)7(3)4/h1-4H3 Copy

  
• IUPAC Standard InChIKey: MAJFLEHNBOUSIY-UHFFFAOYSA-N Copy
• CAS Registry Number: 3348-44-5
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Bis(dimethylamino)chlorophosphine; Bis(dimethylamino)phosphorus chloride; Chlorobis(dimethylamino)phosphine; Phosphine, chlorobis(dimethylamino)-; Tetramethyldiaminochlorophosphine; Tetramethylphosphorodiamidous chloride; ((CH3)2N)2PCl; N,N,N',N'-Tetramethylphosphorodiamidous chloride
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
• Options:
  • Switch to SI units

Phase change data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Reduced pressure boiling point

Gas phase ion energetics data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Al-Maydama, Finch, et al., 1995
Al-Maydama, H.M.A.; Finch, Arthur; Gardner, P.J.; Head, A.J., The enthalpies of formation of (dimethylamino)dichlorophosphine, bis(dimethylamino)chlorophosphine, and tris(dimethylamino)phosphine, The Journal of Chemical Thermodynamics, 1995, 27, 3, 273-279, https://doi.org/10.1006/jcht.1995.0026 . [all data]

Lappert, Pedley, et al., 1975
Lappert, M.F.; Pedley, J.B.; Wilkins, B.T.; Stelzer, O.; Unger, E., Bonding studies of compounds of boron and the group 3-5 elements. Part XIII. He(I) photoelectron spectra of phosphines R_nPX_3-n (R=Me or Bu'; X=H, Cl, or F; n=1-3), (Me₂N)_nPCl_3-n(n=1-3), and (R₂N)PF₂(R=Me or Et), J. Chem. Soc. Dalton Trans., 1975, 1207. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.