Chloropropylmercury


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-171.8 ± 3.3kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -24.9 ± 5.0 kJ/mol for the enthalpy of formation of Hg(Pr)2(l).

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C6H14Hg (l) + Cl2Hg (cr) = 2C3H7ClHg (cr)

By formula: C6H14Hg (l) + Cl2Hg (cr) = 2C3H7ClHg (cr)

Quantity Value Units Method Reference Comment
Δr-88.6 ± 1.3kJ/molRSCMortimer, Pritchard, et al., 1952Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.5 ± 0.2PINekrasov, Zagorevskii, et al., 1992LL
10.15 ± 0.05PEBaidin, Timoshenko, et al., 1985Vertical value; LBLHLM
10.15 ± 0.05PEBaidin, Chizhov, et al., 1981Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H4ClHg+10.5 ± 0.2CH3PINekrasov, Zagorevskii, et al., 1992LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Mortimer, Pritchard, et al., 1952
Mortimer, C.T.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. Part V.?Mercury di-propyl and mercury di-isopropyl, Trans. Faraday Soc., 1952, 48, 220, https://doi.org/10.1039/tf9524800220 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Nekrasov, Zagorevskii, et al., 1992
Nekrasov, Y.S.; Zagorevskii, D.V.; Mikeladze, M.S., Mass spectrometry of organomercury compounds, Organomet. Chem. USSR, 1992, 5, 237, In original 499. [all data]

Baidin, Timoshenko, et al., 1985
Baidin, V.N.; Timoshenko, M.M.; Chizhov, Y.V.; Ustynyuk, Y.A.; Kritskaya, I.I., Photoelectron spectra nad the structure of organomercury compounds, J. Organomet. Chem., 1985, 292, 55. [all data]

Baidin, Chizhov, et al., 1981
Baidin, V.N.; Chizhov, Y.V.; Timoshenko, M.M.; Sokolikova, O.K.; Grishin, Y.K.; Ustynyuk, Y.A., The photoelectron spectra of alkylmercury chlorides, J. Struct. Chem., 1981, 22, 616, In original 164. [all data]


Notes

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