Thiophosphoryl fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.1 ± 0.3EIKiser, Dillard, et al., 1969RDSH
11.05 ± 0.035PEElbel and Dieck, 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
PF+22.9 ± 0.4?EIKiser, Dillard, et al., 1969RDSH
PF2+17.2 ± 0.3?EIKiser, Dillard, et al., 1969RDSH
PSF2+16.0 ± 0.2FEIKiser, Dillard, et al., 1969RDSH
PF3+14.3 ± 0.2SEIKiser, Dillard, et al., 1969RDSH
PS+19.2 ± 0.5?EIKiser, Dillard, et al., 1969RDSH

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + Thiophosphoryl fluoride = (Fluorine anion • Thiophosphoryl fluoride)

By formula: F- + F3PS = (F- • F3PS)

Quantity Value Units Method Reference Comment
Δr201. ± 38.kJ/molIMRBRhyne and Dillard, 1971gas phase; Fluoride Affinity: between SF4, SF5. Original value 32±10, now altered with new aff.

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C     Symmetry Number σ = 3


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1 1 PF3 s-str 981  B 981 VS gas 969 p liq.
a1 2 PS str 695  B 695 M gas 696 p liq.
a1 3 PF3 s-deform 440  B 440 M gas 441 p liq.
e 4 PF3 d-str 945  B 945 VS gas 937 dp liq.
e 5 PF3 d-deform 402  C 402 M gas 404 dp liq.
e 6 PF3 rock 275  B 275 W gas 276 dp liq.

Source: Shimanouchi, 1972

Notes

VSVery strong
MMedium
WWeak
pPolarized
dpDepolarized
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]

Elbel and Dieck, 1976
Elbel, S.; Dieck, H.t., Photoelectron spectra of group 5 compounds. Part IV. A study of the E-X bond in R3EX compounds (R = Me or F; E = N or P; X = O or S), J. Chem. Soc. Dalton Trans., 1976, 1757. [all data]

Rhyne and Dillard, 1971
Rhyne, T.C.; Dillard, J.G., Reactions of gaseous inorganic negative ions: III. SF6- with POF3 and PSF3, Int. J. Mass Spectrom. Ion Phys., 1971, 7, 371. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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