Cyclooctane

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-126.1 ± 1.6kJ/molN/ASpitzer and Huffman, 1947Value computed using ΔfHliquid° value of -169.4±1.6 kj/mol from Spitzer and Huffman, 1947 and ΔvapH° value of 43.35±0.21 kj/mol from missing citation.; DRB
Quantity Value Units Method Reference Comment
gas366.8 ± 1.3J/mol*KN/AFinke H.L., 1956GT

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
38.6250.Dorofeeva O.V., 1986S(T) values calculated by [ Stull D.R., 1969] are in good agreement with those selected here; however, the discrepancy in Cp(298.15 K) amounts to 6.2 J/mol*K. S(T) values calculated by molecular mechanics method [ Chang S., 1970] are about 13 J/mol*K less than recommended ones; discrepancies in Cp(T) values amount to 1-2 J/mol*K.; GT
64.77100.
83.16150.
99.99200.
133.07273.15
146.2 ± 5.0298.15
147.19300.
202.16400.
253.07500.
296.64600.
333.38700.
364.46800.
390.90900.
413.471000.
432.791100.
449.361200.
463.611300.
475.901400.
486.531500.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-169.4 ± 1.6kJ/molCcbSpitzer and Huffman, 1947Reanalyzed by Cox and Pilcher, 1970, Original value = -169.9 ± 2.5 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Δcliquid-5265.7 ± 0.9kJ/molCcbKaarsemaker and Coops, 1952Corresponding Δfliquid = -169.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-5265.3 ± 1.6kJ/molCcbSpitzer and Huffman, 1947Reanalyzed by Cox and Pilcher, 1970, Original value = -5264.9 ± 1.6 kJ/mol; Corresponding Δfliquid = -169.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid262.00J/mol*KN/AFinke, Scott, et al., 1956DH
Quantity Value Units Method Reference Comment
Δcsolid-5252.6kJ/molCcbRuzieka and Schlapfer, 1933Heat of combustion corrected for pressure; Corresponding Δfsolid = -182. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
215.78298.15Shiohama, Ogawa, et al., 1988DH
215.53298.15Tanaka, 1985DH
215.461298.15Fortier, D'Arcy, et al., 1979DH
214.53298.15Wilhelm, Faradjzadeh, et al., 1979DH
214.24298.15Jolicoeur, Boileau, et al., 1975DH
215.48298.15Finke, Scott, et al., 1956T = 12 to 330 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil422. ± 6.KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus285. ± 5.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple287.94KN/AFinke, Scott, et al., 1956, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.07 K; TRC
Ttriple287.98KN/AFinke, Scott, et al., 1956, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.05 K; TRC
Ttriple287.940KN/AWaddington, 1955Uncertainty assigned by TRC = 0.05 K; date of correspondence not given on card; TRC
Ttriple287.970KN/AWaddington, 1955Uncertainty assigned by TRC = 0.02 K; date of correspondence not given on card; TRC
Ttriple288.0KN/AKaarsemaker, 1951Crystal phase 1 phase; Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tc647.2 ± 0.5KN/ADaubert, 1996 
Tc674.2KN/AYoung, 1972Uncertainty assigned by TRC = 0.6 K; TRC
Tc647.2KN/AHicks and Young, 1971Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Pc35.6 ± 0.4barN/ADaubert, 1996 
Pc35.50barN/AYoung, 1972Uncertainty assigned by TRC = 0.40 bar; TRC
Pc35.60barN/AHicks and Young, 1971Uncertainty assigned by TRC = 0.4053 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.410l/molN/ADaubert, 1996 
Vc0.411l/molN/AYoung, 1972Uncertainty assigned by TRC = 0.007 l/mol; TRC
Quantity Value Units Method Reference Comment
ρc2.44 ± 0.04mol/lN/ADaubert, 1996 
Quantity Value Units Method Reference Comment
Δvap43.35 ± 0.21kJ/molVFinke, Scott, et al., 1956, 3ALS
Δvap43.3 ± 0.2kJ/molN/AFinke, Scott, et al., 1956AC
Δvap44.7kJ/molVKaarsemaker and Coops, 1952ALS
Δvap43.5kJ/molESpitzer and Huffman, 1947ALS

