Bromine anion

• Formula: Br^-
• Molecular weight: 79.905
• IUPAC Standard InChI: InChI=1S/BrH/h1H/p-1 Copy

  
• IUPAC Standard InChIKey: CPELXLSAUQHCOX-UHFFFAOYSA-M Copy
• CAS Registry Number: 24959-67-9
• Chemical structure:
  This structure is also available as a 2d Mol file
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• Information on this page:
  • Ion clustering data
  • References
  • Notes
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  • Gas phase thermochemistry data
  • Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 185
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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = (  )

By formula: Br^- + Ar = (Br^-  Ar)

Quantity	Value	Units	Method	Reference	Comment
rH°	3.3	kJ/mol	Ther	Zhao, Yourshaw, et al., 1994	gas phase; B
rH°	5.86	kJ/mol	Mobl	Gatland, 1984	gas phase; B,M

 +  = Br₃Se^-

By formula: Br^- + Br₂Se = Br₃Se^-

Quantity	Value	Units	Method	Reference	Comment
rH°	110. ± 5.9	kJ/mol	CIDT	Lobring, Hao, et al., 2003	gas phase; B

 +  = (  )

By formula: Br^- + Br₂ = (Br^-  Br₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	127. ± 7.1	kJ/mol	CIDT	Nizzi, Pommerening, et al., 1998	gas phase; B
rH°	141.0	kJ/mol	N/A	Check, Faust, et al., 2001	gas phase; Fe-; ; «DELTA»S(EA)=5.8; B
Quantity	Value	Units	Method	Reference	Comment
rG°	94.14	kJ/mol	N/A	Check, Faust, et al., 2001	gas phase; Fe-; ; «DELTA»S(EA)=5.8; B

 +  = Br₄P^-

By formula: Br^- + Br₃P = Br₄P^-

Quantity	Value	Units	Method	Reference	Comment
rH°	64.9 ± 5.9	kJ/mol	CIDT	Heil, Check, et al., 2002	gas phase; B

 +  = CBr₂F₃^-

By formula: Br^- + CBrF₃ = CBr₂F₃^-

Quantity	Value	Units	Method	Reference	Comment
rH°	58.16 ± 0.84	kJ/mol	TDAs	Bogdanov and McMahon, 2006	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	30.5	kJ/mol	TDAs	Bogdanov and McMahon, 2006	gas phase; B

 +  = (  )

By formula: Br^- + CHCl₃ = (Br^-  CHCl₃)

Quantity	Value	Units	Method	Reference	Comment
rH°	66.11	kJ/mol	Mobl	Giles and Grimsrud, 1993	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	39.7	kJ/mol	Mobl	Giles and Grimsrud, 1993	gas phase; B

 +  = (  )

By formula: Br^- + CHN = (Br^-  CHN)

Quantity	Value	Units	Method	Reference	Comment
rH°	81.2 ± 4.2	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B,M
rH°	66.9 ± 8.4	kJ/mol	Est	Larson and McMahon, 1984	gas phase; Extrapolated from other halide data; B
Quantity	Value	Units	Method	Reference	Comment
rS°	82.8	J/mol*K	PHPMS	Meot-ner, Cybulski, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	56.5 ± 6.7	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B

(  ) +  = (  2)

By formula: (Br^-  CHN) + CHN = (Br^-  2CHN)

Quantity	Value	Units	Method	Reference	Comment
rH°	68.2 ± 4.2	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	95.0	J/mol*K	PHPMS	Meot-ner, Cybulski, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	39.7	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B

(  2) +  = (  3)

By formula: (Br^-  2CHN) + CHN = (Br^-  3CHN)

Quantity	Value	Units	Method	Reference	Comment
rH°	53.6 ± 4.2	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	91.6	J/mol*K	PHPMS	Meot-ner, Cybulski, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	26.4	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B

(  3) +  = (  4)

By formula: (Br^-  3CHN) + CHN = (Br^-  4CHN)

Quantity	Value	Units	Method	Reference	Comment
rH°	43.5 ± 4.2	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	92.5	J/mol*K	PHPMS	Meot-ner, Cybulski, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	15.9	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B

(  4) +  = (  5)

By formula: (Br^-  4CHN) + CHN = (Br^-  5CHN)

Quantity	Value	Units	Method	Reference	Comment
rH°	34. ± 4.2	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	77.4	J/mol*K	PHPMS	Meot-ner, Cybulski, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	10.9	kJ/mol	TDAs	Meot-ner, Cybulski, et al., 1988	gas phase; B

