Bromine anion
- Formula: Br-
- Molecular weight: 79.905
- IUPAC Standard InChI:
- InChI=1S/BrH/h1H/p-1
- Download the identifier in a file.
- IUPAC Standard InChIKey: CPELXLSAUQHCOX-UHFFFAOYSA-M
- CAS Registry Number: 24959-67-9
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 185
- Gas phase ion energetics data
- Options:
Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Br- + Ar = (Br- Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3.3 | kJ/mol | Ther | Zhao, Yourshaw, et al., 1994 | gas phase; B |
![]() | 5.86 | kJ/mol | Mobl | Gatland, 1984 | gas phase; B,M |
+
= Br3Se-
By formula: Br- + Br2Se = Br3Se-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 110. ± 5.9 | kJ/mol | CIDT | Lobring, Hao, et al., 2003 | gas phase; B |
By formula: Br- + Br2 = (Br- Br2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 127. ± 7.1 | kJ/mol | CIDT | Nizzi, Pommerening, et al., 1998 | gas phase; B |
![]() | 141.0 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; Fe-; ; «DELTA»S(EA)=5.8; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.14 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; Fe-; ; «DELTA»S(EA)=5.8; B |
+
= Br4P-
By formula: Br- + Br3P = Br4P-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.9 ± 5.9 | kJ/mol | CIDT | Heil, Check, et al., 2002 | gas phase; B |
+
= CBr2F3-
By formula: Br- + CBrF3 = CBr2F3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.16 ± 0.84 | kJ/mol | TDAs | Bogdanov and McMahon, 2006 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.5 | kJ/mol | TDAs | Bogdanov and McMahon, 2006 | gas phase; B |
By formula: Br- + CHCl3 = (Br- CHCl3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.11 | kJ/mol | Mobl | Giles and Grimsrud, 1993 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 39.7 | kJ/mol | Mobl | Giles and Grimsrud, 1993 | gas phase; B |
By formula: Br- + CHN = (Br- CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 81.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
![]() | 66.9 ± 8.4 | kJ/mol | Est | Larson and McMahon, 1984 | gas phase; Extrapolated from other halide data; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.8 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 56.5 ± 6.7 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Br- CHN) + CHN = (Br-
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.0 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 39.7 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Br- 2CHN) + CHN = (Br-
3CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.6 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.6 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.4 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Br- 3CHN) + CHN = (Br-
4CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.5 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.9 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Br- 4CHN) + CHN = (Br-
5CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34. ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.4 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.9 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
+
= CH2BrO2-
By formula: Br- + CH2O2 = CH2BrO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.0 ± 7.1 | kJ/mol | CIDT | Walker and Sunderlin, 1999 | gas phase; B |
By formula: Br- + CH3Br = (Br- CH3Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 38.5 ± 2.1 | kJ/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 58.6 | J/mol*K | HPMS | Dougherty and Roberts, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.2 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 20.9 ± 3.3 | kJ/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B |
By formula: Br- + CH3Cl = (Br- CH3Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.6 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.3 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
+
= CH3BrNO2-
By formula: Br- + CH3NO2 = CH3BrNO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
By formula: Br- + CH4O = (Br- CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.67 ± 0.42 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 58.2 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 73.6 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 33.5 ± 0.42 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 36. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
![]() | 35. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
By formula: (Br- CH4O) + CH4O = (Br-
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.21 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 52.3 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 86.6 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.5 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 26. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 2CH4O) + CH4O = (Br-
3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39.7 ± 2.1 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 44.4 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.8 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 18. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 3CH4O) + CH4O = (Br-
4CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 4CH4O) + CH4O = (Br-
5CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.6 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 5CH4O) + CH4O = (Br-
6CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.8 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 6CH4O) + CH4O = (Br-
7CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.1 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 7CH4O) + CH4O = (Br-
8CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.7 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.3 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 8CH4O) + CH4O = (Br-
9CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.4 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B |
By formula: (Br- 9CH4O) + CH4O = (Br-
10CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.6 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B |
+
= CH4Br-
By formula: Br- + CH4 = CH4Br-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.0 | kJ/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -9.50 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
By formula: Br- + CO2 = (Br- CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B |
![]() | 28. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 69.0 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (Br- CO2) + CO2 = (Br-
2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 25. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.5 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (Br- 2CO2) + CO2 = (Br-
3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 3CO2) + CO2 = (Br-
4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 4CO2) + CO2 = (Br-
5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 5CO2) + CO2 = (Br-
6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 6CO2) + CO2 = (Br-
7CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 7CO2) + CO2 = (Br-
8CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 8CO2) + CO2 = (Br-
9CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 9CO2) + CO2 = (Br-
10CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 10CO2) + CO2 = (Br-
11CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: Br- + CS2 = (Br- CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34.7 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 54.4 | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
By formula: (Br- CS2) + CS2 = (Br-
2CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 30.5 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.0 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
+
= C2BrF4-
By formula: Br- + C2F4 = C2BrF4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.7 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mochizuki, et al., 2008 | gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.7 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mochizuki, et al., 2008 | gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B |
+
= C2H2Br-
By formula: Br- + C2H2 = C2H2Br-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36.0 | kJ/mol | LPES | Wild, Milley, et al., 2000 | gas phase; Given: 8.635±0.009 kcal/mol(0 K); B |
