2-Methylene-bicyclo[2.2.2]-octane
- Formula: C9H14
- Molecular weight: 122.2075
- IUPAC Standard InChI: InChI=1S/C9H14/c1-7-6-8-2-4-9(7)5-3-8/h8-9H,1-6H2
- IUPAC Standard InChIKey: BOXGGSPOSRTPTH-UHFFFAOYSA-N
- CAS Registry Number: 2972-20-5
- Chemical structure:
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -13.01 ± 0.59 | kcal/mol | Cm | Kozina, Bychikhina, et al., 1974 | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -1311.66 ± 0.58 | kcal/mol | Cm | Kozina, Bychikhina, et al., 1974 | Corresponding ΔfHºliquid = -13.01 kcal/mol (simple calculation by NIST; no Washburn corrections) |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.87 | PE | Asmus and Klessinger, 1974 | Vertical value; LLK |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kozina, Bychikhina, et al., 1974
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L.; Kalinichenko, A.N.; Bobyleva, A.A.; Belikova, N.A.; Plate, A.F.,
Enthalpies of combustion and formation of 2-methylenebicyclo-[2,2,2]octane and 2-methylbicylo-[2,2,2]oct-2-ene,
Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 1226-1227. [all data]
Asmus and Klessinger, 1974
Asmus, P.; Klessinger, M.,
Photoelectron spectra of organic compounds. VI. Exocyclic methylene compounds,
Tetrahedron, 1974, 30, 2477. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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