MeO anion
- Formula: CH3O-
- Molecular weight: 31.0345
- CAS Registry Number: 3315-60-4
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 12655 ± 15 | gas | Engleking, Ellison, et al., 1978 | |||||
Osborn, Leahy, et al., 1998 | |||||||
Ramond, Davico, et al., 2000 | |||||||
Nee, Osterwalder, et al., 2006 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 3 | 1113 | gas | TPE | Nee, Osterwalder, et al., 2006 | ||
e | 6 | 1120 | gas | TPE | Nee, Osterwalder, et al., 2006 | ||
Additional references: Jacox, 1994, page 242; Jacox, 2003, page 260; Oakes, Harding, et al., 1985
Notes
d | Photodissociation threshold |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Engleking, Ellison, et al., 1978
Engleking, P.C.; Ellison, G.B.; Lineberger, W.C.,
Laser photodetachment electron spectrometry of methoxide, deuteromethoxide, and thiomethoxide: Electron affinities and vibrational structure of CH3O, and CH3S,
J. Chem. Phys., 1978, 69, 1826. [all data]
Osborn, Leahy, et al., 1998
Osborn, D.L.; Leahy, D.J.; Kim, E.H.; de Beer, E.; Neumark, D.M.,
Photoelectron spectroscopy of CH3O- and CD3O-,
Chem. Phys. Lett., 1998, 292, 4-6, 651, https://doi.org/10.1016/S0009-2614(98)00717-9
. [all data]
Ramond, Davico, et al., 2000
Ramond, T.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C.,
Vibronic structure of alkoxy radicals via photoelectron spectroscopy,
J. Chem. Phys., 2000, 112, 3, 1158, https://doi.org/10.1063/1.480767
. [all data]
Nee, Osterwalder, et al., 2006
Nee, M.J.; Osterwalder, A.; Zhou, J.; Neumark, D.M.,
Slow electron velocity-map imaging photoelectron spectra of the methoxide anion,
J. Chem. Phys., 2006, 125, 1, 014306, https://doi.org/10.1063/1.2212411
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Oakes, Harding, et al., 1985
Oakes, J.M.; Harding, L.B.; Ellison, G.B.,
The photoelectron spectroscopy of HO2-,
J. Chem. Phys., 1985, 83, 5400. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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