Manganese, pentacarbonyl(trimethylsilyl)-
- Formula: C8H9MnO5Si
- Molecular weight: 268.1776
- CAS Registry Number: 26500-16-3
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.47 | PE | Harris and Spalding, 1980 | |
8.7 ± 0.2 | EI | Saalfeld, McDowell, et al., 1973 | |
9.0 ± 0.1 | PE | Cradock, Ebsworth, et al., 1973 | Vertical value |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CMnO+ | 17.9 | ? | EI | Saalfeld, McDowell, et al., 1973 | |
C3H9MnSi+ | 12.8 | ? | EI | Saalfeld, McDowell, et al., 1973 | |
C3H9Si+ | 9.81 ± 0.11 | ? | EI | Harris and Spalding, 1980 | |
C4H9MnOSi+ | 12.0 | 4CO | EI | Saalfeld, McDowell, et al., 1973 | |
C5H9MnO2Si+ | 10.8 | 3CO | EI | Saalfeld, McDowell, et al., 1973 | |
C6H9MnO3Si+ | 10.2 | 2CO | EI | Saalfeld, McDowell, et al., 1973 | |
C7H9MnO4Si+ | 9.2 | CO | EI | Saalfeld, McDowell, et al., 1973 | |
Mn+ | 21.7 | ? | EI | Saalfeld, McDowell, et al., 1973 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harris and Spalding, 1980
Harris, D.H.; Spalding, T.R.,
Electron impact study of compounds with main group IV element to transition metal bonds,
Inorg. Chim. Acta, 1980, 39, 187. [all data]
Saalfeld, McDowell, et al., 1973
Saalfeld, F.E.; McDowell, M.V.; DeCorpo, J.J.; Berry, A.D.; MacDiarmid, A.G.,
Mass spectral studies of some manganese carbonyls,
Inorg. Chem., 1973, 12, 48. [all data]
Cradock, Ebsworth, et al., 1973
Cradock, S.; Ebsworth, E.A.V.; Robertson, A.,
Photoelectron spectra of some silyl and germyl transition-metal carbonyls and related specis,
J. Chem. Soc. Dalton Trans., 1973, 22. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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