Methylthiomethyl radical
- Formula: C2H5S
- Molecular weight: 61.126
- IUPAC Standard InChI: InChI=1S/C2H5S/c1-3-2/h1H2,2H3
- IUPAC Standard InChIKey: HLVMZRXHDRXSJY-UHFFFAOYSA-N
- CAS Registry Number: 31533-72-9
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess
View reactions leading to C2H5S+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.868 ± 0.051 | LPES | Moran and Ellison, 1988 | B |
| 0.74 ± 0.10 | D-EA | Ingemann and Nibbering, 1985 | B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 6.85 ± 0.03 | PE | Baker and Dyke, 1993 | LL |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Moran and Ellison, 1988
Moran, S.; Ellison, G.B.,
Photoelectron Spectroscopy of Sulfur Ions,
J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021
. [all data]
Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M.,
Gas phase chemistry of alpha-thio carbanions,
Can. J. Chem., 1985, 62, 2273. [all data]
Baker and Dyke, 1993
Baker, J.; Dyke, J.M.,
A photoelectron and ab initio study of the CH3SCH2 radical,
Chem. Phys. Lett., 1993, 213, 257. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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