By formula: Br- + C2H3N = (Br- C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.8 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 50.6 ± 1.7 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 54.0 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 54.0 ± 8.4 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
![]() | 54.0 | kJ/mol | HPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 51.0 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 69.0 | J/mol*K | HPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 36.4 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 37. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
![]() | 38.5 ± 2.9 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 33. ± 8.4 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Br- C2H3N) + C2H3N = (Br-
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 48.1 ± 2.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 49.37 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 85.4 | J/mol*K | HPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28. ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 24.3 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Br- 2C2H3N) + C2H3N = (Br-
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38.5 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 43.5 ± 2.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 41.84 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 69.9 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 90.8 | J/mol*K | HPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18. ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 15.1 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Br- 3C2H3N) + C2H3N = (Br-
4C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36.4 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 35.6 ± 3.3 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 23.0 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.0 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 45.6 | J/mol*K | HPMS | Yamdagni and Kebarle, 1972 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 12. ± 5.0 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 9.20 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Br- 4C2H3N) + C2H3N = (Br-
5C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35.6 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 24.3 ± 3.8 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.9 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (Br- 5C2H3N) + C2H3N = (Br-
6C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33.5 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 23. ± 4.2 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.0 ± 3.8 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (Br- 6C2H3N) + C2H3N = (Br-
7C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.2 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 13. ± 4.6 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3. ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (Br- 7C2H3N) + C2H3N = (Br-
8C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 5.0 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Br- 8C2H3N) + C2H3N = (Br-
9C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12. ± 5.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Br- 9C2H3N) + C2H3N = (Br-
10C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 6.3 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Br- 10C2H3N) + C2H3N = (Br-
11C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.0 ± 6.7 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Br- 11C2H3N) + C2H3N = (Br-
12C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.0 ± 7.1 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Br- 12C2H3N) + C2H3N = (Br-
13C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2. ± 7.5 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Br- 13C2H3N) + C2H3N = (Br-
14C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3. ± 7.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: Br- + C2H5Br = (Br- C2H5Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.2 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 48.53 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.3 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.7 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 24.7 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C2H5Cl = (Br- C2H5Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.4 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Br- + C2H6OS = (Br- C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.38 | kJ/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B,M |
![]() | 72.0 | kJ/mol | HPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 89.5 | J/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.61 | kJ/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B |
By formula: (Br- C2H6OS) + C2H6OS = (Br-
2C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.7 | kJ/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.7 | J/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
By formula: (Br- 2C2H6OS) + C2H6OS = (Br-
3C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 | kJ/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 115. | J/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
+
= C2H6BrO-
By formula: Br- + C2H6O = C2H6BrO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.99 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34.3 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 37. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
+ 2
= C4H12BrO2-
By formula: Br- + 2C2H6O = C4H12BrO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.1 ± 2.5 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.9 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+ 3
= C6H18BrO3-
By formula: Br- + 3C2H6O = C6H18BrO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39.7 ± 1.3 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.3 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+
= C3BrF6-
By formula: Br- + C3F6 = C3BrF6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.4 ± 1.3 | kJ/mol | TDAs | Hiraoka, Takao, et al., 2002 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.7 ± 1.3 | kJ/mol | TDAs | Hiraoka, Takao, et al., 2002 | gas phase; B |
By formula: Br- + C3H7Br = (Br- C3H7Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 51.04 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.3 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.4 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 26.4 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C3H7Br = (Br- C3H7Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.53 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.8 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.8 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C3H7Cl = (Br- C3H7Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.2 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Br- + C3H7Cl = (Br- C3H7Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.6 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.9 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
+
= C3H8BrO-
By formula: Br- + C3H8O = C3H8BrO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.25 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34.9 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 38. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
+ 2
= C6H16BrO2-
By formula: Br- + 2C3H8O = C6H16BrO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.46 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.8 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
By formula: Br- + C4H9Br = (Br- C4H9Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.97 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.2 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.8 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C4H9Br = (Br- C4H9Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.3 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 51.88 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.8 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.5 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 28.0 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C4H9Cl = (Br- C4H9Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.2 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.6 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
