Bromine anion
Formula : Br-
Molecular weight : 79.905
IUPAC Standard InChI:
InChI=1S/BrH/h1H/p-1
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IUPAC Standard InChIKey:
CPELXLSAUQHCOX-UHFFFAOYSA-M
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CAS Registry Number: 24959-67-9
Chemical structure:
This structure is also available as a 2d Mol file
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Gas phase thermochemistry data
Go To: Top , Reaction thermochemistry data , Ion clustering data , References , Notes
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
Quantity
Value
Units
Method
Reference
Comment
S°gas,1 bar 39.075 cal/mol*K Review Chase, 1998 Data last reviewed in June, 1982
Reaction thermochemistry data
Go To: Top , Gas phase thermochemistry data , Ion clustering data , References , Notes
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the
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Reactions 1 to 50
( • ) + = ( • 2 )
By formula: ( Br- • H2 O ) + H2 O = ( Br- • 2 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.60 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 12.20 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 12.3 ± 1.0 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr H° 12.3 ± 1.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 18.0 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 22.9 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.2 ± 1.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 5.4 ± 1.4 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr G° 5.40 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
Δr G° 5.7 ± 2.0 kcal/mol TDAs Kebarle, Arshadi, et al., 1968 gas phase; B,M
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 H2 O ) + H2 O = ( Br- • 3 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.40 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 6.90 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 11.5 ± 1.0 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr H° 11.5 ± 1.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.5 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 24.8 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.7 ± 1.1 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 4.1 ± 1.4 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr G° 4.10 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
Δr G° 4.4 ± 2.0 kcal/mol TDAs Kebarle, Arshadi, et al., 1968 gas phase; B,M
+ = ( • )
By formula: Br- + H2 O = ( Br- • H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.70 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 11.70 ± 0.40 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 12.60 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Δr H° 12.7 kcal/mol HPMS Caldwell, Masucci, et al., 1989 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 14.7 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 18.4 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Δr S° 19.8 cal/mol*K MS Burdett and Hayhurst, 1982 gas phase; FLAME SOURCE, 1600 K; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.30 ± 0.80 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 7.0 ± 2.8 kcal/mol TDAs Burdett and Hayhurst, 1982 gas phase; B
Δr G° 7.0 ± 2.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
+ = ( • )
By formula: Br- + C7 H6 O2 = ( Br- • C7 H6 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 25.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 16.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
15.4 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
16.1 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C2 H3 N = ( Br- • C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.3 ± 1.0 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr H° 12.10 ± 0.40 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Δr H° 12.90 ± 0.40 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 12.9 ± 2.0 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B,M
Δr H° 12.9 kcal/mol HPMS Caldwell, Masucci, et al., 1989 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 12.2 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 16.5 cal/mol*K HPMS Yamdagni and Kebarle, 1972 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.70 ± 0.20 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr G° 8.8 ± 2.0 kcal/mol IMRE Tanabe, Morgon, et al., 1996 gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 1988 2; B
Δr G° 9.20 ± 0.70 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 8.0 ± 2.0 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B
+ = ( • )
By formula: Br- + C7 H5 F3 = ( Br- • C7 H5 F3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Δr H° 25.7 kcal/mol PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
16.0 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H6 O = ( Br- • C6 H6 O )
Free energy of reaction
+ = ( • )
By formula: Br- + HBr = ( Br- • HBr )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.6 ± 2.0 kcal/mol TDAs Caldwell and Kebarle, 1985 gas phase; B,M
Δr H° 17.5 kcal/mol FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, Δr H>; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.3 cal/mol*K PHPMS Caldwell and Kebarle, 1985 gas phase; M
Δr S° 22. cal/mol*K FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, Δr H>; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 13.9 ± 2.6 kcal/mol TDAs Caldwell and Kebarle, 1985 gas phase; B
Free energy of reaction
( • 3 ) + = ( • 4 )
By formula: ( Br- • 3 H2 O ) + H2 O = ( Br- • 4 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.00 ± 0.20 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 6.2 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 10.9 ± 1.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 26.2 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 26.8 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.10 ± 0.70 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 2.90 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
Δr G° 3.3 ± 2.0 kcal/mol TDAs Kebarle, Arshadi, et al., 1968 gas phase; B,M
+ =
By formula: Br- + H+ = HBr
Quantity
Value
Units
Method
Reference
Comment
Δr H° 323.540 ± 0.050 kcal/mol D-EA Blondel, Cacciani, et al., 1989 gas phase; reported: 27129.170±0.015 cm-1; B
Δr H° 323.4 ± 2.1 kcal/mol G+TS Taft and Bordwell, 1988 gas phase; B
Δr H° 320.60 kcal/mol N/A Check, Faust, et al., 2001 gas phase; F-; ; ΔS(acid)=19.2; ΔS(EA)=6.4; B
Quantity
Value
Units
Method
Reference
Comment
Δr G° 318.30 ± 0.15 kcal/mol H-TS Blondel, Cacciani, et al., 1989 gas phase; reported: 27129.170±0.015 cm-1; B
Δr G° 318.2 ± 2.0 kcal/mol IMRE Taft and Bordwell, 1988 gas phase; B
Δr G° 315.40 kcal/mol N/A Check, Faust, et al., 2001 gas phase; F-; ; ΔS(acid)=19.2; ΔS(EA)=6.4; B
+ = ( • )
By formula: Br- + C7 H7 NO2 = ( Br- • C7 H7 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H7 NO2 = ( Br- • C7 H7 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 16.2 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.8 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H3 F3 N2 O4 = ( Br- • C7 H3 F3 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.4 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
