Nickel acetylacetonate
- Formula: C10H14NiO4
- Molecular weight: 256.9092
- IUPAC Standard InChIKey: BMGNSKKZFQMGDH-FDGPNNRMSA-L
- CAS Registry Number: 3264-82-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Nickel, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-; Nickel, bis(2,4-pentanedionato)-; Acetylacetonato nickel; Bis(acetylacetonate)nickel; Bis(acetylacetonato)nickel; Bis(2,4-pentanedionato)nickel; Bis-2,4-pentanedionatonickel(II); Ni(II) Acetylacetone complex (1:2); Nickel acetonylacetonate; Nickel bis(acetylacetonate); Nickel bis(2,4-pentanedionate); Nickel(II) acetylacetonate; Nickel(2+) acetylacetonate; Nickelous acetylacetonate; Nickel(II) 2,4-pentanedionate; Bis(acetylacetonato)nickel(II); Acetylacetonatonickel (II); Bis(acetylacetone)nickel; NSC 4657; bis(pentane-2,4-dionato-O,O')nickel
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 30.2 ± 1.1 | kcal/mol | ME | Malkerova, Alikhanyan, et al., 1990 | Based on data from 357. to 420. K. |
ΔsubH° | 37. ± 19. | kcal/mol | C | Murata, Sakiyama, et al., 1985 | |
ΔsubH° | 31.5 ± 2.4 | kcal/mol | ME | Burkinshaw and Mortimer, 1984 |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
26. ± 1. | 207. | DSC | Murray and Hill, 1987 | |
25.9 ± 1.2 | 480. | DSC | Ribeiro Da Silva and Ferrão, 1987 | |
30.5 ± 2.4 | 381. | ME | Burkinshaw and Mortimer, 1984 | Based on data from 378. to 403. K. |
22.8 | 400. | N/A | Götze, Bloss, et al., 1970 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.23 ± 0.05 | EI | Reichert and Westmore, 1969 | RDSH |
7.62 | PE | Kitagawa, Morishima, et al., 1983 | Vertical value; LBLHLM |
7.35 | PE | Fragala, Costanzo, et al., 1980 | Vertical value; LLK |
7.40 | PE | Cauletti, Furlani, et al., 1980 | Vertical value; LLK |
7.41 | PE | Cauletti and Furlani, 1975 | Vertical value; LLK |
7.61 | PE | Brittain and Disch, 1975 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C5H7O2Ni+ | 13.5 ± 0.2 | ? | EI | Reichert and Westmore, 1969 | RDSH |
C9H11O4Ni+ | 11.6 ± 0.1 | ? | EI | Reichert and Westmore, 1969 | RDSH |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | STANDARD OIL OF OHIO |
Source reference | COBLENTZ NO. 196 |
Date | Not specified, most likely prior to 1970 |
State | SOLID (0.5% IN KBr PELLET) |
Instrument | Not specified, most likely a grating spectrometer. |
Resolution | 4 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY NIST FROM HARD COPY |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Chemical Concepts |
NIST MS number | 157252 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I.,
Thermal behavior of 3d transition metal acetylacetonates,
Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]
Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S.,
Sublimation calorimetric studies using a calvet microcalorimeter,
Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8
. [all data]
Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T.,
Enthalpies of sublimation of transition metal complexes,
J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075
. [all data]
Murray and Hill, 1987
Murray, J.P.; Hill, J.O.,
DSC determination of the sublimation enthalpy of tris(2,4-pentanedionato)cobalt(III) and bis(2,4-pentanedionato) nickel(II) and -copper(II),
Thermochimica Acta, 1987, 109, 2, 383-390, https://doi.org/10.1016/0040-6031(87)80034-5
. [all data]
Ribeiro Da Silva and Ferrão, 1987
Ribeiro Da Silva, Manuel A.V.; Ferrão, Maria Luísa C.C.H.,
Standard enthalpies of formation of tris(β-diketonate)chromium(III) complexes: the mean (Cr«58872»O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1987, 19, 6, 645-652, https://doi.org/10.1016/0021-9614(87)90070-X
. [all data]
Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H.,
Dampfdruckbestimmung von Acetylacetonaten,
Zeitschrift für Physikalische Chemie, 1970, 73, 46, 314-320, https://doi.org/10.1524/zpch.1970.73.46.314
. [all data]
Reichert and Westmore, 1969
Reichert, C.; Westmore, J.B.,
Mass spectral studies of metal chelates. IV.Mass spectra, appearance potentials, and coordinate bond energies of bis(acetylacetonate)metal(II) complexes of the first transition series,
Inorg. Chem., 1969, 8, 1012. [all data]
Kitagawa, Morishima, et al., 1983
Kitagawa, S.; Morishima, I.; Yoshikawa, K.,
UV photoelectron spectra of some transition metal(II)aAcetylacetonates,
Polyhedron, 1983, 2, 43. [all data]
Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C.,
He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with β-diketonate ligands,
Inorg. Chim. Acta, 1980, 40, 15. [all data]
Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G.,
Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues,
J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]
Cauletti and Furlani, 1975
Cauletti, C.; Furlani, C.,
He(I) photoelectron spectra of bis(β-diketonate)nickel(II) complexes their and mono- and di-thio analogues,
J. Electron Spectrosc. Relat. Phenom., 1975, 6, 465. [all data]
Brittain and Disch, 1975
Brittain, H.G.; Disch, R.L.,
The He(I) photoelectron spectra of some bivalent transition metal β-diketonate complexes*,
J. Electron Spectrosc. Relat. Phenom., 1975, 7, 475. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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