Thiophosphoryl fluoride
- Formula: F3PS
- Molecular weight: 120.034
- IUPAC Standard InChI: InChI=1S/FH2O2PS/c1-4(2,3)5/h(H2,2,3,5)
- IUPAC Standard InChIKey: FDYJNMHGRBMQLJ-UHFFFAOYSA-N
- CAS Registry Number: 2404-52-6
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.1 ± 0.3 | EI | Kiser, Dillard, et al., 1969 | RDSH |
| 11.05 ± 0.035 | PE | Elbel and Dieck, 1976 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| PF+ | 22.9 ± 0.4 | ? | EI | Kiser, Dillard, et al., 1969 | RDSH |
| PF2+ | 17.2 ± 0.3 | ? | EI | Kiser, Dillard, et al., 1969 | RDSH |
| PSF2+ | 16.0 ± 0.2 | F | EI | Kiser, Dillard, et al., 1969 | RDSH |
| PF3+ | 14.3 ± 0.2 | S | EI | Kiser, Dillard, et al., 1969 | RDSH |
| PS+ | 19.2 ± 0.5 | ? | EI | Kiser, Dillard, et al., 1969 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L.,
Mass spectrometry of inorganic halides,
Advan. Chem. Ser., 1969, 72, 153. [all data]
Elbel and Dieck, 1976
Elbel, S.; Dieck, H.t.,
Photoelectron spectra of group 5 compounds. Part IV. A study of the E-X bond in R3EX compounds (R = Me or F; E = N or P; X = O or S),
J. Chem. Soc. Dalton Trans., 1976, 1757. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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