1-Cyanoethyl radical
- Formula: C3H4N
- Molecular weight: 54.0706
- IUPAC Standard InChI: InChI=1S/C3H4N/c1-2-3-4/h2H,1H3
- IUPAC Standard InChIKey: VQGISNOMGHCEPX-UHFFFAOYSA-N
- CAS Registry Number: 3264-99-1
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
View reactions leading to C3H4N+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.766 ± 0.012 | LPES | Duan, Burggraf, et al., 2002 | B |
| 1.50 ± 0.10 | LPES | Nakajima, Taguwa, et al., 1995 | Vertical Detachment Energy: 1.71±0.10 eV; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.8 ± 0.1 | EI | Pottie and Lossing, 1961 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Duan, Burggraf, et al., 2002
Duan, X.F.; Burggraf, L.W.; Weeks, D.E.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C.,
Photoelectron spectroscopy of Si2C3- and quantum chemistry of the linear Si2C3 cluster and its isomers,
J. Chem. Phys., 2002, 116, 9, 3601-3611, https://doi.org/10.1063/1.1427709
. [all data]
Nakajima, Taguwa, et al., 1995
Nakajima, A.; Taguwa, T.; Nakao, K.; Gomei, M.; Kishi, R.; Iwata, S.; Kaya, K.,
Photoelectron Spectroscopy of silicon-carbon cluster Anions (SinCm-),
J. Chem. Phys., 1995, 103, 6, 2050, https://doi.org/10.1063/1.469731
. [all data]
Pottie and Lossing, 1961
Pottie, R.F.; Lossing, F.P.,
Free radicals by mass spectrometry. XXV. Ionization potentials of cyanoalkyl radicals,
J. Am. Chem. Soc., 1961, 83, 4737. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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