Azulene
- Formula: C10H8
- Molecular weight: 128.1705
- IUPAC Standard InChIKey: CUFNKYGDVFVPHO-UHFFFAOYSA-N
- CAS Registry Number: 275-51-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Bicyclo[5.3.0]decapentaene; Cyclopentacycloheptene; Azunamic; Bicyclo(5.3.0)-1,3,5,7,9-decapentaene; Bicyclo(0.3.5)deca-1,3,5,7,9-pentaene; BICYCLO(5.3.0)-DECA-2,4,6,8,10-PENTAENE; Azusalen [as sodium sulfonate]
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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
ΔsubH° (kJ/mol) | Method | Reference | Comment |
---|---|---|---|
72.7 | CGC-DSC | Chickos, Hesse, et al., 1998 | AC |
82.9 | H | Stephenson and Malanowski, 1987 | See also Chickos, Hosseini, et al., 1993.; AC |
75.3 | H | Stephenson and Malanowski, 1987 | See also Chickos, Hosseini, et al., 1993.; AC |
76.8 ± 0.2 | V | Morawetz, 1972 | ALS |
95.4 ± 0.4 | ME | Bauder and G«65533»nthard, 1962 | Based on data from 293. to 323. K. See also Cox and Pilcher, 1970.; AC |
95.48 ± 0.42 | V | Bauder and Gunthard, 1962 | ALS |
68.0 | N/A | Kovats, Gunthard, et al., 1957 | DRB |
References
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chickos, Hesse, et al., 1998
Chickos, James; Hesse, Donald; Hosseini, Sarah; Nichols, Gary; Webb, Paul,
Sublimation enthalpies at 298.15K using correlation gas chromatography and differential scanning calorimetry measurements,
Thermochimica Acta, 1998, 313, 2, 101-110, https://doi.org/10.1016/S0040-6031(97)00432-2
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Chickos, Hosseini, et al., 1993
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G.; Liebman, Joel F.,
Heat capacity corrections to a standard state: a comparison of new and some literature methods for organic liquids and solids,
Struct Chem, 1993, 4, 4, 271-278, https://doi.org/10.1007/BF00673701
. [all data]
Morawetz, 1972
Morawetz, E.,
Enthalpies of vaporization for a number of aromatic compounds,
J. Chem. Thermodyn., 1972, 4, 455. [all data]
Bauder and G«65533»nthard, 1962
Bauder, A.; G«65533»nthard, Hs.H.,
Dampfdruck von Azulen,
Helv. Chim. Acta, 1962, 45, 5, 1698-1702, https://doi.org/10.1002/hlca.19620450536
. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]
Bauder and Gunthard, 1962
Bauder, A.; Gunthard, H.Hs.,
196. Dampfdruck von azulen,
Helv. Chim. Acta, 1962, 62, 1698. [all data]
Kovats, Gunthard, et al., 1957
Kovats, E.; Gunthard, H.; Plattner, A.,
Die tabellen 4 und 5 enthalten numerische fehler und lanten richtig,
Helv. Chim. Acta, 1957, 40, 000. [all data]
Notes
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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