Carbon monosulfide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas67.000kcal/molReviewChase, 1998Data last reviewed in December, 1976
Quantity Value Units Method Reference Comment
gas,1 bar50.323cal/mol*KReviewChase, 1998Data last reviewed in December, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. to 600.600. to 6000.
A 5.2016908.240251
B 5.9748810.708952
C -1.934891-0.227228
D -1.0908100.027179
E 0.030204-0.238404
F 65.3042163.82110
G 55.1027059.05189
H 67.0001067.00010
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1976 Data last reviewed in December, 1976

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) • Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ • CS)

Quantity Value Units Method Reference Comment
Δr49.5 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000 
Δr55.2 ± 2.8kcal/molCIDTSchroeder, Kretzschmar, et al., 1999 

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) • Carbon monosulfide)

By formula: Co+ + CS = (Co+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001 
Δr57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Chromium ion (1+) + Carbon monosulfide = (Chromium ion (1+) • Carbon monosulfide)

By formula: Cr+ + CS = (Cr+ • CS)

Quantity Value Units Method Reference Comment
Δr38.9 ± 1.4kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr37.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) • Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ • CS)

Quantity Value Units Method Reference Comment
Δr19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Molybdenum ion (1+) + Carbon monosulfide = (Molybdenum ion (1+) • Carbon monosulfide)

By formula: Mo+ + CS = (Mo+ • CS)

Quantity Value Units Method Reference Comment
Δr38.7 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003 
Δr38.7 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000 

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) • Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ • CS)

Quantity Value Units Method Reference Comment
Δr36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000 

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) • Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ • CS)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Zirconium ion (1+) + Carbon monosulfide = (Zirconium ion (1+) • Carbon monosulfide)

By formula: Zr+ + CS = (Zr+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) • Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ • CS)

Quantity Value Units Method Reference Comment
Δr36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
Δr39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) • Carbon monosulfide)

By formula: Y+ + CS = (Y+ • CS)

Quantity Value Units Method Reference Comment
Δr32.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Nickel ion (1+) + Carbon monosulfide = (Nickel ion (1+) • Carbon monosulfide)

By formula: Ni+ + CS = (Ni+ • CS)

Quantity Value Units Method Reference Comment
Δr56.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Zinc ion (1+) + Carbon monosulfide = (Zinc ion (1+) • Carbon monosulfide)

By formula: Zn+ + CS = (Zn+ • CS)

Quantity Value Units Method Reference Comment
Δr33.7 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Copper ion (1+) + Carbon monosulfide = (Copper ion (1+) • Carbon monosulfide)

By formula: Cu+ + CS = (Cu+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000 

Niobium ion (1+) + Carbon monosulfide = (Niobium ion (1+) • Carbon monosulfide)

By formula: Nb+ + CS = (Nb+ • CS)

Quantity Value Units Method Reference Comment
Δr57.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Ruthenium ion (1+) + Carbon monosulfide = (Ruthenium ion (1+) • Carbon monosulfide)

By formula: Ru+ + CS = (Ru+ • CS)

Quantity Value Units Method Reference Comment
Δr60.5 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Palladium ion (1+) + Carbon monosulfide = (Palladium ion (1+) • Carbon monosulfide)

By formula: Pd+ + CS = (Pd+ • CS)

Quantity Value Units Method Reference Comment
Δr47.8 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Rh+ + Carbon monosulfide = (Rh+ • Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to CS+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)11.33 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)189.2kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity182.kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Δf(+) ion327.kcal/molN/AN/A 
Quantity Value Units Method Reference Comment
ΔfH(+) ion,0K324.kcal/molN/AN/A 

Electron affinity determinations

EA (eV) Method Reference Comment
0.205 ± 0.021LPESBurnett, Feigerle, et al., 1982B
>1.60 ± 0.30EIAEThynne, 1972From COS; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.335EVALHuber and Herzberg, 1979LLK
11.0 ± 0.03EITal'roze, Butkovskaya, et al., 1978LLK
11.33 ± 0.01PIDrowart, Smets, et al., 1978LLK
11.4 ± 0.1EIHildenbrand, 1975LLK
11.33 ± 0.02PEKing, Kroto, et al., 1972LLK
11.33 ± 0.01PEJonathan, Morris, et al., 1972LLK
11.33 ± 0.02PEJonathan, Morris, et al., 1972, 2LLK
11.39 ± 0.10EIHildenbrand, 1972LLK
11.34 ± 0.02PEFrost, Lee, et al., 1972LLK
~11.65SDonovan, Husain, et al., 1970RDSH
11.71 ± 0.03DERDibeler and Walker, 1967RDSH
11.8 ± 0.2EIBlanchard and LeGoff, 1957RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) • Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ • CS)

Quantity Value Units Method Reference Comment
Δr36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) • Carbon monosulfide)

By formula: Co+ + CS = (Co+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001 
Δr57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Chromium ion (1+) + Carbon monosulfide = (Chromium ion (1+) • Carbon monosulfide)

By formula: Cr+ + CS = (Cr+ • CS)

Quantity Value Units Method Reference Comment
Δr38.9 ± 1.4kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr37.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Copper ion (1+) + Carbon monosulfide = (Copper ion (1+) • Carbon monosulfide)

By formula: Cu+ + CS = (Cu+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000 

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) • Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ • CS)

Quantity Value Units Method Reference Comment
Δr49.5 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000 
Δr55.2 ± 2.8kcal/molCIDTSchroeder, Kretzschmar, et al., 1999 

