Tricyclo[8.2.2.24,7]-hexadecane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-152. ± 13.kJ/molCcbShieh, McNally, et al., 1969Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -153. ± 15. kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-244. ± 13.kJ/molCcbShieh, McNally, et al., 1969 
Quantity Value Units Method Reference Comment
Δcsolid-10054. ± 13.kJ/molCcbShieh, McNally, et al., 1969Corresponding Δfsolid = -244. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub92. ± 2.kJ/molVShieh, McNally, et al., 1969ALS
Δsub92.0kJ/molN/AShieh, McNally, et al., 1969DRB

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
85.2327.N/AStephenson and Malanowski, 1987Based on data from 316. to 338. K.; AC
91.6 ± 0.9327.MEShieh, McNally, et al., 1969Based on data from 316. to 338. K. See also Pedley and Rylance, 1977.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
9.1PEGleiter, Spanget-Larsen, et al., 1984LBLHLM
9.4PEGleiter, Spanget-Larsen, et al., 1984Vertical value; LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shieh, McNally, et al., 1969
Shieh, C.; McNally, D.; Boyd, R.H., The heats of combustion and strain energies of some cyclophanes, Tetrahedron, 1969, 3653-3665. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]

Gleiter, Spanget-Larsen, et al., 1984
Gleiter, R.; Spanget-Larsen, J.; Hopf, H.; Mlynek, C., Photoelectron spectra of some reduction products of [2.2]paracyclophane, Chem. Ber., 1984, 117, 1987. [all data]


Notes

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