 +  = CH₂BrO₂^-

By formula: Br^- + CH₂O₂ = CH₂BrO₂^-

Quantity	Value	Units	Method	Reference	Comment
rH°	72.0 ± 7.1	kJ/mol	CIDT	Walker and Sunderlin, 1999	gas phase; B

 +  = (  )

By formula: Br^- + CH₃Br = (Br^-  CH₃Br)

Quantity	Value	Units	Method	Reference	Comment
rH°	46.9 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rH°	38.5 ± 2.1	kJ/mol	TDAs	Dougherty and Roberts, 1974	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	58.6	J/mol*K	HPMS	Dougherty and Roberts, 1974	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	19.2 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rG°	20.9 ± 3.3	kJ/mol	TDAs	Dougherty and Roberts, 1974	gas phase; B

 +  = (  )

By formula: Br^- + CH₃Cl = (Br^-  CH₃Cl)

Quantity	Value	Units	Method	Reference	Comment
rH°	45.6 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	20.3 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B

 +  = CH₃BrNO₂^-

By formula: Br^- + CH₃NO₂ = CH₃BrNO₂^-

Quantity	Value	Units	Method	Reference	Comment
rG°	40. ± 8.4	kJ/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

 +  = (  )

By formula: Br^- + CH₄O = (Br^-  CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	60.67 ± 0.42	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rH°	58.2 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	73.6	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	33.5 ± 0.42	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rG°	36. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B
rG°	35. ± 8.4	kJ/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

(  ) +  = (  2)

By formula: (Br^-  CH₄O) + CH₄O = (Br^-  2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	50.21 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rH°	52.3 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	86.6	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	23.5	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rG°	26. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

(  2) +  = (  3)

By formula: (Br^-  2CH₄O) + CH₄O = (Br^-  3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	39.7 ± 2.1	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rH°	44.4 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	90.4	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	17.8	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rG°	18. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

(  3) +  = (  4)

By formula: (Br^-  3CH₄O) + CH₄O = (Br^-  4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	41. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	97.1	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	13. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

(  4) +  = (  5)

By formula: (Br^-  4CH₄O) + CH₄O = (Br^-  5CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	41. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	105.	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	9.6 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

(  5) +  = (  6)

By formula: (Br^-  5CH₄O) + CH₄O = (Br^-  6CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	38. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	98.7	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	8.8 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

(  6) +  = (  7)

By formula: (Br^-  6CH₄O) + CH₄O = (Br^-  7CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	36. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	95.8	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	7.1 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

(  7) +  = (  8)

By formula: (Br^-  7CH₄O) + CH₄O = (Br^-  8CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	35. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	96.7	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	6.3 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

(  8) +  = (  9)

By formula: (Br^-  8CH₄O) + CH₄O = (Br^-  9CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	34. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	96.	J/mol*K	N/A	Hiraoka and Yamabe, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
rG°	5.4 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B

(  9) +  = (  10)

By formula: (Br^-  9CH₄O) + CH₄O = (Br^-  10CH₄O)

Quantity	Value	Units	Method	Reference	Comment
rH°	33. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	96.	J/mol*K	N/A	Hiraoka and Yamabe, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
rG°	4.6 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B

 +  = CH₄Br^-

By formula: Br^- + CH₄ = CH₄Br^-

Quantity	Value	Units	Method	Reference	Comment
rH°	13.0	kJ/mol	N/A	Hiraoka, Mizuno, et al., 2001	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	-9.50	kJ/mol	TDAs	Hiraoka, Mizuno, et al., 2001	gas phase; B

 +  = (  )

By formula: Br^- + CO₂ = (Br^-  CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	22. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995	gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
rH°	28. ± 4.2	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	69.0	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	7.5 ± 8.4	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1987	gas phase; B

(  ) +  = (  2)

By formula: (Br^-  CO₂) + CO₂ = (Br^-  2CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	21. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
rH°	25. ± 4.2	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	79.5	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	1. ± 8.4	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1987	gas phase; B

(  2) +  = (  3)

By formula: (Br^-  2CO₂) + CO₂ = (Br^-  3CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	21. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  3) +  = (  4)

By formula: (Br^-  3CO₂) + CO₂ = (Br^-  4CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	22. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  4) +  = (  5)

By formula: (Br^-  4CO₂) + CO₂ = (Br^-  5CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	18. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  5) +  = (  6)