10.4 423. PHPMS Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H3 N3 O4 = ( Br- • C7 H3 N3 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 21.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 12.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
12.2 423. PHPMS Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C8 H3 F6 NO2 = ( Br- • C8 H3 F6 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
8.2 423. PHPMS Paul and Kebarle, 1991 gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H8 O = ( Br- • C7 H8 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.3 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 Cl = ( Br- • C6 H5 Cl )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C8 H11 N = ( Br- • C8 H11 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.7 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 F = ( Br- • C6 H5 F )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 10.6 ± 1.6 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 = ( Br- • C7 H8 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 0.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 Cl3 = ( Br- • C7 H5 Cl3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C8 H8 O = ( Br- • C8 H8 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 5.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
( • 3 ) + = ( • 4 )
By formula: ( Br- • 3 C2 H3 N ) + C2 H3 N = ( Br- • 4 C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.70 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 8.50 ± 0.80 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Δr H° 5.50 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.6 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 10.9 cal/mol*K HPMS Yamdagni and Kebarle, 1972 gas phase; Entropy change is questionable; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.8 ± 1.2 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 2.20 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B
+ = ( • )
By formula: Br- + C6 H5 NO3 = ( Br- • C6 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 28.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 18.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
18.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H6 O2 = ( Br- • C7 H6 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 25.2 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 15.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
15.5 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H5 ClO = ( Br- • C6 H5 ClO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 24.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 14.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
14.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H5 ClO = ( Br- • C6 H5 ClO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 24.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 14.4 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
14.4 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H4 FNO2 = ( Br- • C6 H4 FNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + CF3 C6 H4 OH = ( Br- • CF3 C6 H4 OH )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 26.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 16.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
16.9 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H4 N2 O4 = ( Br- • C6 H4 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 21.0 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 NO3 = ( Br- • C6 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 17.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
17.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 NO = ( Br- • C7 H5 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.0 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 17.3 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
17.3 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H4 N2 O2 = ( Br- • C7 H4 N2 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.9 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 N2 O2 = ( Br- • C7 H4 N2 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 NO = ( Br- • C7 H5 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 18.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
18.1 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 HF5 O = ( Br- • C6 HF5 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 25.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 15.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
15.9 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 NO = ( Br- • C7 H5 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 17.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
17.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H4 ClNO2 = ( Br- • C6 H4 ClNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 16.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 N2 O4 = ( Br- • C6 H4 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 ClNO2 = ( Br- • C6 H4 ClNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 FNO2 = ( Br- • C6 H4 FNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.4 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 F3 NO2 = ( Br- • C7 H4 F3 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.2 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.8 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 F3 NO2 = ( Br- • C7 H4 F3 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 16.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.0 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 FNO2 = ( Br- • C6 H4 FNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 NO3 = ( Br- • C7 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 N2 O2 = ( Br- • C7 H4 N2 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 NO3 = ( Br- • C7 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.7 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.3 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 N2 O4 = ( Br- • C6 H4 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 ClNO2 = ( Br- • C6 H4 ClNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H7 NO2 = ( Br- • C7 H7 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.9 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Ion clustering data
Go To: Top , Gas phase thermochemistry data , Reaction thermochemistry data , References , Notes
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the
reaction search for this species. This page allows searching
of all reactions involving this species. Searches may be limited
to ion clustering reactions. A general reaction search form is
also available .
Clustering reactions
+ = ( • )
By formula: Br- + Ar = ( Br- • Ar )
+ = Br3 Se-
By formula: Br- + Br2 Se = Br3 Se-
+ = ( • )
By formula: Br- + Br2 = ( Br- • Br2 )
+ = Br4 P-
By formula: Br- + Br3 P = Br4 P-
+ = CBr2 F3 -
By formula: Br- + CBrF3 = CBr2 F3 -
+ = ( • )
By formula: Br- + CHCl3 = ( Br- • CHCl3 )
+ = ( • )
By formula: Br- + CHN = ( Br- • CHN )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.4 ± 1.0 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B,M
