Chlorine dioxide anion

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 62200 ± 80 gas Flesch, Ruhl, et al., 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 485 ± 40 gas PE Flesch, Ruhl, et al., 1993

State:   d
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 59460 ± 80 gas Cornford, Frost, et al., 1971
Cornford, Frost, et al., 1972
Flesch, Ruhl, et al., 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO s-stretch 605 ± 40 gas PE Flesch, Ruhl, et al., 1993

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 39530 ± 80 gas Cornford, Frost, et al., 1971
Cornford, Frost, et al., 1972
Flesch, Ruhl, et al., 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO s-stretch 765 ± 40 gas PE Flesch, Ruhl, et al., 1993

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 25410 ± 80 gas Flesch, Ruhl, et al., 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO s-stretch 725 ± 40 gas PE Flesch, Ruhl, et al., 1993

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 24040 ± 80 gas Flesch, Ruhl, et al., 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO s-stretch 810 ± 40 gas PE Flesch, Ruhl, et al., 1993

State:   c
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19690 ± 80 gas Cornford, Frost, et al., 1971
Cornford, Frost, et al., 1972
Flesch, Ruhl, et al., 1993

State:   b
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 20330 ± 80 gas Flesch, Ruhl, et al., 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 Bend 485 ± 40 gas PE Flesch, Ruhl, et al., 1993

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16540 ± 80 gas Cornford, Frost, et al., 1971
Cornford, Frost, et al., 1972
Flesch, Ruhl, et al., 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO s-stretch 765 ± 40 gas PE Flesch, Ruhl, et al., 1993

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO s-stretch 1015 ± 40 gas PE Cornford, Frost, et al., 1972
Flesch, Ruhl, et al., 1993
2 Bend 520 ± 40 gas PE Cornford, Frost, et al., 1972
Flesch, Ruhl, et al., 1993

Additional references: Jacox, 1994, page 106; Jacox, 2003, page 144; Mok, Lee, et al., 2000

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Flesch, Ruhl, et al., 1993
Flesch, R.; Ruhl, E.; Hottmann, K.; Baumgartel, H., Photoabsorption and photoionization of chlorine dioxide, J. Phys. Chem., 1993, 97, 837. [all data]

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., The photoelectron spectrum of the free radical chlorine dioxide, Chem. Phys. Lett., 1971, 10, 345. [all data]

Cornford, Frost, et al., 1972
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., J. Chem. Soc., 1972, Faraday Disc. 54, 56. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Mok, Lee, et al., 2000
Mok, D.K.W.; Lee, E.P.F.; Chau, F.-T.; Wang, D.-C.; Dyke, J.M., A new method of calculation of Franck--Condon factors which includes allowance for anharmonicity and the Duschinsky effect: Simulation of the He I photoelectron spectrum of ClO[sub 2], J. Chem. Phys., 2000, 113, 14, 5791, https://doi.org/10.1063/1.1290124 . [all data]

Notes

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