Phosphorodiamidous chloride, tetramethyl-

• Formula: C₄H₁₂ClN₂P
• Molecular weight: 154.578
• IUPAC Standard InChI: InChI=1S/C4H12ClN2P/c1-6(2)8(5)7(3)4/h1-4H3 Copy

  
• IUPAC Standard InChIKey: MAJFLEHNBOUSIY-UHFFFAOYSA-N Copy
• CAS Registry Number: 3348-44-5
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Bis(dimethylamino)chlorophosphine; Bis(dimethylamino)phosphorus chloride; Chlorobis(dimethylamino)phosphine; Phosphine, chlorobis(dimethylamino)-; Tetramethyldiaminochlorophosphine; Tetramethylphosphorodiamidous chloride; ((CH3)2N)2PCl; N,N,N',N'-Tetramethylphosphorodiamidous chloride
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Reduced pressure boiling point

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Al-Maydama, Finch, et al., 1995
Al-Maydama, H.M.A.; Finch, Arthur; Gardner, P.J.; Head, A.J., The enthalpies of formation of (dimethylamino)dichlorophosphine, bis(dimethylamino)chlorophosphine, and tris(dimethylamino)phosphine, The Journal of Chemical Thermodynamics, 1995, 27, 3, 273-279, https://doi.org/10.1006/jcht.1995.0026 . [all data]

Lappert, Pedley, et al., 1975
Lappert, M.F.; Pedley, J.B.; Wilkins, B.T.; Stelzer, O.; Unger, E., Bonding studies of compounds of boron and the group 3-5 elements. Part XIII. He(I) photoelectron spectra of phosphines R_nPX_3-n (R=Me or Bu'; X=H, Cl, or F; n=1-3), (Me₂N)_nPCl_3-n(n=1-3), and (R₂N)PF₂(R=Me or Et), J. Chem. Soc. Dalton Trans., 1975, 1207. [all data]

Notes

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• Symbols used in this document:
  

  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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