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) • Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ • CS)

Quantity Value Units Method Reference Comment
Δr19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Molybdenum ion (1+) + Carbon monosulfide = (Molybdenum ion (1+) • Carbon monosulfide)

By formula: Mo+ + CS = (Mo+ • CS)

Quantity Value Units Method Reference Comment
Δr38.7 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003 
Δr38.7 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000 

Niobium ion (1+) + Carbon monosulfide = (Niobium ion (1+) • Carbon monosulfide)

By formula: Nb+ + CS = (Nb+ • CS)

Quantity Value Units Method Reference Comment
Δr57.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Nickel ion (1+) + Carbon monosulfide = (Nickel ion (1+) • Carbon monosulfide)

By formula: Ni+ + CS = (Ni+ • CS)

Quantity Value Units Method Reference Comment
Δr56.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Palladium ion (1+) + Carbon monosulfide = (Palladium ion (1+) • Carbon monosulfide)

By formula: Pd+ + CS = (Pd+ • CS)

Quantity Value Units Method Reference Comment
Δr47.8 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Rh+ + Carbon monosulfide = (Rh+ • Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000 

Ruthenium ion (1+) + Carbon monosulfide = (Ruthenium ion (1+) • Carbon monosulfide)

By formula: Ru+ + CS = (Ru+ • CS)

Quantity Value Units Method Reference Comment
Δr60.5 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) • Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ • CS)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) • Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ • CS)

Quantity Value Units Method Reference Comment
Δr36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000 

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
Δr39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) • Carbon monosulfide)

By formula: Y+ + CS = (Y+ • CS)

Quantity Value Units Method Reference Comment
Δr32.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Zinc ion (1+) + Carbon monosulfide = (Zinc ion (1+) • Carbon monosulfide)

By formula: Zn+ + CS = (Zn+ • CS)

Quantity Value Units Method Reference Comment
Δr33.7 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Zirconium ion (1+) + Carbon monosulfide = (Zirconium ion (1+) • Carbon monosulfide)

By formula: Zr+ + CS = (Zr+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B., On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2, Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]

Rue, Armentrout, et al., 2001, 2
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B., Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase, Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Burnett, Feigerle, et al., 1982
Burnett, S.M.; Feigerle, C.S.; Stevens, A.E.; Lineberger, C.W., Photoelectron spectroscopy of CS- and NS-, J. Phys. Chem., 1982, 86, 4486. [all data]

Thynne, 1972
Thynne, J.C.J., Negative Ion Studies with a Time-of-Flight Mass Spectrometer., Dyn. Mass Spectrom., 1972, 3, 67. [all data]

Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G., Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules,, Van Nostrand Reinhold Co., 1979, ,1. [all data]

Tal'roze, Butkovskaya, et al., 1978
Tal'roze, V.L.; Butkovskaya, N.I.; Larichev, M.N.; Leipunskii, I.O.; Morozov, I.I.; Dodonov, A.F.; Kudrov, B.V.; Zelenov, V.V.; Raznikov, V.V., Advances in the mass spectrometry of free radicals, Adv. Mass Spectrom., 1978, 7, 693. [all data]

Drowart, Smets, et al., 1978
Drowart, J.; Smets, J.; Reynaert, J.C.; Coppens, P., Mass spectrometric study of the photoionization of inorganic gases vapours, Adv. Mass Spectrom., 1978, 7, 647. [all data]

Hildenbrand, 1975
Hildenbrand, D.L., Vertical ionization potential of the CF2 radical, Chem. Phys. Lett., 1975, 32, 30. [all data]

King, Kroto, et al., 1972
King, G.H.; Kroto, H.W.; Suffolk, R.J., The photoelectron spectrum of a short-lived species in the decomposition products of CS2, Chem. Phys. Lett., 1972, 13, 457. [all data]

Jonathan, Morris, et al., 1972
Jonathan, N.; Morris, A.; Okuda, M.; Ross, K.J.; Smith, D.J., Photoelectron spectroscopy of transient species. The CS molecule, Faraday Discuss. Chem. Soc., 1972, 54, 48. [all data]

Jonathan, Morris, et al., 1972, 2
Jonathan, N.; Morris, A.; Okuda, M.; Smith, D.J.; Ross, K.J., Photoelectron spectroscopy of transient species: The CS molecule, Chem. Phys. Lett., 1972, 13, 334. [all data]

Hildenbrand, 1972
Hildenbrand, D.L., Thermochemistry of the molecules CS and CS+, Chem. Phys. Lett., 1972, 15, 379. [all data]

Frost, Lee, et al., 1972
Frost, D.C.; Lee, S.T.; McDowell, C.A., The high resolution photoelectron spectrum of CS, Chem. Phys. Lett., 1972, 17, 153. [all data]

Donovan, Husain, et al., 1970
Donovan, R.J.; Husain, D.; Stevenson, C.D., Vacuum ultra-violet spectra of transient molecules and radicals. Part 1. CS and S2, J. Chem. Soc. Faraday Trans., 1970, 66, 1. [all data]

Dibeler and Walker, 1967
Dibeler, V.H.; Walker, J.A., Mass spectrometric study of the photoionization of small polyatomic molecules, Advan. Mass Spectrom., 1967, 4, 767. [all data]

Blanchard and LeGoff, 1957
Blanchard, L.P.; LeGoff, P., Mass spectrometric study of the species CS, SO, and CCl2 produced in primary heterogeneous reactions, Can. J. Chem., 1957, 35, 89. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References