Δr H° 16.0 ± 2.0 kcal/mol Est Larson and McMahon, 1984 gas phase; Extrapolated from other halide data; B
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.8 cal/mol*K PHPMS Meot-ner, Cybulski, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 13.5 ± 1.6 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B
( • ) + = ( • 2 )
By formula: ( Br- • CHN ) + CHN = ( Br- • 2 CHN )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 16.3 ± 1.0 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.7 cal/mol*K PHPMS Meot-ner, Cybulski, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.50 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 CHN ) + CHN = ( Br- • 3 CHN )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.8 ± 1.0 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 21.9 cal/mol*K PHPMS Meot-ner, Cybulski, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.30 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B
( • 3 ) + = ( • 4 )
By formula: ( Br- • 3 CHN ) + CHN = ( Br- • 4 CHN )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 10.4 ± 1.0 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.1 cal/mol*K PHPMS Meot-ner, Cybulski, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.80 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B
( • 4 ) + = ( • 5 )
By formula: ( Br- • 4 CHN ) + CHN = ( Br- • 5 CHN )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.1 ± 1.0 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 18.5 cal/mol*K PHPMS Meot-ner, Cybulski, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.60 kcal/mol TDAs Meot-ner, Cybulski, et al., 1988 gas phase; B
+ = CH2 BrO2 -
By formula: Br- + CH2 O2 = CH2 BrO2 -
+ = ( • )
By formula: Br- + CH3 Br = ( Br- • CH3 Br )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.2 ± 1.0 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr H° 9.20 ± 0.50 kcal/mol TDAs Dougherty and Roberts, 1974 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 14.0 cal/mol*K HPMS Dougherty and Roberts, 1974 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.60 ± 0.20 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr G° 5.00 ± 0.80 kcal/mol TDAs Dougherty and Roberts, 1974 gas phase; B
+ = ( • )
By formula: Br- + CH3 Cl = ( Br- • CH3 Cl )
+ = CH3 BrNO2 -
By formula: Br- + CH3 NO2 = CH3 BrNO2 -
+ = ( • )
By formula: Br- + CH4 O = ( Br- • CH4 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.50 ± 0.10 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr H° 13.9 ± 1.0 kcal/mol TDAs Hiraoka and Yamabe, 1991 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 17.6 cal/mol*K PHPMS Hiraoka and Yamabe, 1991 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.00 ± 0.10 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr G° 8.7 ± 2.0 kcal/mol TDAs Hiraoka and Yamabe, 1991 gas phase; B
Δr G° 8.4 ± 2.0 kcal/mol IMRE Tanabe, Morgon, et al., 1996 gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 1988 2; B
( • ) + = ( • 2 )
By formula: ( Br- • CH4 O ) + CH4 O = ( Br- • 2 CH4 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.00 ± 0.20 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr H° 12.5 ± 1.0 kcal/mol TDAs Hiraoka and Yamabe, 1991 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20.7 cal/mol*K PHPMS Hiraoka and Yamabe, 1991 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 5.62 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr G° 6.3 ± 2.0 kcal/mol TDAs Hiraoka and Yamabe, 1991 gas phase; B
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 CH4 O ) + CH4 O = ( Br- • 3 CH4 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 9.50 ± 0.50 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr H° 10.6 ± 1.0 kcal/mol TDAs Hiraoka and Yamabe, 1991 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 21.6 cal/mol*K PHPMS Hiraoka and Yamabe, 1991 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.25 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr G° 4.2 ± 2.0 kcal/mol TDAs Hiraoka and Yamabe, 1991 gas phase; B
( • 3 ) + = ( • 4 )
By formula: ( Br- • 3 CH4 O ) + CH4 O = ( Br- • 4 CH4 O )
( • 4 ) + = ( • 5 )
By formula: ( Br- • 4 CH4 O ) + CH4 O = ( Br- • 5 CH4 O )
( • 5 ) + = ( • 6 )
By formula: ( Br- • 5 CH4 O ) + CH4 O = ( Br- • 6 CH4 O )
( • 6 ) + = ( • 7 )
By formula: ( Br- • 6 CH4 O ) + CH4 O = ( Br- • 7 CH4 O )
( • 7 ) + = ( • 8 )
By formula: ( Br- • 7 CH4 O ) + CH4 O = ( Br- • 8 CH4 O )
( • 8 ) + = ( • 9 )
By formula: ( Br- • 8 CH4 O ) + CH4 O = ( Br- • 9 CH4 O )
( • 9 ) + = ( • 10 )
By formula: ( Br- • 9 CH4 O ) + CH4 O = ( Br- • 10 CH4 O )
+ = CH4 Br-
By formula: Br- + CH4 = CH4 Br-
+ = ( • )
By formula: Br- + CO2 = ( Br- • CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 5.3 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995 gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Δr H° 6.7 ± 1.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1987 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 16.5 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1987 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 1.8 ± 2.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1987 gas phase; B
( • ) + = ( • 2 )
By formula: ( Br- • CO2 ) + CO2 = ( Br- • 2 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 5.1 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Δr H° 6.0 ± 1.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1987 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.0 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1987 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 0.3 ± 2.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1987 gas phase; B
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 CO2 ) + CO2 = ( Br- • 3 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 5.1 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 3 ) + = ( • 4 )
By formula: ( Br- • 3 CO2 ) + CO2 = ( Br- • 4 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 5.2 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 4 ) + = ( • 5 )
By formula: ( Br- • 4 CO2 ) + CO2 = ( Br- • 5 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 4.2 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 5 ) + = ( • 6 )
By formula: ( Br- • 5 CO2 ) + CO2 = ( Br- • 6 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 4.0 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 6 ) + = ( • 7 )
By formula: ( Br- • 6 CO2 ) + CO2 = ( Br- • 7 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 3.6 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 7 ) + = ( • 8 )
By formula: ( Br- • 7 CO2 ) + CO2 = ( Br- • 8 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 3.7 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 8 ) + = ( • 9 )
By formula: ( Br- • 8 CO2 ) + CO2 = ( Br- • 9 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 1.8 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 9 ) + = ( • 10 )
By formula: ( Br- • 9 CO2 ) + CO2 = ( Br- • 10 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 1.8 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
( • 10 ) + = ( • 11 )
