H3+
- Formula: H3+
- Molecular weight: 3.02327
- CAS Registry Number: 28132-48-1
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1' | 1 | Ring breathing | 3178.18 | gas | IR LD | Majewski, Marshall, et al., 1987 Lembo, Petit, et al., 1989 Ketterle, Messmer, et al., 1989 Xu, Rosslein, et al., 1992 Majewski, McKellar, et al., 1994 | |
| e' | 2 | Deformation | 2521.42 | gas | LD | Oka, 1980 Watson, Foster, et al., 1984 Nakanaga, Ito, et al., 1990 Majewski, McKellar, et al., 1994 McKellar and Watson, 1998 | |
| 2 | Deformation | 2521.42 | gas | EM | Civis, Kubat, et al., 2006 | ||
| 2 | Deformation | 2109.7 | T | H2 | IR | Chan, Okumura, et al., 2000 | |
Additional references: Jacox, 1994, page 11; Jacox, 1998, page 123; Jacox, 2003, page 9; Shy, Farley, et al., 1980; Amano and Watson, 1984; Lubic and Amano, 1984; Amano, 1985; Foster, McKellar, et al., 1986; Foster, McKellar, et al., 1986, 2; Watson, Foster, et al., 1987; Kozin, Polyansky, et al., 1988; Polyansky and McKellar, 1990; Bawendi, Rehfuss, et al., 1990; Xu, Gabrys, et al., 1990; Lee, Ventrudo, et al., 1991; Ventrudo, Cassidy, et al., 1994; Amano, Chan, et al., 1994; Amano and Hirao, 2005
Notes
| T | Tentative assignment or approximate value |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Majewski, Marshall, et al., 1987
Majewski, W.A.; Marshall, M.D.; McKellar, A.R.W.; Johns, J.W.C.; Watson, J.K.G.,
Higher rotational lines in the ν2 fundamental of the H3+ molecular ion,
J. Mol. Spectrosc., 1987, 122, 2, 341, https://doi.org/10.1016/0022-2852(87)90009-9
. [all data]
Lembo, Petit, et al., 1989
Lembo, L.J.; Petit, A.; Helm, H.,
Vibrational autoionization in H_{3} and measurements of the symmetric-stretch frequency of the metastable 2p A_{2}^{''} state,
Phys. Rev. A, 1989, 39, 7, 3721, https://doi.org/10.1103/PhysRevA.39.3721
. [all data]
Ketterle, Messmer, et al., 1989
Ketterle, W.; Messmer, H.-P.; Walther, H.,
The ν,
Europhys. Lett., 1989, 8, 4, 333, https://doi.org/10.1209/0295-5075/8/4/006
. [all data]
Xu, Rosslein, et al., 1992
Xu, L.-W.; Rosslein, M.; Gabrys, C.M.; Oka, T.,
Observation of infrared forbidden transitions of H3+,
J. Mol. Spectrosc., 1992, 153, 1-2, 726, https://doi.org/10.1016/0022-2852(92)90507-K
. [all data]
Majewski, McKellar, et al., 1994
Majewski, W.A.; McKellar, A.R.W.; Sadovskii, D.; Watson, J.K.G.,
New observations and analysis of the infrared vibration--rotation spectrum of H,
Can. J. Phys., 1994, 72, 11-12, 1016, https://doi.org/10.1139/p94-133
. [all data]
Oka, 1980
Oka, T.,
Observation of the Infrared Spectrum of H_{3}^{+},
Phys. Rev. Lett., 1980, 45, 7, 531, https://doi.org/10.1103/PhysRevLett.45.531
. [all data]
Watson, Foster, et al., 1984
Watson, J.K.G.; Foster, S.C.; McKellar, A.R.W.; Bernath, P.; Amano, T.; Pan, F.S.; Crofton, M.W.; Altman, R.S.; Oka, T.,
The infrared spectrum of the ν,
Can. J. Phys., 1984, 62, 12, 1875, https://doi.org/10.1139/p84-231
. [all data]
Nakanaga, Ito, et al., 1990
Nakanaga, T.; Ito, F.; Sugawara, K.; Takeo, H.; Matsumura, C.,
Observation of infrared absorption spectra of molecular ions, H3+ and HN2+, by FTIR spectroscopy,
Chem. Phys. Lett., 1990, 169, 3, 269, https://doi.org/10.1016/0009-2614(90)85199-M
. [all data]
McKellar and Watson, 1998
McKellar, A.R.W.; Watson, J.K.G.,
The Infrared Spectrum of H+3Revealed,
J. Mol. Spectrosc., 1998, 191, 1, 215, https://doi.org/10.1006/jmsp.1998.7613
. [all data]
Civis, Kubat, et al., 2006
Civis, S.; Kubat, P.; Nishida, S.; Kawaguchi, K.,
Time-resolved Fourier transform infrared emission spectroscopy of molecular ion,
Chem. Phys Lett., 2006, 418, 4-6, 448, https://doi.org/10.1016/j.cplett.2005.10.136
. [all data]
Chan, Okumura, et al., 2000
