Sulfur fluoride anion

• Formula: F₅S^-
• Molecular weight: 127.058
• CAS Registry Number: 31140-82-6
• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Ion clustering data
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(F₅S^- • F₆S^-) + F₆S^- = (F₅S^- • 2F₆S^-)

By formula: (F₅S^- • F₆S^-) + F₆S^- = (F₅S^- • 2F₆S^-)

F₅S^- +  = (F₅S^- • )

By formula: F₅S^- + H₂S = (F₅S^- • H₂S)

F₅S^- + F₆S^- = (F₅S^- • F₆S^-)

By formula: F₅S^- + F₆S^- = (F₅S^- • F₆S^-)

Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 359; Jacox, 2003, page 333

Notes

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M. Fujimaki, Gas-Phase Stability of Cluster Ions SFm+(SF6)n with m = 0-5 and n = 1-3, J. Am. Soc. Mass Spectrom., 1995, 6, 12, 1137, https://doi.org/10.1016/1044-0305(95)00583-8 . [all data]

Zangerle, Hansel, et al., 1993
Zangerle, R.; Hansel, A.; Richter, R.; Lindinger, W., The Reaction of SF5+ + H2S at Near Thermal Energies: Competition between Association and Binary Reactions, Int. J. Mass Spectrom. Ion Proc., 1993, 129, 117, https://doi.org/10.1016/0168-1176(93)87035-Q . [all data]

Lugez, Jacox, et al., 1998
Lugez, C.L.; Jacox, M.E.; King, R.A.; Schaefer, H.F., III, Experimental and ab initio study of the infrared spectra of ionic species derived from SF[sub 6] and SF[sub 4] and trapped in solid neon, J. Chem. Phys., 1998, 108, 23, 9639, https://doi.org/10.1063/1.476440 . [all data]

Smardzewski and Fox, 1977
Smardzewski, R.R.; Fox, W.B., Vacuum ultraviolet photolysis of sulfur hexafluoride and its derivatives in argon matrices. The infrared spectrum of the SF5 radical, J. Chem. Phys., 1977, 67, 5, 2309, https://doi.org/10.1063/1.435066 . [all data]

Hassanzadeh and Andrews, 1992
Hassanzadeh, P.; Andrews, L., Matrix reactions of sulfur atoms and fluorine. Infrared spectra of sulfur monofluoride, sulfur difluoride and sulfur trifluoride in solid argon, J. Phys. Chem., 1992, 96, 1, 79, https://doi.org/10.1021/j100180a018 . [all data]

Barefield and Guillory, 1977
Barefield, J.E., II; Guillory, W.A., Infrared spectroscopic evidence for matrix-isolated sulfur hexafluoride(1-) ion, J. Phys. Chem., 1977, 81, 7, 634, https://doi.org/10.1021/j100522a009 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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