Arsenous acid, triethyl ester


Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap50.6 ± 4.2kJ/molN/ACharnley, Mortimer, et al., 1953Based on data from 305. to 340. K. See also Cox and Pilcher, 1970.

Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H4OAs+12.30?EIPreiss, 1974 
C2H5OAs+10.80?EIPreiss, 1974 
C2H6OAs+12.30?EIPreiss, 1974 
C4H9O2As+8.60C2H5OHEIPreiss, 1974 
C4H10O2As+10.03C2H5OEIPreiss, 1974 
C4H11O2As+8.52C2H4OEIPreiss, 1974 

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin O7-75-1B
NIST MS number 32245

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Charnley, Mortimer, et al., 1953
Charnley, T.; Mortimer, C.T.; Skinner, H.A., 236. The thermochemistry of organo-arsenic compounds. Part II. Esters of arsenious acid, J. Chem. Soc., 1953, 1181, https://doi.org/10.1039/jr9530001181 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

Preiss, 1974
Preiss, H., Die Massenspektren einiger arsen- und arsenigsaureester. Kinetische untersuchung ihres fragmentierungsverhaltens, Z. Anorg. Allg. Chem., 1974, 404, 175. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References