Isopropyl mercuric chloride
- Formula: C3H7ClHg
- Molecular weight: 279.13
- CAS Registry Number: 30615-19-1
- Information on this page:
- Other data available:
- Options:
Condensed phase thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -170.6 ± 3.8 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -16.7 ± 6.0 kJ/mol for the enthalpy of formation of Hg(i-Pr)2(l). |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.5 ± 0.2 | PI | Nekrasov, Zagorevskii, et al., 1992 | LL |
| 9.80 ± 0.05 | PE | Baidin, Timoshenko, et al., 1985 | Vertical value; LBLHLM |
| 9.80 ± 0.05 | PE | Baidin, Chizhov, et al., 1981 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C2H4ClHg+ | >12.5 | CH3 | PI | Nekrasov, Zagorevskii, et al., 1992 | LL |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Nekrasov, Zagorevskii, et al., 1992
Nekrasov, Y.S.; Zagorevskii, D.V.; Mikeladze, M.S.,
Mass spectrometry of organomercury compounds,
Organomet. Chem. USSR, 1992, 5, 237, In original 499. [all data]
Baidin, Timoshenko, et al., 1985
Baidin, V.N.; Timoshenko, M.M.; Chizhov, Y.V.; Ustynyuk, Y.A.; Kritskaya, I.I.,
Photoelectron spectra nad the structure of organomercury compounds,
J. Organomet. Chem., 1985, 292, 55. [all data]
Baidin, Chizhov, et al., 1981
Baidin, V.N.; Chizhov, Y.V.; Timoshenko, M.M.; Sokolikova, O.K.; Grishin, Y.K.; Ustynyuk, Y.A.,
The photoelectron spectra of alkylmercury chlorides,
J. Struct. Chem., 1981, 22, 616, In original 164. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.