By formula: ( Br- • 10 CO2 ) + CO2 = ( Br- • 11 CO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 0.5 ± 2.0 kcal/mol PDis Arnold, Bradforth, et al., 1995, 2 gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
+ = ( • )
By formula: Br- + CS2 = ( Br- • CS2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.30 ± 0.20 kcal/mol TDAs Hiraoka, Fujimaki, et al., 1993 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 13.0 cal/mol*K PHPMS Hiraoka, Fujimaki, et al., 1993 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.4 ± 1.0 kcal/mol TDAs Hiraoka, Fujimaki, et al., 1993 gas phase; B
( • ) + = ( • 2 )
By formula: ( Br- • CS2 ) + CS2 = ( Br- • 2 CS2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 7.30 ± 0.20 kcal/mol TDAs Hiraoka, Fujimaki, et al., 1993 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20.4 cal/mol*K PHPMS Hiraoka, Fujimaki, et al., 1993 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 1.2 ± 1.0 kcal/mol TDAs Hiraoka, Fujimaki, et al., 1993 gas phase; B
+ = C2 BrF4 -
By formula: Br- + C2 F4 = C2 BrF4 -
Quantity
Value
Units
Method
Reference
Comment
Δr H° 7.10 ± 0.50 kcal/mol TDAs Hiraoka, Mochizuki, et al., 2008 gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374 , 11CHA/DEN; B
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.33 ± 0.50 kcal/mol TDAs Hiraoka, Mochizuki, et al., 2008 gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374 , 11CHA/DEN; B
+ = C2 H2 Br-
By formula: Br- + C2 H2 = C2 H2 Br-
+ = ( • )
By formula: Br- + C2 H3 N = ( Br- • C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.3 ± 1.0 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr H° 12.10 ± 0.40 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Δr H° 12.90 ± 0.40 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 12.9 ± 2.0 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B,M
Δr H° 12.9 kcal/mol HPMS Caldwell, Masucci, et al., 1989 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 12.2 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 16.5 cal/mol*K HPMS Yamdagni and Kebarle, 1972 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.70 ± 0.20 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr G° 8.8 ± 2.0 kcal/mol IMRE Tanabe, Morgon, et al., 1996 gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 1988 2; B
Δr G° 9.20 ± 0.70 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 8.0 ± 2.0 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B
( • ) + = ( • 2 )
By formula: ( Br- • C2 H3 N ) + C2 H3 N = ( Br- • 2 C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.70 ± 0.40 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 11.50 ± 0.70 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Δr H° 11.80 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 17.0 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 20.4 cal/mol*K HPMS Yamdagni and Kebarle, 1972 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.6 ± 1.3 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 5.80 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 C2 H3 N ) + C2 H3 N = ( Br- • 3 C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 9.20 ± 0.40 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 10.40 ± 0.70 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Δr H° 10.00 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 16.7 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 21.7 cal/mol*K HPMS Yamdagni and Kebarle, 1972 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.2 ± 1.3 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 3.60 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B
( • 3 ) + = ( • 4 )
By formula: ( Br- • 3 C2 H3 N ) + C2 H3 N = ( Br- • 4 C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.70 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 8.50 ± 0.80 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Δr H° 5.50 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.6 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 10.9 cal/mol*K HPMS Yamdagni and Kebarle, 1972 gas phase; Entropy change is questionable; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.8 ± 1.2 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 2.20 kcal/mol TDAs Yamdagni and Kebarle, 1972 gas phase; B
( • 4 ) + = ( • 5 )
By formula: ( Br- • 4 C2 H3 N ) + C2 H3 N = ( Br- • 5 C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.50 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 5.80 ± 0.90 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.2 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 1.8 ± 1.3 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
( • 5 ) + = ( • 6 )
By formula: ( Br- • 5 C2 H3 N ) + C2 H3 N = ( Br- • 6 C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.00 ± 0.20 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 5.5 ± 1.0 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.5 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 1.20 ± 0.90 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
( • 6 ) + = ( • 7 )
By formula: ( Br- • 6 C2 H3 N ) + C2 H3 N = ( Br- • 7 C2 H3 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 7.70 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 3.0 ± 1.1 kcal/mol N/A Markovich, Perera, et al., 1996 gas phase; B
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.9 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 0.8 ± 1.3 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
( • 7 ) + = ( • 8 )
By formula: ( Br- • 7 C2 H3 N ) + C2 H3 N = ( Br- • 8 C2 H3 N )
( • 8 ) + = ( • 9 )
By formula: ( Br- • 8 C2 H3 N ) + C2 H3 N = ( Br- • 9 C2 H3 N )
( • 9 ) + = ( • 10 )
By formula: ( Br- • 9 C2 H3 N ) + C2 H3 N = ( Br- • 10 C2 H3 N )
( • 10 ) + = ( • 11 )
By formula: ( Br- • 10 C2 H3 N ) + C2 H3 N = ( Br- • 11 C2 H3 N )
( • 11 ) + = ( • 12 )
By formula: ( Br- • 11 C2 H3 N ) + C2 H3 N = ( Br- • 12 C2 H3 N )
( • 12 ) + = ( • 13 )
By formula: ( Br- • 12 C2 H3 N ) + C2 H3 N = ( Br- • 13 C2 H3 N )
( • 13 ) + = ( • 14 )
By formula: ( Br- • 13 C2 H3 N ) + C2 H3 N = ( Br- • 14 C2 H3 N )
+ = ( • )
By formula: Br- + C2 H5 Br = ( Br- • C2 H5 Br )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.0 ± 1.0 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr H° 11.60 kcal/mol TDAs Dougherty, 1974 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.2 cal/mol*K HPMS Dougherty, 1974 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 5.90 ± 0.20 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr G° 5.90 kcal/mol TDAs Dougherty, 1974 gas phase; B
+ = ( • )
By formula: Br- + C2 H5 Cl = ( Br- • C2 H5 Cl )
+ = ( • )
By formula: Br- + C2 H6 OS = ( Br- • C2 H6 OS )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.30 kcal/mol TDAs Magnera, Caldwell, et al., 1984 gas phase; B,M
Δr H° 17.2 kcal/mol HPMS Caldwell, Masucci, et al., 1989 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 21.4 cal/mol*K PHPMS Magnera, Caldwell, et al., 1984 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.90 kcal/mol TDAs Magnera, Caldwell, et al., 1984 gas phase; B
( • ) + = ( • 2 )
By formula: ( Br- • C2 H6 OS ) + C2 H6 OS = ( Br- • 2 C2 H6 OS )