+
= C4H10BrO-
By formula: Br- + C4H10O = C4H10BrO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.11 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 35.9 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+ 2
= C8H20BrO2-
By formula: Br- + 2C4H10O = C8H20BrO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 ± 1.7 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.6 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+ 3
= C12H30BrO3-
By formula: Br- + 3C4H10O = C12H30BrO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 ± 2.1 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.1 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+
= C5BrF8-
By formula: Br- + C5F8 = C5BrF8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.1 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.5 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
By formula: Br- + C5H11Br = (Br- C5H11Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.25 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.9 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C6F6 = (Br- C6F6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.2 ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.2 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34. ± 6.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; B |
By formula: (Br- C6F6) + C6F6 = (Br-
2C6F6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; M |
By formula: Br- + C6HF5O = (Br- C6HF5O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 107. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 66.5 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
66.5 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C6H3N3O6 = (Br- C6H3N3O6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 54.8 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
54.8 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M |
By formula: Br- + C6H4ClNO2 = (Br- C6H4ClNO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
32. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4ClNO2 = (Br- C6H4ClNO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 67.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4ClNO2 = (Br- C6H4ClNO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 73.2 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
34. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4FNO2 = (Br- C6H4FNO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.1 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
27. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4FNO2 = (Br- C6H4FNO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 33. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
33. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4FNO2 = (Br- C6H4FNO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 73.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
34. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4N2O4 = (Br- C6H4N2O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.6 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
45.6 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4N2O4 = (Br- C6H4N2O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.8 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
38. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H4N2O4 = (Br- C6H4N2O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 48.5 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
48.5 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5ClO = (Br- C6H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 88.7 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 48.1 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
48.1 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5ClO = (Br- C6H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 102. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 61.5 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
61.5 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C6H5ClO = (Br- C6H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 101. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 60.2 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
60.2 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C6H5Cl = (Br- C6H5Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
11. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5FO = (Br- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 46.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
46.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5FO = (Br- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 56.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
56.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5FO = (Br- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 57.3 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
57.3 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5F = (Br- C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.4 ± 6.7 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.8 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
8.8 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5NO = (Br- C6H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.3 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
By formula: Br- + C6H5NO2 = (Br- C6H5NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 ± 7.5 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.5 | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. ± 4.2 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
27. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5NO3 = (Br- C6H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 119. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 78.2 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
78.2 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C6H5NO3 = (Br- C6H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 74.1 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
74.1 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C6H6O = (Br- C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.0 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
![]() | 82.0 | kJ/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 46.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
46.4 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
46.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H6 = (Br- C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 71. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; B |
![]() | 16. ± 11. | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H7NO = (Br- C6H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 81.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 41. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H7NO = (Br- C6H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H7N = (Br- C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.1 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H3F3N2O4 = (Br- C7H3F3N2O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.8 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 43.5 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
43.5 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M |
By formula: Br- + C7H3N3O4 = (Br- C7H3N3O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 90.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 51.0 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.0 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M |
By formula: Br- + C7H4F3NO2 = (Br- C7H4F3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.4 ± 7.5 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.3 | J/mol*K | PHPMS | Paul and Kebarle, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 4.2 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B |
By formula: Br- + C7H4F3NO2 = (Br- C7H4F3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 80.3 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 41. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
38. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H4F3NO2 = (Br- C7H4F3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
29. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H4N2O2 = (Br- C7H4N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 48.1 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
48.1 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H4N2O2 = (Br- C7H4N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 85.8 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 46.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
46.4 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H4N2O2 = (Br- C7H4N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.8 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
38. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H5Cl3 = (Br- C7H5Cl3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
16. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H5F3O = (Br- C7H5F3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 108. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
![]() | 52.7 | kJ/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 66.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
17. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + CF3C6H4OH = (Br- CF3C6H4OH)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 111. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 70.7 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
70.7 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H5F3O = (Br- C7H5F3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 101. | kJ/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
60.2 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H5F3 = (Br- C7H5F3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 52.7 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
![]() | 108. | kJ/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
66.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H5NO = (Br- C7H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 113. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 72.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
72.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H5NO = (Br- C7H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 116. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 75.7 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
75.7 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H5NO = (Br- C7H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 74.1 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
74.1 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H5NO3 = (Br- C7H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 43.1 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
43.1 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H5NO3 = (Br- C7H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
38. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H5N = (Br- C7H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H6O = (Br- C7H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.2 | kJ/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
20. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H6O2 = (Br- C7H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 76.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 41. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H6O2 = (Br- C7H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 105. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 64.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
64.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H6O2 = (Br- C7H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 108. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 67.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
64.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
67.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: Br- + C7H7NO2 = (Br- C7H7NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H7NO2 = (Br- C7H7NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H7NO2 = (Br- C7H7NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 67.8 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O = (Br- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.2 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.6 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
45.6 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O = (Br- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
14. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O = (Br- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O = (Br- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.2 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.6 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
45.6 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O2 = (Br- C7H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 51.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O2 = (Br- C7H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 47.3 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
47.3 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8 = (Br- C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.4 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C8H3F6NO2 = (Br- C8H3F6NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 73.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
34. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M |
By formula: Br- + C8H8O = (Br- C8H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.0 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
23. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C8H8O2 = (Br- C8H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 105. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 64.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
By formula: Br- + C8H11N = (Br- C8H11N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: (Br- 4294967295Cs) + Cs = Br-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 124.7 ± 4.0 | kJ/mol | N/A | Miller, Leopold, et al., 1986 | gas phase; Extrapolated by polarizability and radius from experimental data.; B |
By formula: Br- + HBr = (Br- HBr)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.2 ± 8.4 | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B,M |
![]() | 73.2 | kJ/mol | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.3 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
![]() | 92. | J/mol*K | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 58. ± 11. | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
39. | 367. | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M |
By formula: (Br- HBr) + HBr = (Br-
2HBr)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.1 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
By formula: (Br- HBr) + O2S = (Br-
O2S
HBr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.6 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.1 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
By formula: Br- + HCl = (Br- HCl)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.0 ± 8.4 | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Br-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 54. ± 11. | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B |
By formula: (Br- HCl) + HCl = (Br-
2HCl)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 52.3 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Br-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.0 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Br-)SO2; M |
By formula: (Br- HCl) + O2S = (Br-
O2S
HCl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.6 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.8 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
By formula: Br- + HF = (Br- HF)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.1 ± 8.4 | kJ/mol | Est | Larson and McMahon, 1984 | gas phase; Extrapolated from other bihalide data; B |
![]() | 71.1 | kJ/mol | HPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
By formula: Br- + HNO3 = (Br- HNO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 83.7 | kJ/mol | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.4 | J/mol*K | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