By formula: (Br^-  5CO₂) + CO₂ = (Br^-  6CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	17. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  6) +  = (  7)

By formula: (Br^-  6CO₂) + CO₂ = (Br^-  7CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	15. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  7) +  = (  8)

By formula: (Br^-  7CO₂) + CO₂ = (Br^-  8CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	15. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  8) +  = (  9)

By formula: (Br^-  8CO₂) + CO₂ = (Br^-  9CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	7.5 ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  9) +  = (  10)

By formula: (Br^-  9CO₂) + CO₂ = (Br^-  10CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	7.5 ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(  10) +  = (  11)

By formula: (Br^-  10CO₂) + CO₂ = (Br^-  11CO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	2. ± 8.4	kJ/mol	PDis	Arnold, Bradforth, et al., 1995, 2	gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

 +  = (  )

By formula: Br^- + CS₂ = (Br^-  CS₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	34.7 ± 0.84	kJ/mol	TDAs	Hiraoka, Fujimaki, et al., 1993	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	54.4	J/mol*K	PHPMS	Hiraoka, Fujimaki, et al., 1993	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	18. ± 4.2	kJ/mol	TDAs	Hiraoka, Fujimaki, et al., 1993	gas phase; B

(  ) +  = (  2)

By formula: (Br^-  CS₂) + CS₂ = (Br^-  2CS₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	30.5 ± 0.84	kJ/mol	TDAs	Hiraoka, Fujimaki, et al., 1993	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	85.4	J/mol*K	PHPMS	Hiraoka, Fujimaki, et al., 1993	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	5.0 ± 4.2	kJ/mol	TDAs	Hiraoka, Fujimaki, et al., 1993	gas phase; B

 +  = C₂BrF₄^-

By formula: Br^- + C₂F₄ = C₂BrF₄^-

Quantity	Value	Units	Method	Reference	Comment
rH°	29.7 ± 2.1	kJ/mol	TDAs	Hiraoka, Mochizuki, et al., 2008	gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B
Quantity	Value	Units	Method	Reference	Comment
rG°	9.7 ± 2.1	kJ/mol	TDAs	Hiraoka, Mochizuki, et al., 2008	gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B

 +  = C₂H₂Br^-

By formula: Br^- + C₂H₂ = C₂H₂Br^-

Quantity	Value	Units	Method	Reference	Comment
rH°	36.0	kJ/mol	LPES	Wild, Milley, et al., 2000	gas phase; Given: 8.635±0.009 kcal/mol(0 K); B

 +  = (  )

By formula: Br^- + C₂H₃N = (Br^-  C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	59.8 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rH°	50.6 ± 1.7	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B
rH°	54.0 ± 1.7	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B,M
rH°	54.0 ± 8.4	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B,M
rH°	54.0	kJ/mol	HPMS	Caldwell, Masucci, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rS°	51.0	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1988	gas phase; M
rS°	69.0	J/mol*K	HPMS	Yamdagni and Kebarle, 1972	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	36.4 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rG°	37. ± 8.4	kJ/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B
rG°	38.5 ± 2.9	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B
rG°	33. ± 8.4	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B

(  ) +  = (  2)

By formula: (Br^-  C₂H₃N) + C₂H₃N = (Br^-  2C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	49.0 ± 1.7	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B,M
rH°	48.1 ± 2.9	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B
rH°	49.37	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	71.1	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1988	gas phase; M
rS°	85.4	J/mol*K	HPMS	Yamdagni and Kebarle, 1972	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	28. ± 5.4	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B
rG°	24.3	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B

(  2) +  = (  3)

By formula: (Br^-  2C₂H₃N) + C₂H₃N = (Br^-  3C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	38.5 ± 1.7	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B,M
rH°	43.5 ± 2.9	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B
rH°	41.84	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	69.9	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1988	gas phase; M
rS°	90.8	J/mol*K	HPMS	Yamdagni and Kebarle, 1972	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	18. ± 5.4	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B
rG°	15.1	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B

(  3) +  = (  4)

By formula: (Br^-  3C₂H₃N) + C₂H₃N = (Br^-  4C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	36.4 ± 1.3	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B,M
rH°	35.6 ± 3.3	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B
rH°	23.0	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	82.0	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1988	gas phase; M
rS°	45.6	J/mol*K	HPMS	Yamdagni and Kebarle, 1972	gas phase; Entropy change is questionable; M
Quantity	Value	Units	Method	Reference	Comment
rG°	12. ± 5.0	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B
rG°	9.20	kJ/mol	TDAs	Yamdagni and Kebarle, 1972	gas phase; B

