1,2,3-Metheno-1H-cycloprop[cd]indene,2,2a,2b,3,5a,5b-hexahydro-
- Formula: C10H10
- Molecular weight: 130.1864
- IUPAC Standard InChIKey: LMCKJCBKGXLUDT-UHFFFAOYSA-N
- CAS Registry Number: 26934-61-2
- Chemical structure:
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 244.2 ± 3.3 | kJ/mol | Ccb | Luk'yanova, Timofeeva, et al., 1991 | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -5608.4 ± 3.0 | kJ/mol | Ccb | Luk'yanova, Timofeeva, et al., 1991 | Corresponding ΔfHºsolid = 244.2 kJ/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 58.7 ± 0.4 | kJ/mol | GS | Verevkin, Kümmerlin, et al., 2002 | Based on data from 274. to 313. K. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
58.9 ± 0.4 | 294. | GS | Verevkin, Kümmerlin, et al., 2002 | Based on data from 274. to 313. K. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference |
---|---|---|---|
7.87 | 334. | DSC | Verevkin, Kümmerlin, et al., 2002 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C10H10+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.8 ± 0.2 | PE | Martin, Heller, et al., 1974 | Vertical value |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Luk'yanova, Timofeeva, et al., 1991
Luk'yanova, V.A.; Timofeeva, L.P.; Kozina, M.P.; Kirin, V.N.; Tarakanova, A.V.,
Enthalpies of formation of certain unsaturated cyclic hydrocarbons,
Russ. J. Phys. Chem. (Engl. Transl.), 1991, 65, 439-441. [all data]
Verevkin, Kümmerlin, et al., 2002
Verevkin, Sergei P.; Kümmerlin, Martin; Hickl, Ernst; Beckhaus, Hans-Dieter; Rüchardt, Christoph; Kozhushkov, Sergei I.; Haag, Rainer; Boese, Roland; Benet-Bucholz, Jordi; Nordhoff, Karsten; Meijere, Armin de,
Thermochemical and X-ray Crystallographic Investigations of Some (CH)10 Hydrocarbons: Basketene, Nenitzescu's Hydrocarbon, and Snoutene,
Eur. J. Org. Chem., 2002, 2002, 14, 2280-262, https://doi.org/10.1002/1099-0690(200207)2002:14<2280::AID-EJOC2280>3.0.CO;2-R
. [all data]
Martin, Heller, et al., 1974
Martin, H.-D.; Heller, C.; Werp, J.,
Bishomofulvenkonjugation. Photoelektronenspektren und elektronenstruktur homologer quadricyclane,
Chem. Ber., 1974, 107, 1393. [all data]
Notes
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- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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