Tetracyclo[5.2.1.02,6.03,5]dec-8-ene


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2Hydrogen + Tetracyclo[5.2.1.0(2,6).0(3,5)]dec-8-ene = endo-Ttricyclo[5.2.1.0(2,6)]decane

By formula: 2H2 + C10H12 = C10H16

Quantity Value Units Method Reference Comment
Δr-363. ± 1.kJ/molChydRoth, Klarner, et al., 1980liquid phase; solvent: Cyclohexane

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C10H12+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.83 ± 0.03PEMartin, Kagabu, et al., 1974Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roth, Klarner, et al., 1980
Roth, W.R.; Klarner, F.-G.; Lennartz, H.-W., Heats of hydrogenation. II. Heat of hydrogenation of bicyclo[2.1.0]pent-2-ene, an antiaromatic system, Chem. Ber., 1980, 113, 1806-1818. [all data]

Martin, Kagabu, et al., 1974
Martin, H.-D.; Kagabu, S.; Schwesinger, R., Photoelektronenspektroskopische untersuchung der intramolekularen π,π-wechselwirkungen in endo-tricyclo[4.2.1.02,5]- nonadienen. Homokonjugation mit cyclobutanen, Chem. Ber., 1974, 107, 3130. [all data]


Notes

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