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
424.20.987Aldrich Chemical Company Inc., 1990BS
421.70.999Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
40.3373.N/AWu, Locke, et al., 1991Based on data from 358. to 413. K.; AC
43.3304.AStephenson and Malanowski, 1987Based on data from 289. to 369. K.; AC
39.4384.A,EBStephenson and Malanowski, 1987Based on data from 369. to 467. K. See also Finke, Scott, et al., 1956.; AC
39.3388.EBMeyer and Hotz, 1976Based on data from 373. to 434. K.; AC
43.1306.N/AAnand, Grolier, et al., 1975Based on data from 291. to 323. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
369.86 to 467.63.988051438.687-63.024Finke, Scott, et al., 1956Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
58.7166.BBondi, 1963AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
2.41288.Acree, 1991AC

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
6.3057166.5crystaline, IIIcrystaline, IIFinke, Scott, et al., 1956DH
0.4782183.8crystaline, IIcrystaline, IFinke, Scott, et al., 1956DH
2.4096287.98crystaline, IliquidFinke, Scott, et al., 1956DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
37.87166.5crystaline, IIIcrystaline, IIFinke, Scott, et al., 1956DH
2.60183.8crystaline, IIcrystaline, IFinke, Scott, et al., 1956DH
8.37287.98crystaline, IliquidFinke, Scott, et al., 1956DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + Cyclooctene, (Z)- = Cyclooctane

By formula: H2 + C8H14 = C8H16

Quantity Value Units Method Reference Comment
Δr-102.kJ/molChydDoering, Roth, et al., 1989liquid phase
Δr-103. ± 0.8kJ/molChydRoth and Lennartz, 1980liquid phase; solvent: Cyclohexane
Δr-96.40 ± 0.71kJ/molChydRogers, Von Voithenberg, et al., 1978liquid phase; solvent: Hexane
Δr-96.1 ± 0.4kJ/molChydTurner and Meador, 1957liquid phase; solvent: Acetic acid
Δr-97.40 ± 0.63kJ/molChydConn, Kistiakowsky, et al., 1939gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -98.4 ± 0.2 kJ/mol; At 355 K

Hydrogen + trans-Cyclooctene = Cyclooctane

By formula: H2 + C8H14 = C8H16

Quantity Value Units Method Reference Comment
Δr-144. ± 0.4kJ/molChydRoth, Adamczak, et al., 1991liquid phase; see Doering, Roth, et al., 1989
Δr-144.0 ± 1.8kJ/molChydRogers, Von Voithenberg, et al., 1978liquid phase; solvent: Hexane
Δr-134.9 ± 0.88kJ/molChydTurner and Meador, 1957liquid phase; solvent: Acetic acid

3Hydrogen + 1,3,5-Cyclooctatriene = Cyclooctane

By formula: 3H2 + C8H10 = C8H16

Quantity Value Units Method Reference Comment
Δr-319.6 ± 1.8kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Acetic acid
Δr-302.8 ± 1.1kJ/molChydTurner, Meador, et al., 1957liquid phase; solvent: Acetic acid

2Hydrogen + Cyclooctyne = Cyclooctane

By formula: 2H2 + C8H12 = C8H16

Quantity Value Units Method Reference Comment
Δr-291. ± 0.8kJ/molChydRoth, Hopf, et al., 1994liquid phase; solvent: Isooctane
Δr-289.kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid

1,5-Cyclooctadiene + 2Hydrogen = Cyclooctane

By formula: C8H12 + 2H2 = C8H16

Quantity Value Units Method Reference Comment
Δr-230. ± 0.4kJ/molChydRoth, Adamczak, et al., 1991liquid phase
Δr-224.6 ± 0.08kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

