Stannane, tetrakis(1-methylethyl)-
- Formula: C12H28Sn
- Molecular weight: 291.061
- IUPAC Standard InChI: InChI=1S/4C3H7.Sn/c4*1-3-2;/h4*3H,1-2H3;
- IUPAC Standard InChIKey: NJASUIDIZMMYED-UHFFFAOYSA-N
- CAS Registry Number: 2949-42-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraisopropyltin; Stannane, tetraisopropyl-; Tetraisopropylstannane; (iso-C3H7)4Sn; tetra-i-Propyltin
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -119.6 ± 7.1 | kJ/mol | Review | Martinho Simões | Selected data |
| ΔfH°gas | -140.1 ± 5.9 | kJ/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -184.5 ± 5.7 | kJ/mol | Review | Martinho Simões | Selected data |
| ΔfH°liquid | -205.0 ± 4.2 | kJ/mol | Review | Martinho Simões | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -9116.9 ± 5.4 | kJ/mol | CC-SB | Coleman and Skinner, 1966 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. |
| ΔcH°liquid | -9096.4 ± 3.8 | kJ/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Cox and Pilcher, 1970. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 64.9 ± 4.2 | kJ/mol | CC-SB | Coleman and Skinner, 1966 | MS |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 48.0 ± 0.7 | 392. | N/A | Baev, 2001 | Based on data from 342. to 441. K.; AC |
| 56.4 | 333. to 393. | GC | Hawker, 1992 | AC |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.46 | PE | Kochi, 1980 | Vertical value; LLK |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Coleman and Skinner, 1966
Coleman, D.J.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 15.?Heats of combustion of trimethyl-isopropyl tin, trimethyl-t-butyl tin and tetra-isopropyl tin,
Trans. Faraday Soc., 1966, 62, 1721, https://doi.org/10.1039/tf9666201721
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Baev, 2001
Baev, A.K.,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]
Hawker, 1992
Hawker, Darryl,
Equilibrium vapour pressures of tetraorganostannanes,
Chemosphere, 1992, 25, 4, 427-436, https://doi.org/10.1016/0045-6535(92)90276-W
. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Notes
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- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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