Perfluorotributylamine

• Formula: C₁₂F₂₇N
• Molecular weight: 671.0920
• IUPAC Standard InChI: InChI=1S/C12F27N/c13-1(14,7(25,26)27)4(19,20)10(34,35)40(11(36,37)5(21,22)2(15,16)8(28,29)30)12(38,39)6(23,24)3(17,18)9(31,32)33 Copy

  
• IUPAC Standard InChIKey: RVZRBWKZFJCCIB-UHFFFAOYSA-N Copy
• CAS Registry Number: 311-89-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: PFTBA; 1-Butanamine, 1,1,2,2,3,3,4,4,4-nonafluoro-N,N-bis(nonafluorobutyl)-; FC 43; FC 47; Fluorinert FC 43; Fluorocarbon FC 43; Heptacosafluorotributylamine; Mediflor FC 43; Medifluor FC 47; Tributylamine, heptacosafluoro-; (n-C4F9)3N; tri(Perfluorobutyl)amine; Perfluorotri-n-butylamine; Heptacosafluorotri-n-butylamine; Butylamine, 1,1,2,2,3,3,4,4,4-nonafluoro-N,N-bis(nonafluorobutyl)-; Fluosol 43; Tri(nonafluorobutyl)amine; Tris(nonafluorobutyl)amine; Tris(perfluorobutyl)amine; 1-Butanamine, 1,1,2,2,3,3,4,4,4-nonafluoro-N,N-bis(1,1,2,2,3,3,4,4,4-nonafluorobutyl)-; NSC 3501
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• Information on this page:
  • Gas phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • IR Spectrum
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Enthalpy of vaporization

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Erastov and Kolesov, 1979
Erastov, P.A.; Kolesov, V.P., Thermodynamic properties of nitrogen-containing organofluorine compounds. Enthalpies of formation of perfluorotriethylamine and perfluorotributylamine, J. Gen. Chem. USSR (Engl. Transl.), 1979, 49, 1186-1189. [all data]

Kolesov and Kozina, 1986
Kolesov, V.P.; Kozina, M.P., Thermochemistry of organic and organohalogen compounds, Russ. Chem. Rev., 1986, 55, 912. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Kyle and Tetlow, 1960
Kyle, B.G.; Tetlow, N.J., Perfluorotributylamine as an Extractive Distillation Solvent for a Hydrocarbon Mixture, J. Chem. Eng. Data, 1960, 5, 275. [all data]

Varouchtchenko and Droujinina, 1995
Varouchtchenko, R.M.; Droujinina, A.I., Thermodynamics of vaporization of some perfluorotrialkylamines, J. Chem. Thermodyn., 1995, 27, 355-368. [all data]

Varushchenko, Ammar, et al., 1977
Varushchenko, R.M.; Ammar, M.M.; Bulgakova, L.L., Russ. J. Phys. Chem., 1977, 51, 167. [all data]

Varushchenko, Ammar, et al., 1977, 2
Varushchenko, R.M.; Ammar, M.M.; Bulgakova, L.L., Zh. Fiz. Khim., 1977, 51, 278. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Molder, Pikver, et al., 1983
Molder, U.H.; Pikver, R.J.; Koppel, I.A., Photoelectron spectra of molecules. 4. Amines, Org. React. Tartu, 1983, 20, 355. [all data]

Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R., Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect, J. Fluorine Chem., 1982, 19, 349. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Tboil	Boiling point
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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