Methyl, 1,2-phenylenebis-


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   b


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 7520 U gas Wenthold, Kim, et al., 1997

State:   a


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 3350 ± 65 gas Wenthold, Kim, et al., 1997


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1260 ± 40 gas PE Wenthold, Kim, et al., 1997
1000 ± 40 gas PE Wenthold, Kim, et al., 1997
265 ± 20 gas PE Wenthold, Kim, et al., 1997

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 CH2 scissors 1500 ± 40 gas PE Wenthold, Kim, et al., 1997
Ring deform. 540 ± 20 gas PE Wenthold, Kim, et al., 1997
Ring=C bend 290 ± 20 gas PE Wenthold, Kim, et al., 1997

Additional references: Jacox, 1998, page 351

Notes

UUpper bound
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wenthold, Kim, et al., 1997
Wenthold, P.G.; Kim, J.B.; Lineberger, W.C., Photoelectron Spectroscopy of m-Xylylene Anion, J. Am. Chem. Soc., 1997, 119, 6, 1354, https://doi.org/10.1021/ja9623830 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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