(  4) +  = (  5)

By formula: (Br^-  4C₂H₃N) + C₂H₃N = (Br^-  5C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	35.6 ± 1.3	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B,M
rH°	24.3 ± 3.8	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rS°	92.9	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	7.5 ± 5.4	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B

(  5) +  = (  6)

By formula: (Br^-  5C₂H₃N) + C₂H₃N = (Br^-  6C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	33.5 ± 0.84	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B,M
rH°	23. ± 4.2	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rS°	94.1	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	5.0 ± 3.8	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B

(  6) +  = (  7)

By formula: (Br^-  6C₂H₃N) + C₂H₃N = (Br^-  7C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	32.2 ± 1.3	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B,M
rH°	13. ± 4.6	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rS°	95.8	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	3. ± 5.4	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1988	gas phase; B

(  7) +  = (  8)

By formula: (Br^-  7C₂H₃N) + C₂H₃N = (Br^-  8C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	15. ± 5.0	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B

(  8) +  = (  9)

By formula: (Br^-  8C₂H₃N) + C₂H₃N = (Br^-  9C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	12. ± 5.9	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B

(  9) +  = (  10)

By formula: (Br^-  9C₂H₃N) + C₂H₃N = (Br^-  10C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	15. ± 6.3	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B

(  10) +  = (  11)

By formula: (Br^-  10C₂H₃N) + C₂H₃N = (Br^-  11C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	5.0 ± 6.7	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B

(  11) +  = (  12)

By formula: (Br^-  11C₂H₃N) + C₂H₃N = (Br^-  12C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	5.0 ± 7.1	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B

(  12) +  = (  13)

By formula: (Br^-  12C₂H₃N) + C₂H₃N = (Br^-  13C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	2. ± 7.5	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B

(  13) +  = (  14)

By formula: (Br^-  13C₂H₃N) + C₂H₃N = (Br^-  14C₂H₃N)

Quantity	Value	Units	Method	Reference	Comment
rH°	3. ± 7.9	kJ/mol	N/A	Markovich, Perera, et al., 1996	gas phase; B

 +  = (  )

By formula: Br^- + C₂H₅Br = (Br^-  C₂H₅Br)

Quantity	Value	Units	Method	Reference	Comment
rH°	50.2 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rH°	48.53	kJ/mol	TDAs	Dougherty, 1974	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	80.3	J/mol*K	HPMS	Dougherty, 1974	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	24.7 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rG°	24.7	kJ/mol	TDAs	Dougherty, 1974	gas phase; B

 +  = (  )

By formula: Br^- + C₂H₅Cl = (Br^-  C₂H₅Cl)

Quantity	Value	Units	Method	Reference	Comment
rH°	46.9 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	22.4 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B

 +  = (  )

By formula: Br^- + C₂H₆OS = (Br^-  C₂H₆OS)

Quantity	Value	Units	Method	Reference	Comment
rH°	72.38	kJ/mol	TDAs	Magnera, Caldwell, et al., 1984	gas phase; B,M
rH°	72.0	kJ/mol	HPMS	Caldwell, Masucci, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rS°	89.5	J/mol*K	PHPMS	Magnera, Caldwell, et al., 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	45.61	kJ/mol	TDAs	Magnera, Caldwell, et al., 1984	gas phase; B

(  ) +  = (  2)

By formula: (Br^-  C₂H₆OS) + C₂H₆OS = (Br^-  2C₂H₆OS)

Quantity	Value	Units	Method	Reference	Comment
rH°	60.7	kJ/mol	PHPMS	Magnera, Caldwell, et al., 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rS°	93.7	J/mol*K	PHPMS	Magnera, Caldwell, et al., 1984	gas phase; M

(  2) +  = (  3)

By formula: (Br^-  2C₂H₆OS) + C₂H₆OS = (Br^-  3C₂H₆OS)

Quantity	Value	Units	Method	Reference	Comment
rH°	56.9	kJ/mol	PHPMS	Magnera, Caldwell, et al., 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rS°	115.	J/mol*K	PHPMS	Magnera, Caldwell, et al., 1984	gas phase; M

 +  = C₂H₆BrO^-

By formula: Br^- + C₂H₆O = C₂H₆BrO^-

Quantity	Value	Units	Method	Reference	Comment
rH°	58.99 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	34.3	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rG°	37. ± 8.4	kJ/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