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 C2 H6 OS ) + C2 H6 OS = ( Br- • 3 C2 H6 OS )
+ = C2 H6 BrO-
By formula: Br- + C2 H6 O = C2 H6 BrO-
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.10 ± 0.20 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.20 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr G° 8.8 ± 2.0 kcal/mol IMRE Tanabe, Morgon, et al., 1996 gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 1988 2; B
+ 2 = C4 H12 BrO2 -
By formula: Br- + 2 C2 H6 O = C4 H12 BrO2 -
+ 3 = C6 H18 BrO3 -
By formula: Br- + 3 C2 H6 O = C6 H18 BrO3 -
+ = C3 BrF6 -
By formula: Br- + C3 F6 = C3 BrF6 -
+ = ( • )
By formula: Br- + C3 H7 Br = ( Br- • C3 H7 Br )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.2 ± 1.0 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr H° 12.20 kcal/mol TDAs Dougherty, 1974 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.9 cal/mol*K HPMS Dougherty, 1974 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.30 ± 0.20 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr G° 6.30 kcal/mol TDAs Dougherty, 1974 gas phase; B
+ = ( • )
By formula: Br- + C3 H7 Br = ( Br- • C3 H7 Br )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.60 kcal/mol TDAs Dougherty, 1974 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.8 cal/mol*K HPMS Dougherty, 1974 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 5.70 kcal/mol TDAs Dougherty, 1974 gas phase; B
+ = ( • )
By formula: Br- + C3 H7 Cl = ( Br- • C3 H7 Cl )
+ = ( • )
By formula: Br- + C3 H7 Cl = ( Br- • C3 H7 Cl )
+ = C3 H8 BrO-
By formula: Br- + C3 H8 O = C3 H8 BrO-
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.40 ± 0.20 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.35 kcal/mol TDAs Bogdanov, Peschke, et al., 1999 gas phase; B
Δr G° 9.2 ± 2.0 kcal/mol IMRE Tanabe, Morgon, et al., 1996 gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 1988 2; B
+ 2 = C6 H16 BrO2 -
By formula: Br- + 2 C3 H8 O = C6 H16 BrO2 -
+ = ( • )
By formula: Br- + C4 H9 Br = ( Br- • C4 H9 Br )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.90 kcal/mol TDAs Dougherty, 1974 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 21.8 cal/mol*K HPMS Dougherty, 1974 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.40 kcal/mol TDAs Dougherty, 1974 gas phase; B
+ = ( • )
By formula: Br- + C4 H9 Br = ( Br- • C4 H9 Br )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.6 ± 1.0 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr H° 12.40 kcal/mol TDAs Dougherty, 1974 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.3 cal/mol*K HPMS Dougherty, 1974 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.30 ± 0.20 kcal/mol TDAs Li, Ross, et al., 1996 gas phase; B
Δr G° 6.70 kcal/mol TDAs Dougherty, 1974 gas phase; B
+ = ( • )
By formula: Br- + C4 H9 Cl = ( Br- • C4 H9 Cl )
+ = C4 H10 BrO-
By formula: Br- + C4 H10 O = C4 H10 BrO-
+ 2 = C8 H20 BrO2 -
By formula: Br- + 2 C4 H10 O = C8 H20 BrO2 -
+ 3 = C12 H30 BrO3 -
By formula: Br- + 3 C4 H10 O = C12 H30 BrO3 -
+ = C5 BrF8 -
By formula: Br- + C5 F8 = C5 BrF8 -
+ = ( • )
By formula: Br- + C5 H11 Br = ( Br- • C5 H11 Br )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.40 kcal/mol TDAs Dougherty, 1974 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 25.2 cal/mol*K HPMS Dougherty, 1974 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.90 kcal/mol TDAs Dougherty, 1974 gas phase; B
+ = ( • )
By formula: Br- + C6 F6 = ( Br- • C6 F6 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 13.9 ± 1.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1987, 2 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.4 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1987, 2 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.1 ± 1.6 kcal/mol TDAs Hiraoka, Mizuse, et al., 1987, 2 gas phase; B
( • ) + = ( • 2 )
By formula: ( Br- • C6 F6 ) + C6 F6 = ( Br- • 2 C6 F6 )
+ = ( • )
By formula: Br- + C6 HF5 O = ( Br- • C6 HF5 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 25.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 15.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
15.9 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H3 N3 O6 = ( Br- • C6 H3 N3 O6 )
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 13.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
13.1 423. PHPMS Paul and Kebarle, 1991 gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H4 ClNO2 = ( Br- • C6 H4 ClNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 ClNO2 = ( Br- • C6 H4 ClNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 16.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 ClNO2 = ( Br- • C6 H4 ClNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 FNO2 = ( Br- • C6 H4 FNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.4 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 FNO2 = ( Br- • C6 H4 FNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 FNO2 = ( Br- • C6 H4 FNO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 N2 O4 = ( Br- • C6 H4 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 N2 O4 = ( Br- • C6 H4 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H4 N2 O4 = ( Br- • C6 H4 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 21.0 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 ClO = ( Br- • C6 H5 ClO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 21.2 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 ClO = ( Br- • C6 H5 ClO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 24.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 14.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
14.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H5 ClO = ( Br- • C6 H5 ClO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 24.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 14.4 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
14.4 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H5 Cl = ( Br- • C6 H5 Cl )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 FO = ( Br- • C6 H5 FO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.9 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 FO = ( Br- • C6 H5 FO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 23.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 13.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 FO = ( Br- • C6 H5 FO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 23.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 13.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 F = ( Br- • C6 H5 F )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 10.6 ± 1.6 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 NO = ( Br- • C6 H5 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 13.7 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Quantity
Value
Units
Method
Reference
Comment
Δr G° 5.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
+ = ( • )