Chan, M.-C.; Okumura, M.; Oka, T.,
Infrared Spectrum of,
J. Phys. Chem. A, 2000, 104, 16, 3775, https://doi.org/10.1021/jp993890h
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Shy, Farley, et al., 1980
Shy, J.-T.; Farley, J.W.; Lamb, W.E., Jr.; Wing, W.H.,
Observation of the Infrared Spectrum of the Triatomic Deuterium Molecular Ion D_{3}^{+},
Phys. Rev. Lett., 1980, 45, 7, 535, https://doi.org/10.1103/PhysRevLett.45.535
. [all data]
Amano and Watson, 1984
Amano, T.; Watson, J.K.G.,
Observation of the ν1 fundamental band of H2D+,
J. Chem. Phys., 1984, 81, 7, 2869, https://doi.org/10.1063/1.448059
. [all data]
Lubic and Amano, 1984
Lubic, K.G.; Amano, T.,
Observation of the ν,
Can. J. Phys., 1984, 62, 12, 1886, https://doi.org/10.1139/p84-232
. [all data]
Amano, 1985
Amano, T.,
Difference-frequency laser spectroscopy of molecular ions with a hollow-cathode cell: extended analysis of the ν_1 band of H_2D^+,
J. Opt. Soc. Am. B, 1985, 2, 5, 790, https://doi.org/10.1364/JOSAB.2.000790
. [all data]
Foster, McKellar, et al., 1986
Foster, S.C.; McKellar, A.R.W.; Peterkin, I.R.; Watson, J.K.G.; Pan, F.S.; Crofton, M.W.; Altman, R.S.; Oka, T.,
Observation and analysis of the ν2 and ν3 fundamental bands of the H2D+ ion,
J. Chem. Phys., 1986, 84, 1, 91, https://doi.org/10.1063/1.450137
. [all data]
Foster, McKellar, et al., 1986, 2
Foster, S.C.; McKellar, A.R.W.; Watson, J.K.G.,
Observation and analysis of the ν2 and ν3 fundamental bands of the D2H+ ion,
J. Chem. Phys., 1986, 85, 2, 664, https://doi.org/10.1063/1.451841
. [all data]
Watson, Foster, et al., 1987
Watson, J.K.G.; Foster, S.C.; McKellar, A.R.W.,
The infrared spectrum of the ν,
Can. J. Phys., 1987, 65, 1, 38, https://doi.org/10.1139/p87-008
. [all data]
Kozin, Polyansky, et al., 1988
Kozin, I.N.; Polyansky, O.L.; Zobov, N.F.,
Improved analysis of the experimental data on the H2D+ and D2H+ absorption spectra,
J. Mol. Spectrosc., 1988, 128, 1, 126, https://doi.org/10.1016/0022-2852(88)90212-3
. [all data]
Polyansky and McKellar, 1990
Polyansky, O.L.; McKellar, A.R.W.,
Improved analysis of the infrared spectrum of D2H+,
J. Chem. Phys., 1990, 92, 7, 4039, https://doi.org/10.1063/1.457817
. [all data]
Bawendi, Rehfuss, et al., 1990
Bawendi, M.G.; Rehfuss, B.D.; Oka, T.,
Laboratory observation of hot bands of H+3,
J. Chem. Phys., 1990, 93, 9, 6200, https://doi.org/10.1063/1.458989
. [all data]
Xu, Gabrys, et al., 1990
Xu, L.-W.; Gabrys, C.; Oka, T.,
Observation of the 2ν2(l=2)←0 overtone band of H+3,
J. Chem. Phys., 1990, 93, 9, 6210, https://doi.org/10.1063/1.458990
. [all data]
Lee, Ventrudo, et al., 1991
Lee, S.S.; Ventrudo, B.F.; Cassidy, D.T.; Oka, T.; Miller, S.; Tennyson, J.,
Observation of the 3ν2 ← 0 overtone band of H3+,
J. Mol. Spectrosc., 1991, 145, 1, 222, https://doi.org/10.1016/0022-2852(91)90365-H
. [all data]
Ventrudo, Cassidy, et al., 1994
Ventrudo, B.F.; Cassidy, D.T.; Guo, Z.Y.; Joo, S.; Lee, S.S.; Oka, T.,
Near infrared 3ν2 overtone band of H+3,
J. Chem. Phys., 1994, 100, 9, 6162, https://doi.org/10.1063/1.467088
. [all data]
Amano, Chan, et al., 1994
Amano, T.; Chan, M.-C.; Civis, S.; McKellar, A.R.W.; Majewski, W.A.; Sadovskii, D.; Watson, J.K.G.,
The infrared vibration--rotation spectrum of the molecular ion: extension to higher vibrational and rotational quantum numbers,
Can. J. Phys., 1994, 72, 11-12, 1007, https://doi.org/10.1139/p94-132
. [all data]
Amano and Hirao, 2005
Amano, T.; Hirao, T.,
Accurate rest frequencies of submillimeter-wave lines of H2D+ and D2H+,
J. Mol. Spectrosc., 2005, 233, 1, 7, https://doi.org/10.1016/j.jms.2005.05.008
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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