1,3,5-Trithiane

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Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub93.2 ± 0.2kJ/molMERoux, Jiménez, et al., 2001 
Δsub93.9kJ/molN/ADe Wit, Van Miltenburg, et al., 1983 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
91.5331.TE,MEDe Wit, Van Miltenburg, et al., 1983Based on data from 320. to 339. K.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference
32.2488.4van Miltenburg and van Ekeren, 2002

Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.7PEBock, Schulz, et al., 1981LLK
8.58PEBock, Schulz, et al., 1981Vertical value; LLK
8.83 ± 0.05PEKroto, Landsberg, et al., 1974Vertical value; LLK
8.76PESweigart and Turner, 1972Vertical value; LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-6848
NIST MS number 236249

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roux, Jiménez, et al., 2001
Roux, María Victoria; Jiménez, Pilar; Dávalos, Juan Z.; Notario, Rafael; Juaristi, Eusebio, Calorimetric and Computational Study of 1,3,5-Trithiane «8224», J. Org. Chem., 2001, 66, 16, 5343-5351, https://doi.org/10.1021/jo001757b . [all data]

De Wit, Van Miltenburg, et al., 1983
De Wit, H.G.M.; Van Miltenburg, J.C.; De Kruif, C.G., Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen, and sulphur 1. Vapour pressures and enthalpies of sublimation, The Journal of Chemical Thermodynamics, 1983, 15, 7, 651-663, https://doi.org/10.1016/0021-9614(83)90079-4 . [all data]

van Miltenburg and van Ekeren, 2002
van Miltenburg, J.C.; van Ekeren, P.J., Thermodynamic properties of 1,3,5-trithiane derived from solid phase heat capacity measurements by adiabatic calorimetry and DSC measurements in the melting range, Thermochimica Acta, 2002, 385, 1-2, 11-17, https://doi.org/10.1016/S0040-6031(01)00719-5 . [all data]

Bock, Schulz, et al., 1981
Bock, H.; Schulz, W.; Schmidt, M., P. E. spektren und molekuleigenschaften. 89. Ionissationsmuster und konformation von Cyclo-Polythianen (H2CS)n, Z. Anorg. Allg. Chem., 1981, 474, 199. [all data]

Kroto, Landsberg, et al., 1974
Kroto, H.W.; Landsberg, B.M.; Suffolk, R.J.; Vodden, A., The photoelectron and microwave spectra of the unstable species thioacetaldehyde, CH3CHS, and thioacetone, (CH3)2CS, Chem. Phys. Lett., 1974, 29, 265. [all data]

Sweigart and Turner, 1972
Sweigart, D.A.; Turner, D.W., Lone pair orbitals and their interactions studied by photoelectron spectroscopy. II. Equivalent orbitals in saturated oxygen and sulfur J. Heterocycl. Chem., J. Am. Chem. Soc., 1972, 94, 5599. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References