Isopropyl methyl-d3-ether
- Formula: C4H7D3O
- Molecular weight: 77.1401
- CAS Registry Number: 29366-06-1
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.49 | PI | McAdoo, Traeger, et al., 1988 | LL |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CHD2O+ | 12.9 ± 0.1 | ? | EI | Tsang and Harrison, 1970 | RDSH |
C3H4D3O+ | 9.68 | CH3 | PI | McAdoo, Traeger, et al., 1988 | LL |
C4H6D3O+ | 9.66 | CH4 | PI | McAdoo, Traeger, et al., 1988 | LL |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
McAdoo, Traeger, et al., 1988
McAdoo, D.J.; Traeger, J.C.; Hudson, C.E.; Griffin, L.L.,
Decompositions of ionized isopropryl methyl ether: Complex-mediated and direct processes in unimolecular dissociations,
J. Phys. Chem., 1988, 92, 1524. [all data]
Tsang and Harrison, 1970
Tsang, C.W.; Harrison, A.G.,
Four-centred rearrangements in the mass spectra of aliphatic ethers,
Org. Mass Spectrom., 1970, 3, 647. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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