Perfluoronaphthalene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
19.0 ± 0.60308.AStephenson and Malanowski, 1987Based on data from 293. to 323. K. See also Radchenko and Kataigorodskii, 1974.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference
4.195358.8Michaud, Negrier, et al., 1999

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
IE (evaluated)8.87 ± 0.02eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
8.85PEHohlneicher, Distler, et al., 1984LBLHLM
8.90 ± 0.05PEBastide, Hall, et al., 1979LLK
8.85PEBrundle, Robin, et al., 1972LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
NIST MS number 340581

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UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Jakobson, Shteingarts, et al., 1964
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 287
Instrument Spectrophotometer SF-16
Melting point 87-88

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPB-11090.Andersson and Weis, 199450. m/0.32 mm/0.2 μm, H2, 80. C @ 2. min, 4. K/min, 270. C @ 5. min
CapillaryDB-51103.Andersson and Weis, 199430. m/0.32 mm/0.25 μm, H2, 80. C @ 2. min, 4. K/min, 270. C @ 5. min

Lee's RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPB-1186.73Andersson and Weis, 199450. m/0.32 mm/0.2 μm, H2, 80. C @ 2. min, 4. K/min, 270. C @ 5. min
CapillaryDB-5189.2Andersson and Weis, 199430. m/0.32 mm/0.25 μm, H2, 80. C @ 2. min, 4. K/min, 270. C @ 5. min

Lee's RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryDB-Wax162.99Andersson and Weis, 199430. m/0.2 mm/0.15 μm, H2, 80. C @ 2. min, 4. K/min, 270. C @ 5. min

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Radchenko and Kataigorodskii, 1974
Radchenko, L.G.; Kataigorodskii, A.I., Zh. Fiz. Khim., 1974, 48, 2702. [all data]

Michaud, Negrier, et al., 1999
Michaud, F.; Negrier, Ph.; Mikailitchenko, D.; Marbeuf, A.; Haget, Y.; Cuevas-diarte, M.; Oonk, H.A.J., Measurement and Analysis of the Naphthalene --- Octafluoronaphthalene Phase Diagram: Complex Formation in Solid and Liquid, Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 1999, 326, 1, 409-424, https://doi.org/10.1080/10587259908025429 . [all data]

Hohlneicher, Distler, et al., 1984
Hohlneicher, G.; Distler, D.; Muller, M.; Freund, H.-J., Identification of shake-up satellites in valence photoelectron spectra of organic compounds by comparison with electronic absorption spectra of radical cations. Case study: Octafluoronaphthalene, Chem. Phys. Lett., 1984, 111, 151. [all data]

Bastide, Hall, et al., 1979
Bastide, J.; Hall, D.; Heilbronner, E.; Maier, J.P., He(Iα) photoelectron spectra of some higher aromatic perfluoro compounds, J. Electron Spectrosc. Relat. Phenom., 1979, 16, 205. [all data]

Brundle, Robin, et al., 1972
Brundle, C.R.; Robin, M.B.; Kuebler, N.A., Perfluoro effect in photoelectron spectroscopy. II. Aromatic molecules, J. Am. Chem. Soc., 1972, 94, 1466. [all data]

Jakobson, Shteingarts, et al., 1964
Jakobson, G.G.; Shteingarts, V.D.; Vorozhtsov, N.N., Jr., Synthesis of octofluoronaphthalene and dekafluorodiphenyl, Izv. Akad. Nauk SSSR, Ser. Khim., 1964, 1551-1552. [all data]

Andersson and Weis, 1994
Andersson, J.T.; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. A, 1994, 659, 1, 151-161, https://doi.org/10.1016/0021-9673(94)85017-8 . [all data]


Notes

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