PhN radical

• Formula: C₆H₅N
• Molecular weight: 91.1106
• CAS Registry Number: 2655-25-6
• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Options:
  • Switch to SI units

Gas phase ion energetics data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?

State:   ?

State:   a

State:   X

Additional references: Jacox, 1994, page 442; Jacox, 1998, page 370

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Drzaic and Brauman, 1984
Drzaic, P.S.; Brauman, J.I., A determination of the singlet-triplet splitting in phenylnitrene via photoelectron detachment, J. Am. Chem. Soc., 1984, 106, 3443. [all data]

Mcdonald and Davidson, 1993
Mcdonald, R.N.; Davidson, S.J., Electron Photodetachment of the Phenylnitrene Anion Radical - EA, ΔH(degrees(f), and the Singlet Triplet Splitting for Phenylnitrene, J. Chem. Soc. Chem. Comm., 1993, 115, 23, 10857, https://doi.org/10.1021/ja00076a049 . [all data]

Travers, Cowles, et al., 1992
Travers, M.J.; Cowles, D.C.; Clifford, E.P.; Ellison, G.B., Photoelectron Spectroscopy of the Phenylnitrene Anion, J. Am. Chem. Soc., 1992, 114, 22, 8699, https://doi.org/10.1021/ja00048a053 . [all data]

Wijeratne, Da Fonte, et al., 2009
Wijeratne, N.R.; Da Fonte, M.; Ronenius, A.; Wyss, P.J.; Tahmassebi, D.; Wenthold, P.G., Photoelectron Spectroscopy of Chloro-Substituted Phenylnitrene Anions, J. Phys. Chem. A, 2009, 113, 34, 9467-9473, https://doi.org/10.1021/jp9039594 . [all data]

Hayes and Sheridan, 1990
Hayes, J.C.; Sheridan, R.S., The IR spectrum of triplet phenylnitrene. On the origin of didehydroazepine in low temperature matrices, J. Am. Chem. Soc., 1990, 112, 15, 5879, https://doi.org/10.1021/ja00171a038 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.