Chromium, pentacarbonyl(trimethylphosphine)-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub21.8 ± 0.38kcal/molN/ABoxhoorn, Ernsting, et al., 1980 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.6PEYarbrough and Hall, 1978 
7.58PEHigginson, Lloyd, et al., 1974Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boxhoorn, Ernsting, et al., 1980
Boxhoorn, G.; Ernsting, J.M.; Stufkens, D.J.; Oskam, A., Thermochim. Acta, 1980, 42, 315. [all data]

Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B., Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative π-acceptor and σ-donor properties of various phosphorus ligands, Inorg. Chem., 1978, 17, 2269. [all data]

Higginson, Lloyd, et al., 1974
Higginson, B.R.; Lloyd, D.R.; Connor, J.A.; Hillier, I.H., Photoelectron studies of metal carbonyls. Part 4. Mono-substituted complexes of chromium tungsten carbonyls, J. Chem Soc., J. Chem. Soc. Faraday Trans. 2, 1974, 70, 1418. [all data]


Notes

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