 + 2 = C₄H₁₂BrO₂^-

By formula: Br^- + 2C₂H₆O = C₄H₁₂BrO₂^-

Quantity	Value	Units	Method	Reference	Comment
rH°	48.1 ± 2.5	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	23.9	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B

 + 3 = C₆H₁₈BrO₃^-

By formula: Br^- + 3C₂H₆O = C₆H₁₈BrO₃^-

Quantity	Value	Units	Method	Reference	Comment
rH°	39.7 ± 1.3	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	18.3	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B

 +  = C₃BrF₆^-

By formula: Br^- + C₃F₆ = C₃BrF₆^-

Quantity	Value	Units	Method	Reference	Comment
rH°	41.4 ± 1.3	kJ/mol	TDAs	Hiraoka, Takao, et al., 2002	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	17.7 ± 1.3	kJ/mol	TDAs	Hiraoka, Takao, et al., 2002	gas phase; B

 +  = (  )

By formula: Br^- + C₃H₇Br = (Br^-  C₃H₇Br)

Quantity	Value	Units	Method	Reference	Comment
rH°	59.4 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rH°	51.04	kJ/mol	TDAs	Dougherty, 1974	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	83.3	J/mol*K	HPMS	Dougherty, 1974	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	26.4 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rG°	26.4	kJ/mol	TDAs	Dougherty, 1974	gas phase; B

 +  = (  )

By formula: Br^- + C₃H₇Br = (Br^-  C₃H₇Br)

Quantity	Value	Units	Method	Reference	Comment
rH°	48.53	kJ/mol	TDAs	Dougherty, 1974	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	82.8	J/mol*K	HPMS	Dougherty, 1974	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	23.8	kJ/mol	TDAs	Dougherty, 1974	gas phase; B

 +  = (  )

By formula: Br^- + C₃H₇Cl = (Br^-  C₃H₇Cl)

Quantity	Value	Units	Method	Reference	Comment
rH°	51.9 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	26.2 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B

 +  = (  )

By formula: Br^- + C₃H₇Cl = (Br^-  C₃H₇Cl)

Quantity	Value	Units	Method	Reference	Comment
rH°	50.6 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	24.9 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B

 +  = C₃H₈BrO^-

By formula: Br^- + C₃H₈O = C₃H₈BrO^-

Quantity	Value	Units	Method	Reference	Comment
rH°	60.25 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	34.9	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
rG°	38. ± 8.4	kJ/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

 + 2 = C₆H₁₆BrO₂^-

By formula: Br^- + 2C₃H₈O = C₆H₁₆BrO₂^-

Quantity	Value	Units	Method	Reference	Comment
rH°	51.46 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	22.8	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B

 +  = (  )

By formula: Br^- + C₄H₉Br = (Br^-  C₄H₉Br)

Quantity	Value	Units	Method	Reference	Comment
rH°	53.97	kJ/mol	TDAs	Dougherty, 1974	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	91.2	J/mol*K	HPMS	Dougherty, 1974	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	26.8	kJ/mol	TDAs	Dougherty, 1974	gas phase; B

 +  = (  )

By formula: Br^- + C₄H₉Br = (Br^-  C₄H₉Br)

Quantity	Value	Units	Method	Reference	Comment
rH°	65.3 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rH°	51.88	kJ/mol	TDAs	Dougherty, 1974	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	80.8	J/mol*K	HPMS	Dougherty, 1974	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	30.5 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
rG°	28.0	kJ/mol	TDAs	Dougherty, 1974	gas phase; B

 +  = (  )

By formula: Br^- + C₄H₉Cl = (Br^-  C₄H₉Cl)

Quantity	Value	Units	Method	Reference	Comment
rH°	58.2 ± 4.2	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	27.6 ± 0.84	kJ/mol	TDAs	Li, Ross, et al., 1996	gas phase; B

 +  = C₄H₁₀BrO^-

By formula: Br^- + C₄H₁₀O = C₄H₁₀BrO^-

Quantity	Value	Units	Method	Reference	Comment
rH°	66.11 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	35.9	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B

 + 2 = C₈H₂₀BrO₂^-

By formula: Br^- + 2C₄H₁₀O = C₈H₂₀BrO₂^-

Quantity	Value	Units	Method	Reference	Comment
rH°	54.0 ± 1.7	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	23.6	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B