56.1 | 367. | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M |
By formula: (Br- HNO3) + HNO3 = (Br-
2HNO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 75.7 | kJ/mol | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | N/A | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 46.4 | kJ/mol | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M |
By formula: Br- + H2O = (Br- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.14 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 49.0 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 52.72 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
![]() | 53.1 | kJ/mol | HPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 61.5 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 77.0 | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
![]() | 82.8 | J/mol*K | MS | Burdett and Hayhurst, 1982 | gas phase; FLAME SOURCE, 1600 K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.5 ± 3.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 29. ± 12. | kJ/mol | TDAs | Burdett and Hayhurst, 1982 | gas phase; B |
![]() | 29. ± 8.4 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
By formula: (Br- H2O) + H2O = (Br-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 51.04 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 51.5 ± 4.2 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 51.5 ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 75.3 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 95.8 | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 23. ± 5.9 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 22.6 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 24. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (Br- 2H2O) + H2O = (Br-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.7 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 28.9 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 48.1 ± 4.2 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 48.1 ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 104. | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. ± 4.6 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 17. ± 5.9 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 17.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 18. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (Br- 3H2O) + H2O = (Br-
4H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.02 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 26. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 45.6 ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 112. | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13.0 ± 2.9 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 12.1 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 14. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (Br- 4H2O) + H2O = (Br-
5H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 26. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 119. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.6 ± 5.0 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (Br- 5H2O) + H2O = (Br-
6H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 25. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 118. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 8.8 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (Br- 6H2O) + H2O = (Br-
7H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy estimated; B,M |
![]() | 10. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | N/A | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.44 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy estimated; B |
By formula: (Br- 7H2O) + H2O = (Br-
8H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 8H2O) + H2O = (Br-
9H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 9H2O) + H2O = (Br-
10H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 10H2O) + H2O = (Br-
11H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 11H2O) + H2O = (Br-
12H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 12H2O) + H2O = (Br-
13H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 13H2O) + H2O = (Br-
14H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 14H2O) + H2O = (Br-
15H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | -2. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 15H2O) + H2O = (Br-
16H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.6 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: Br- + H3N = (Br- H3N)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.2 ± 0.42 | kJ/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.9 | J/mol*K | HPMS | Evans, Keesee, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.37 ± 0.84 | kJ/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B |
By formula: Br- + Kr = (Br- Kr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.60 ± 0.42 | kJ/mol | LPES | Yourshaw, Lenzer, et al., 1998 | gas phase; given: 0.0795(.001) eV; B |
![]() | <11.3 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; B |
![]() | 8.37 | kJ/mol | Mobl | Gatland, 1984 | gas phase; B,M |
By formula: Br- + N2O = (Br- N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23. ± 1. | kJ/mol | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 75.7 | J/mol*K | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
By formula: (Br- N2O) + N2O = (Br-
2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23. ± 1. | kJ/mol | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.2 | J/mol*K | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
By formula: (Br- 2N2O) + N2O = (Br-
3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21. ± 1. | kJ/mol | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
By formula: Br- + O2S = (Br- O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 80.8 ± 8.4 | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 53. ± 11. | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B |
By formula: (Br- O2S) + HBr = (Br-
HBr
O2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.3 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M |
By formula: (Br- O2S) + HCl = (Br-
HCl
O2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 93.7 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.8 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M |
By formula: (Br- O2S) + O2S = (Br-
2O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 78.2 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
By formula: (Br- 2O2S) + O2S = (Br-
3O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 57.7 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
+
= BrO3S-
By formula: Br- + O3S = BrO3S-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 179. ± 11. | kJ/mol | CIDT | Hao, Gilbert, et al., 2006 | gas phase; B |
By formula: (Br- 4294967295Rb) + Rb = Br-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 111. ± 4.2 | kJ/mol | Ther | Miller, Leopold, et al., 1986 | gas phase; Extrapolated by polarizability and radius from experimental data.; B |
By formula: Br- + Xe = (Br- Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.1 ± 1.3 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; B |
![]() | 12.1 ± 0.42 | kJ/mol | LPES | Yourshaw, Lenzer, et al., 1998 | gas phase; Given: 0.12692(.0005) eV; B |
![]() | 14.2 | kJ/mol | Mobl | Gatland, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -4.9 ± 1.3 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; B |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhao, Yourshaw, et al., 1994
Zhao, Y.X.; Yourshaw, I.; Reiser, G.; Arnold, C.C.; Neumark, D.M.,
Study of the ArBr(-), ArI(-), and KrI(-) anions and the corresponding neutral van der Waals complexes by anion zero electron kinetic energy,
J. Chem. Phys., 1994, 101, 8, 6538, https://doi.org/10.1063/1.468500
. [all data]
Gatland, 1984
Gatland, I.R.,
Determination of Ion-Atom Potentials from Mobility Experiments.
in Swarms of Ions and Electrons In Gases, W. Lindinger, Ed., Springer-Verlag, NY,, 1984, 44. [all data]
Lobring, Hao, et al., 2003
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Notes
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- Symbols used in this document:
T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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