By formula: Br- + C6 H5 NO2 = ( Br- • C6 H5 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.0 ± 1.8 kcal/mol TDAs Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20.2 cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.5 ± 1.0 kcal/mol TDAs Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H5 NO3 = ( Br- • C6 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 28.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 18.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
18.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H5 NO3 = ( Br- • C6 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 17.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
17.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C6 H6 O = ( Br- • C6 H6 O )
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H6 = ( Br- • C6 H6 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 9.0 ± 2.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988, 2 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 17.0 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988, 2 gas phase; M
Δr S° 17. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; B
Δr G° 3.9 ± 2.6 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988, 2 gas phase; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H7 NO = ( Br- • C6 H7 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.8 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H7 NO = ( Br- • C6 H7 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C6 H7 N = ( Br- • C6 H7 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H3 F3 N2 O4 = ( Br- • C7 H3 F3 N2 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.4 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
10.4 423. PHPMS Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H3 N3 O4 = ( Br- • C7 H3 N3 O4 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 21.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 12.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
12.2 423. PHPMS Paul and Kebarle, 1991 gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H4 F3 NO2 = ( Br- • C7 H4 F3 NO2 )
+ = ( • )
By formula: Br- + C7 H4 F3 NO2 = ( Br- • C7 H4 F3 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.2 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.8 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 F3 NO2 = ( Br- • C7 H4 F3 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 16.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.0 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 N2 O2 = ( Br- • C7 H4 N2 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.9 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 N2 O2 = ( Br- • C7 H4 N2 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H4 N2 O2 = ( Br- • C7 H4 N2 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 Cl3 = ( Br- • C7 H5 Cl3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 F3 O = ( Br- • C7 H5 F3 O )
Free energy of reaction
+ = ( • )
By formula: Br- + CF3 C6 H4 OH = ( Br- • CF3 C6 H4 OH )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 26.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 16.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
16.9 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 F3 O = ( Br- • C7 H5 F3 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 24.1 kcal/mol PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
14.4 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 F3 = ( Br- • C7 H5 F3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Δr H° 25.7 kcal/mol PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
16.0 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 NO = ( Br- • C7 H5 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.0 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 17.3 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
17.3 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 NO = ( Br- • C7 H5 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 18.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
18.1 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 NO = ( Br- • C7 H5 NO )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 27.4 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 17.7 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
17.7 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H5 NO3 = ( Br- • C7 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 19.7 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.3 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 NO3 = ( Br- • C7 H5 NO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H5 N = ( Br- • C7 H5 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.7 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H6 O = ( Br- • C7 H6 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 13.2 kcal/mol PHPMS Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H6 O2 = ( Br- • C7 H6 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 9.8 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H6 O2 = ( Br- • C7 H6 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 25.2 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 15.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
15.5 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H6 O2 = ( Br- • C7 H6 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 25.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 16.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
15.4 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
16.1 423. PHPMS Paul and Kebarle, 1990 gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C7 H7 NO2 = ( Br- • C7 H7 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.5 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H7 NO2 = ( Br- • C7 H7 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 15.9 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.5 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H7 NO2 = ( Br- • C7 H7 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 16.2 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.8 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 O = ( Br- • C7 H8 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 O = ( Br- • C7 H8 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.8 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.3 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 O = ( Br- • C7 H8 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.3 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 O = ( Br- • C7 H8 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 10.9 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 O2 = ( Br- • C7 H8 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 22.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 12.4 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 O2 = ( Br- • C7 H8 O2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 21.0 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23. cal/mol*K N/A Paul and Kebarle, 1990 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.3 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1990 gas phase; ΔGaff at 423 K; B
Free energy of reaction
+ = ( • )
