GaOH
- Formula: GaHO
- Molecular weight: 86.730
- CAS Registry Number: 32365-63-2
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Tx = 39000 | Ar | A-X | Douglas, Hauge, et al., 1983 | ||||
| Tx = 39000 | Kr | A-X | Douglas, Hauge, et al., 1983 | ||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | OH stretch | 3689.8 | Ar | IR | Hauge, Kauffman, et al., 1980 Macrae and Downs, 2004 Wang and Andrews, 2007 | |
| Π | 2 | Bend | 425.5 | Ar | IR | Hauge, Kauffman, et al., 1980 Macrae and Downs, 2004 | |
| Σ+ | 3 | GaO stretch | 613.2 | Ar | IR | Hauge, Kauffman, et al., 1980 Macrae and Downs, 2004 Wang and Andrews, 2007 | |
Additional references: Jacox, 1994, page 36
Notes
| x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Douglas, Hauge, et al., 1983
Douglas, M.A.; Hauge, R.H.; Margrave, J.L.,
J. Chem. Soc., 1983, Faraday Trans. 1 79, 1533. [all data]
Hauge, Kauffman, et al., 1980
Hauge, R.H.; Kauffman, J.W.; Margrave, J.L.,
Infrared matrix-isolation studies of the interactions and reactions of Group 3A metal atoms with water,
J. Am. Chem. Soc., 1980, 102, 19, 6005, https://doi.org/10.1021/ja00539a005
. [all data]
Macrae and Downs, 2004
Macrae, V.A.; Downs, A.J.,
Matrix studies of the thermal and photolytic reactions of Ga vapour species with H2O: formation and characterisation of the adducts Ga«65533»OH2 and Ga2«65533»OH2 and the photoproducts HGaOH, GaOH and Ga(«65533»-H)(«65533»-OH)GaElectronic supplementary information (ESI) available: UV?vis spectra of an Ar matrix containing Ga and H2O (Fig. S1); calculated and observed IR spectral details for Ga(«65533»-H)(«65533»-OH)Ga (Table S1). See http://www.rsc.org/suppdata/cp/b4/b405298f/,
Phys. Chem. Chem. Phys., 2004, 6, 19, 4571, https://doi.org/10.1039/b405298f
. [all data]
Wang and Andrews, 2007
Wang, X.; Andrews, L.,
Infrared Spectroscopic Observation of the Group 13 Metal Hydroxides, M(OH),
J. Phys. Chem. A, 2007, 111, 10, 1860, https://doi.org/10.1021/jp066390e
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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