1,2,3-Metheno-1H-cycloprop[cd]indene,2,2a,2b,3,5a,5b-hexahydro-
- Formula: C10H10
- Molecular weight: 130.1864
- IUPAC Standard InChIKey: LMCKJCBKGXLUDT-UHFFFAOYSA-N
- CAS Registry Number: 26934-61-2
- Chemical structure:
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 244.2 ± 3.3 | kJ/mol | Ccb | Luk'yanova, Timofeeva, et al., 1991 | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -5608.4 ± 3.0 | kJ/mol | Ccb | Luk'yanova, Timofeeva, et al., 1991 | Corresponding ΔfHºsolid = 244.2 kJ/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 58.7 ± 0.4 | kJ/mol | GS | Verevkin, Kümmerlin, et al., 2002 | Based on data from 274. to 313. K. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
58.9 ± 0.4 | 294. | GS | Verevkin, Kümmerlin, et al., 2002 | Based on data from 274. to 313. K. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference |
---|---|---|---|
7.87 | 334. | DSC | Verevkin, Kümmerlin, et al., 2002 |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C10H10+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.8 ± 0.2 | PE | Martin, Heller, et al., 1974 | Vertical value |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Luk'yanova, Timofeeva, et al., 1991
Luk'yanova, V.A.; Timofeeva, L.P.; Kozina, M.P.; Kirin, V.N.; Tarakanova, A.V.,
Enthalpies of formation of certain unsaturated cyclic hydrocarbons,
Russ. J. Phys. Chem. (Engl. Transl.), 1991, 65, 439-441. [all data]
Verevkin, Kümmerlin, et al., 2002
Verevkin, Sergei P.; Kümmerlin, Martin; Hickl, Ernst; Beckhaus, Hans-Dieter; Rüchardt, Christoph; Kozhushkov, Sergei I.; Haag, Rainer; Boese, Roland; Benet-Bucholz, Jordi; Nordhoff, Karsten; Meijere, Armin de,
Thermochemical and X-ray Crystallographic Investigations of Some (CH)10 Hydrocarbons: Basketene, Nenitzescu's Hydrocarbon, and Snoutene,
Eur. J. Org. Chem., 2002, 2002, 14, 2280-262, https://doi.org/10.1002/1099-0690(200207)2002:14<2280::AID-EJOC2280>3.0.CO;2-R
. [all data]
Martin, Heller, et al., 1974
Martin, H.-D.; Heller, C.; Werp, J.,
Bishomofulvenkonjugation. Photoelektronenspektren und elektronenstruktur homologer quadricyclane,
Chem. Ber., 1974, 107, 1393. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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