By formula: Br- + C7 H8 = ( Br- • C7 H8 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 8.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 0.1 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C8 H3 F6 NO2 = ( Br- • C8 H3 F6 NO2 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 17.6 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 8.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B
Free energy of reaction
Δr G° (kcal/mol)
T (K)
Method
Reference
Comment
8.2 423. PHPMS Paul and Kebarle, 1991 gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + C8 H8 O = ( Br- • C8 H8 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 14.1 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 5.6 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
+ = ( • )
By formula: Br- + C8 H8 O2 = ( Br- • C8 H8 O2 )
+ = ( • )
By formula: Br- + C8 H11 N = ( Br- • C8 H11 N )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.7 ± 1.8 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 20. cal/mol*K N/A Paul and Kebarle, 1991 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.2 ± 1.0 kcal/mol IMRE Paul and Kebarle, 1991 gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Free energy of reaction
( • 4294967295 ) + =
By formula: ( Br- • 4294967295 Cs ) + Cs = Br-
Quantity
Value
Units
Method
Reference
Comment
Δr H° 29.80 ± 0.96 kcal/mol N/A Miller, Leopold, et al., 1986 gas phase; Extrapolated by polarizability and radius from experimental data.; B
+ = ( • )
By formula: Br- + HBr = ( Br- • HBr )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.6 ± 2.0 kcal/mol TDAs Caldwell and Kebarle, 1985 gas phase; B,M
Δr H° 17.5 kcal/mol FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, Δr H>; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.3 cal/mol*K PHPMS Caldwell and Kebarle, 1985 gas phase; M
Δr S° 22. cal/mol*K FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, Δr H>; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 13.9 ± 2.6 kcal/mol TDAs Caldwell and Kebarle, 1985 gas phase; B
Free energy of reaction
( • ) + = ( • 2 )
By formula: ( Br- • HBr ) + HBr = ( Br- • 2 HBr )
Bond type: Hydrogen bond (negative ion to hydride)
( • ) + = ( • • )
By formula: ( Br- • HBr ) + O2 S = ( Br- • O2 S • HBr )
+ = ( • )
By formula: Br- + HCl = ( Br- • HCl )
Bond type: Hydrogen bond (negative ion to hydride)
( • ) + = ( • 2 )
By formula: ( Br- • HCl ) + HCl = ( Br- • 2 HCl )
Bond type: Hydrogen bond (negative ion to hydride)
( • ) + = ( • • )
By formula: ( Br- • HCl ) + O2 S = ( Br- • O2 S • HCl )
+ = ( • )
By formula: Br- + HF = ( Br- • HF )
Bond type: Hydrogen bond (negative ion to hydride)
+ = ( • )
By formula: Br- + HNO3 = ( Br- • HNO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 20.0 kcal/mol FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), Δr H>; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 18.5 cal/mol*K FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), Δr H>; M
Free energy of reaction
( • ) + = ( • 2 )
By formula: ( Br- • HNO3 ) + HNO3 = ( Br- • 2 HNO3 )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 18.1 kcal/mol FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 23.6 cal/mol*K N/A Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 11.1 kcal/mol FA Davidson, Fehsenfeld, et al., 1977 gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M
+ = ( • )
By formula: Br- + H2 O = ( Br- • H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.70 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 11.70 ± 0.40 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 12.60 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Δr H° 12.7 kcal/mol HPMS Caldwell, Masucci, et al., 1989 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 14.7 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 18.4 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Δr S° 19.8 cal/mol*K MS Burdett and Hayhurst, 1982 gas phase; FLAME SOURCE, 1600 K; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 7.30 ± 0.80 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 7.0 ± 2.8 kcal/mol TDAs Burdett and Hayhurst, 1982 gas phase; B
Δr G° 7.0 ± 2.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
( • ) + = ( • 2 )
By formula: ( Br- • H2 O ) + H2 O = ( Br- • 2 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.60 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 12.20 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 12.3 ± 1.0 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr H° 12.3 ± 1.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 18.0 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 22.9 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 6.2 ± 1.0 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 5.4 ± 1.4 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr G° 5.40 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
Δr G° 5.7 ± 2.0 kcal/mol TDAs Kebarle, Arshadi, et al., 1968 gas phase; B,M
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 H2 O ) + H2 O = ( Br- • 3 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.40 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 6.90 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 11.5 ± 1.0 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr H° 11.5 ± 1.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 22.5 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 24.8 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 4.7 ± 1.1 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 4.1 ± 1.4 kcal/mol TDAs Payzant, Yamdagni, et al., 1971 gas phase; B
Δr G° 4.10 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
Δr G° 4.4 ± 2.0 kcal/mol TDAs Kebarle, Arshadi, et al., 1968 gas phase; B,M
( • 3 ) + = ( • 4 )
By formula: ( Br- • 3 H2 O ) + H2 O = ( Br- • 4 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 11.00 ± 0.20 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 6.2 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr H° 10.9 ± 1.0 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 26.2 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Δr S° 26.8 cal/mol*K HPMS Arshadi, Yamdagni, et al., 1970 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 3.10 ± 0.70 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
Δr G° 2.90 kcal/mol TDAs Arshadi, Yamdagni, et al., 1970 gas phase; B
Δr G° 3.3 ± 2.0 kcal/mol TDAs Kebarle, Arshadi, et al., 1968 gas phase; B,M
( • 4 ) + = ( • 5 )
By formula: ( Br- • 4 H2 O ) + H2 O = ( Br- • 5 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 10.80 ± 0.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 6.2 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity
Value
Units
Method
Reference
Comment
Δr S° 28.4 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.3 ± 1.2 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
( • 5 ) + = ( • 6 )
By formula: ( Br- • 5 H2 O ) + H2 O = ( Br- • 6 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 10.30 ± 0.50 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B,M
Δr H° 6.0 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity
Value
Units
Method
Reference
Comment
Δr S° 28.2 cal/mol*K PHPMS Hiraoka, Mizuse, et al., 1988 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 1.8 ± 2.1 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; B
