1,1,2-Trimethyl-1-silacyclobutane

• Formula: C₆H₁₄Si
• Molecular weight: 114.2609
• IUPAC Standard InChI: InChI=1S/C6H14Si/c1-6-4-5-7(6,2)3/h6H,4-5H2,1-3H3 Copy

  
• IUPAC Standard InChIKey: IBURGXLWVCHMET-UHFFFAOYSA-N Copy
• CAS Registry Number: 30681-90-4
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Silacyclobutane, 1,1,2-trimethyl-; 1,1,2-Trimethylsilacyclobutane
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C₆H₁₄Si⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Voronkov, Klyuchnikov, et al., 1991
Voronkov, M.G.; Klyuchnikov, V.A.; Sokolova, E.V.; Danilova, T.F.; Shvets, G.N.; Korchagina, A.N.; Gussel'nikov, L.E.; Volkova, V.V., Thermochemistry of organosilicon compounds, Journal of Organometallic Chemistry, 1991, 401, 3, 245-248, https://doi.org/10.1016/0022-328X(91)86222-C . [all data]

Gusel'nikov, Volkova, et al., 1981
Gusel'nikov, L.E.; Volkova, V.V.; Tarasenko, N.A.; Tishenkov, A.A.; Zaikin, V.G.; Eremina, E.I.; Nametkin, N.S., Deuterium labelling and thermochemical studies of dissociative ionization of methyl substituted monosilacyclobutanes. Ring expansion in the molecular ion of 1,1,3-trimethylΣ-1-silacyclobutane, Org. Mass Spectrom., 1981, 16, 242. [all data]

Cundy, Lappert, et al., 1973
Cundy, C.S.; Lappert, M.F.; Pedley, J.B.; Schmidt, W.; Wilkins, B.T., Bonding studies of compounds of boron and the Group IV elements. XI. Photoelectron spectra of strained cyclic organosilicon compounds, J. Organomet. Chem., 1973, 51, 99. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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