2Hydrogen + 1,3-Cyclooctadiene, (Z,Z)- = Cyclooctane

By formula: 2H2 + C8H12 = C8H16

Quantity Value Units Method Reference Comment
Δr-208.kJ/molChydRoth, Adamczak, et al., 1991liquid phase
Δr-204.8 ± 0.3kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

1,4-Cyclooctadiene + 2Hydrogen = Cyclooctane

By formula: C8H12 + 2H2 = C8H16

Quantity Value Units Method Reference Comment
Δr-217.9 ± 1.2kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

3Hydrogen + 1,3,6-Cyclooctatriene = Cyclooctane

By formula: 3H2 + C8H10 = C8H16

Quantity Value Units Method Reference Comment
Δr-334.3 ± 0.71kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

4Hydrogen + 1,3,5,7-Cyclooctatetraene = Cyclooctane

By formula: 4H2 + C8H8 = C8H16

Quantity Value Units Method Reference Comment
Δr-409.9 ± 0.2kJ/molChydTurner, Meador, et al., 1957liquid phase; solvent: Acetic acid

4Hydrogen + 1,5-Cyclooctadiyne = Cyclooctane

By formula: 4H2 + C8H8 = C8H16

Quantity Value Units Method Reference Comment
Δr640. ± 1.kJ/molChydRoth, Hopf, et al., 1994liquid phase; solvent: Isooctane

Hydrogen + Cyclooctene = Cyclooctane

By formula: H2 + C8H14 = C8H16

Quantity Value Units Method Reference Comment
Δr-94. ± 1.kJ/molChydRogers and McLafferty, 1971liquid phase; solvent: Acetic acid

2Hydrogen + 1,5-Cyclooctadiene, (E,E)- = Cyclooctane

By formula: 2H2 + C8H12 = C8H16

Quantity Value Units Method Reference Comment
Δr-320. ± 0.4kJ/molChydRoth, Adamczak, et al., 1991liquid phase

2Hydrogen + (Z,E)-1,3-Cyclooctadiene = Cyclooctane

By formula: 2H2 + C8H12 = C8H16

Quantity Value Units Method Reference Comment
Δr-271. ± 0.4kJ/molChydRoth, Adamczak, et al., 1991liquid phase

2Hydrogen + 1,5-Cyclooctadiene, (E,Z)- = Cyclooctane

By formula: 2H2 + C8H12 = C8H16

Quantity Value Units Method Reference Comment
Δr-282. ± 0.4kJ/molChydRoth, Adamczak, et al., 1991liquid phase

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
0.0098 QN/ASeveral references are given in the list of Henry's law constants but not assigned to specific species.
0.0095 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
IE (evaluated)9.75 ± 0.04eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.82 ± 0.05EIHolmes and Lossing, 1991LL
9.75EQSieck and Mautner(Meot-Ner), 1982LBLHLM
9.74 ± 0.05PIGolubitskii, Kulikov, et al., 1979LLK
10.08 ± 0.05EIPuttemans, 1974LLK
9.80PEPuttemans, 1974LLK
9.7PEBatich, Bischof, et al., 1973LLK

IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 826
NIST MS number 228916

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Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedC78, Branched paraffin130.965.8Dallos, Sisak, et al., 2000He; Column length: 3.3 m
PackedC78, Branched paraffin130.963.9Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
CapillaryHP-160.911.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryHP-160.912.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryHP-1100.928.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryHP-1100.929.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
PackedApolane130.965.Dutoit, 1991Column length: 3.7 m
CapillaryOV-1100.927.2Engewald, Billing, et al., 1987Column length: 50. m; Column diameter: 0.3 mm
CapillarySE-30130.941.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillarySE-3080.920.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillarySqualane86.928.5Nabivach and Kirilenko, 1979N2; Column length: 50. m
CapillarySqualane42.5908.Engewald, Epsch, et al., 1974N2; Column length: 100. m; Column diameter: 0.23 mm
CapillarySqualane80.925.Engewald, Epsch, et al., 1974N2; Column length: 100. m; Column diameter: 0.23 mm
CapillarySqualane100.933.Besson and Gäumann, 1973Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L100.957.Besson and Gäumann, 1973Column length: 50. m; Column diameter: 0.25 mm
CapillarySqualane120.927.Agrawal, Tesarík, et al., 1972N2, Celite 545; Column length: 50. m; Column diameter: 0.3 mm
CapillarySqualane86.925.Agrawal, Tesarík, et al., 1972N2, Celite 545; Column length: 50. m; Column diameter: 0.3 mm
CapillaryVacuum Grease Oil (VM-4)35.916.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)45.920.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)50.923.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)58.926.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)68.930.Sidorov, Petrova, et al., 1972 
PackedSqualane49.912.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane67.920.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane86.928.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
CapillarySqualane100.934.Schomburg, 1967Ar; Column length: 100. m
CapillarySqualane120.946.Schomburg, 1966 
CapillarySqualane70.920.Schomburg, 1966 
CapillarySqualane80.925.Schomburg, 1966 
PackedSqualane150.946.Schomburg, 1964 

Kovats' RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryApiezon L948.Louis, 1971N2, 1. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 60. C

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPetrocol DH911.White, Hackett, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
PackedSE-30932.Buchman, Cao, et al., 1984He, Chromosorb AW, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-1910.Peng, 200015. m/0.53 mm/1. μm, He; Program: 40C(3min) => 8C/min => 200(1min) => 5C/min => 300C(25min)
PackedSE-30932.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)
PackedSE-30932.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryDB-Wax1036.Peng, 200015. m/0.53 mm/1. μm, He, 40. C @ 3. min, 5. K/min, 220. C @ 30. min
CapillaryHP-Wax1023.Peng, 200015. m/0.53 mm/1. μm, He, 40. C @ 3. min, 5. K/min, 220. C @ 30. min
PackedCarbowax 20M1043.Buchman, Cao, et al., 1984He, Supelcoport, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPetrocol DH918.Supelco, 2012100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySqualane920.Chen, 2008Program: not specified
PackedSE-30947.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m; Program: 50C910min) => 20C/min => 90(6min) => 10C/min => 150C(hold)
PackedSqualane927.Robinson and Odell, 1971N2, Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min => 35 => 4C/min => 95C(hold)
PackedSE-30947.Robinson and Odell, 1971, 2Chrom W; Column length: 6.1 m; Program: 50C(10min) => 20C/min(2min) => 90C(6min) => 10C/min(6min) => (hold at 150C)

Normal alkane RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-Wax1014.Peng, Yang, et al., 1991Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Spitzer and Huffman, 1947
Spitzer, R.; Huffman, H.M., The heats of combustion of cyclopentane, cyclohexane, cycloheptane and cyclooctane, J. Am. Chem. Soc., 1947, 69, 211-213. [all data]

Finke H.L., 1956
Finke H.L., Cycloheptane, cyclooctane, and 1,3,5-cycloheptatriene. Low-temperature thermal properties, vapor pressure, and derived chemical thermodynamic properties, J. Am. Chem. Soc., 1956, 78, 5469-5476. [all data]

Dorofeeva O.V., 1986
Dorofeeva O.V., Thermodynamic properties of twenty-one monocyclic hydrocarbons, J. Phys. Chem. Ref. Data, 1986, 15, 437-464. [all data]

Stull D.R., 1969
Stull D.R., Jr., The Chemical Thermodynamics of Organic Compounds. Wiley, New York, 1969. [all data]

Chang S., 1970
Chang S., The heats of combustion and strain energies of bicyclo[n.m.0]alkanes, J. Am. Chem. Soc., 1970, 92, 3109-3118. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Kaarsemaker and Coops, 1952
Kaarsemaker, S.; Coops, J., Thermal quantities of some cycloparaffins. Part III. Results of measurements, Rec. Trav. Chim. Pays/Bas, 1952, 71, 261. [all data]

Finke, Scott, et al., 1956
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Notes

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