( • 6 ) + = ( • 7 )
By formula: ( Br- • 6 H2 O ) + H2 O = ( Br- • 7 H2 O )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 10.00 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; Entropy estimated; B,M
Δr H° 2.5 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; B
Quantity
Value
Units
Method
Reference
Comment
Δr S° 29. cal/mol*K N/A Hiraoka, Mizuse, et al., 1988 gas phase; Entropy change calculated or estimated; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 1.30 kcal/mol TDAs Hiraoka, Mizuse, et al., 1988 gas phase; Entropy estimated; B
( • 7 ) + = ( • 8 )
By formula: ( Br- • 7 H2 O ) + H2 O = ( Br- • 8 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 1.6 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 8 ) + = ( • 9 )
By formula: ( Br- • 8 H2 O ) + H2 O = ( Br- • 9 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 0.7 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 9 ) + = ( • 10 )
By formula: ( Br- • 9 H2 O ) + H2 O = ( Br- • 10 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 1.6 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 10 ) + = ( • 11 )
By formula: ( Br- • 10 H2 O ) + H2 O = ( Br- • 11 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 1.6 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 11 ) + = ( • 12 )
By formula: ( Br- • 11 H2 O ) + H2 O = ( Br- • 12 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 2.5 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 12 ) + = ( • 13 )
By formula: ( Br- • 12 H2 O ) + H2 O = ( Br- • 13 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 1.8 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 13 ) + = ( • 14 )
By formula: ( Br- • 13 H2 O ) + H2 O = ( Br- • 14 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 3.2 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 14 ) + = ( • 15 )
By formula: ( Br- • 14 H2 O ) + H2 O = ( Br- • 15 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° -0.5 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
( • 15 ) + = ( • 16 )
By formula: ( Br- • 15 H2 O ) + H2 O = ( Br- • 16 H2 O )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 2.3 ± 2.3 kcal/mol N/A Markovich, Pollack, et al., 1994 gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
+ = ( • )
By formula: Br- + H3 N = ( Br- • H3 N )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 7.70 ± 0.10 kcal/mol TDAs Evans, Keesee, et al., 1987 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.1 cal/mol*K HPMS Evans, Keesee, et al., 1987 gas phase; M
Quantity
Value
Units
Method
Reference
Comment
Δr G° 2.00 ± 0.20 kcal/mol TDAs Evans, Keesee, et al., 1987 gas phase; B
+ = ( • )
By formula: Br- + Kr = ( Br- • Kr )
+ = ( • )
By formula: Br- + N2 O = ( Br- • N2 O )
( • ) + = ( • 2 )
By formula: ( Br- • N2 O ) + N2 O = ( Br- • 2 N2 O )
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 N2 O ) + N2 O = ( Br- • 3 N2 O )
+ = ( • )
By formula: Br- + O2 S = ( Br- • O2 S )
( • ) + = ( • • )
By formula: ( Br- • O2 S ) + HBr = ( Br- • HBr • O2 S )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 12.2 kcal/mol PHPMS Caldwell and Kebarle, 1985 gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 19.2 cal/mol*K PHPMS Caldwell and Kebarle, 1985 gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M
( • ) + = ( • • )
By formula: ( Br- • O2 S ) + HCl = ( Br- • HCl • O2 S )
Bond type: Hydrogen bond (negative ion to hydride)
Quantity
Value
Units
Method
Reference
Comment
Δr H° 22.4 kcal/mol PHPMS Caldwell and Kebarle, 1985 gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M
Quantity
Value
Units
Method
Reference
Comment
Δr S° 18.6 cal/mol*K PHPMS Caldwell and Kebarle, 1985 gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M
( • ) + = ( • 2 )
By formula: ( Br- • O2 S ) + O2 S = ( Br- • 2 O2 S )
( • 2 ) + = ( • 3 )
By formula: ( Br- • 2 O2 S ) + O2 S = ( Br- • 3 O2 S )
+ = BrO3 S-
By formula: Br- + O3 S = BrO3 S-
( • 4294967295 ) + =
By formula: ( Br- • 4294967295 Rb ) + Rb = Br-
Quantity
Value
Units
Method
Reference
Comment
Δr H° 26.6 ± 1.0 kcal/mol Ther Miller, Leopold, et al., 1986 gas phase; Extrapolated by polarizability and radius from experimental data.; B
+ = ( • )
By formula: Br- + Xe = ( Br- • Xe )
Quantity
Value
Units
Method
Reference
Comment
Δr H° 3.60 ± 0.30 kcal/mol TDAs Wada, Kikkawa, et al., 2007 gas phase; B
Δr H° 2.90 ± 0.10 kcal/mol LPES Yourshaw, Lenzer, et al., 1998 gas phase; Given: 0.12692(.0005) eV; B
Δr H° 3.40 kcal/mol Mobl Gatland, 1984 gas phase; B,M
Quantity
Value
Units
Method
Reference
Comment
Δr G° -1.17 ± 0.30 kcal/mol TDAs Wada, Kikkawa, et al., 2007 gas phase; B
References
Go To: Top , Gas phase thermochemistry data , Reaction thermochemistry data , Ion clustering data , Notes
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
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Solvation of Halide Ions with H2 O and CH3 CN in the Gas Phase ,
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Markovich, Pollack, et al., 1994
Markovich, G. ; Pollack, S. ; Giniger, R. ; Cheshnovsky, O. ,
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Payzant, Yamdagni, et al., 1971
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Hydration of CN-, NO2 -, NO3 -, and HO- in the gas phase ,
Can. J. Chem. , 1971, 49, 3308. [all data ]
Arshadi, Yamdagni, et al., 1970
Arshadi, M. ; Yamdagni, R. ; Kebarle, P. ,
Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions ,
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Kebarle, Arshadi, et al., 1968
Kebarle, P. ; Arshadi, M. ; Scarborough, J. ,
Hydration of Negative Ions in the Gas Phase ,
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Caldwell, Masucci, et al., 1989
Caldwell, G.W. ; Masucci, J.A. ; Ikonomou, M.G. ,
Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions ,
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Burdett and Hayhurst, 1982
Burdett, N.A. ; Hayhurst, A.N. ,
Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer. ,
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Paul and Kebarle, 1990
Paul, G.J.C. ; Kebarle, P. ,
Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-) ,
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High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions. ,
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Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules ,
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Paul and Kebarle, 1991
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Larson, J.W. ; McMahon, T.B. ,
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Walker, B.W. ; Sunderlin, L.S. ,
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Notes
Go To: Top , Gas phase thermochemistry data , Reaction thermochemistry data , Ion clustering data , References
Symbols used in this document:
S°gas,1 bar
Entropy of gas at standard conditions (1 bar)
T
Temperature
Δr G°
Free energy of reaction at standard conditions
Δr H°
Enthalpy of reaction at standard conditions
Δr S°
Entropy of reaction at standard conditions
Data from NIST Standard Reference Database 69:
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