 + 3 = C₁₂H₃₀BrO₃^-

By formula: Br^- + 3C₄H₁₀O = C₁₂H₃₀BrO₃^-

Quantity	Value	Units	Method	Reference	Comment
rH°	48.5 ± 2.1	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	18.1	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B

 +  = C₅BrF₈^-

By formula: Br^- + C₅F₈ = C₅BrF₈^-

Quantity	Value	Units	Method	Reference	Comment
rH°	53.1 ± 1.3	kJ/mol	TDAs	Hiraoka, Fujita, et al., 1905	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
rG°	29.5 ± 1.3	kJ/mol	TDAs	Hiraoka, Fujita, et al., 1905	gas phase; B

 +  = (  )

By formula: Br^- + C₅H₁₁Br = (Br^-  C₅H₁₁Br)

Quantity	Value	Units	Method	Reference	Comment
rH°	60.25	kJ/mol	TDAs	Dougherty, 1974	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	105.	J/mol*K	HPMS	Dougherty, 1974	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	28.9	kJ/mol	TDAs	Dougherty, 1974	gas phase; B

 +  = (  )

By formula: Br^- + C₆F₆ = (Br^-  C₆F₆)

Quantity	Value	Units	Method	Reference	Comment
rH°	58.2 ± 4.2	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1987, 2	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	81.2	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1987, 2	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rG°	34. ± 6.7	kJ/mol	TDAs	Hiraoka, Mizuse, et al., 1987, 2	gas phase; B

(  ) +  = (  2)

By formula: (Br^-  C₆F₆) + C₆F₆ = (Br^-  2C₆F₆)

Quantity	Value	Units	Method	Reference	Comment
rH°	51.0	kJ/mol	PHPMS	Hiraoka, Mizuse, et al., 1987, 2	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
rS°	102.	J/mol*K	PHPMS	Hiraoka, Mizuse, et al., 1987, 2	gas phase; M

 +  = (  )

By formula: Br^- + C₆HF₅O = (Br^-  C₆HF₅O)

Quantity	Value	Units	Method	Reference	Comment
rH°	107. ± 7.5	kJ/mol	IMRE	Paul and Kebarle, 1990	gas phase; «DELTA»Gaff at 423 K; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	96.	J/mol*K	N/A	Paul and Kebarle, 1990	gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
rG°	66.5 ± 4.2	kJ/mol	IMRE	Paul and Kebarle, 1990	gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

rG° (kJ/mol)	T (K)	Method	Reference	Comment
66.5	423.	PHPMS	Paul and Kebarle, 1990	gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

 +  = (  )

By formula: Br^- + C₆H₃N₃O₆ = (Br^-  C₆H₃N₃O₆)

Quantity	Value	Units	Method	Reference	Comment
rS°	92.	J/mol*K	N/A	Paul and Kebarle, 1991	gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
rG°	54.8 ± 4.2	kJ/mol	IMRE	Paul and Kebarle, 1991	gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

rG° (kJ/mol)	T (K)	Method	Reference	Comment
54.8	423.	PHPMS	Paul and Kebarle, 1991	gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M

 +  = (  )

By formula: Br^- + C₆H₄ClNO₂ = (Br^-  C₆H₄ClNO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	71.5 ± 7.5	kJ/mol	IMRE	Paul and Kebarle, 1991	gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	92.	J/mol*K	N/A	Paul and Kebarle, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
rG°	32. ± 4.2	kJ/mol	IMRE	Paul and Kebarle, 1991	gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

rG° (kJ/mol)	T (K)	Method	Reference	Comment
32.	423.	PHPMS	Paul and Kebarle, 1991	gas phase; Entropy change calculated or estimated; M

 +  = (  )

By formula: Br^- + C₆H₄ClNO₂ = (Br^-  C₆H₄ClNO₂)

Quantity	Value	Units	Method	Reference	Comment
rH°	67.4 ± 7.5	kJ/mol	IMRE	Paul and Kebarle, 1991	gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity	Value	Units	Method	Reference	Comment
rS°	92.	J/mol*K	N/A	Paul and Kebarle, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
rG°	28. ± 4.2	kJ/mol	IMRE	Paul and Kebarle, 1991	gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

rG° (kJ/mol)	T (K)	Method	Reference	Comment
28.	423.	PHPMS	Paul and Kebarle, 1991	gas phase; Entropy change calculated or estimated; M

 +  = (  )

By formula: Br^- + C₆H₄ClNO₂ = (Br^-  C₆H₄ClNO₂)